火力发电厂安全现状评价模式探讨

以火电厂现状评价为例,探索火力发电厂安全现状评价模式。     

焦化废水生物脱氮半生产性试验启动研究

通过试验研究,探索了焦化废水生物脱氮半生产性启动条件,指出了顺利启动的关键技术是适宜的接种污泥及必须提供的环境条件。     

Decomposition Analysis of Sectoral Energy Use in Beijing （1981-2005） Using the LMDI Method

This paper aims to identify the main driving force for changes of total primary energy consumption in Beijing during the period of 1981-2005. Sectoral energy use was investigated when regional economic structure changed significantly. The changes of total primary energy consumption in Beijing are decomposed into production effects, structural effects and intensity effects using the additive version of the logarithmic mean Divisia index （LMDI） method. Aggregate decomposition analysis showed that the major contributor of total effect was made by the production effect followed by the intensity effect, and the structural effect was relatively insignificant. The total and production effects were all positive. In contrast, the structural effect and intensity effect were all negative. Sectoral decomposition investigation indicated that the most effective way to slow down the growth rate of total primary energy consumption （TPEC） was to reduce the production of the energy-intensive industrial sectors and improving industrial energy intensity. The results show that in this period, Beijing＇s economy has undergone a transformation from an industrial to a service economy. However, the structures of sectoral energy use have not been changed yet, and energy demand should be increasing until the energy-intensive industrial production to be reduced and energy intensity of the region reaches a peak. As sequence energy consumption data of sub-sectors are not available, only the fundamental three sectors are considered： agriculture, industry and service. However, further decomposition into secondary and tertiary sectors is definitely needed for detailed investigations.     

Adsorption behavior of ammonium by a bioadsorbent - Boston ivy leaf powder

The adsorption behaviors of ammonium ions from aqueous solution by a novel bioadsorbent,the Boston ivy (Parthenocissus tricuspidata) leaf powder (BPTL) were investigated.The SEM images and FT-IR spectra were used to characterize BPTL.The mathematical models were used to analyze the adsorption kinetics and isotherms.The optimum pH range for ammonium adsorption by BPTL was found to be 5-10.The adsorption reached equilibrium at 14 hr,and the kinetic data were well fitted by the Logistic model.The intraparticle diffusion was the main rate-controlling step of the adsorption process.The high temperature was favorableto the ammonium adsorption by BPTL,indicating that the adsorption was endothermic.The adsorption equilibrium fitted well to both the Langrnuir model and Freundlich model,and the maximum monolayer adsorption capacities calculated from Langmuir model were 3.37,5.28 and 6.59 mg N/g at 15,25 and 35℃,respectively,which were comparable to those by reported minerals.Both the separation factor (RL) from the Langmuir model and Freundlich exponent (n) suggested that the ammonium adsorption by BPTL was favorable.Therefore,the Boston ivy leaf powder could be considered a novel bioadsorbent for ammonium removal from aqueous solution.     

飞机撞击下核电厂安全壳载荷曲线相关问题研究

针对大型商用飞机对核电厂反应堆安全壳恶意撞击的安全评估需求,综述了国外确定飞机撞击安全壳载荷曲线的基础理论、试验测试技术和数值模拟方法.首先,从理论上对飞机撞击安全壳的载荷特性和Riera撞击模型进行分析,给出了Riera模型的基本假设、模型各项物理意义及模型的求解方法,明确了靶体碰撞表面的冲击载荷(力)由静载项和动载项组成;其次,分析总结了确定Riera模型中压损载荷参数的试验方法和真实飞机撞击载荷测量的试验技术和实施方法,指出大型商用飞机对核电厂反应堆安全壳恶意撞击属"软冲击"范畴,撞击载荷可用Riera模型计算得到;再者,在数值模拟方面,总结了采用有限元技术进行飞机撞击载荷计算和安全评估的数值模拟方法及其发展趋势;最后,在分析国内开展飞机撞击载荷研究面临问题的基础上,指出从理论上建立飞机撞击载荷-时间曲线计算模型及方法,并通过试验和数值模拟验证是国内确定大型商用飞机撞击安全壳结构载荷曲线比较可行的技术路线.     

基于熵值法和物元可拓模型的核电站安全运行状态评价

我国核电事业发展迅速,核电安全是核电产业发展的重要基础.针对我国核电的发展和安全运行现状,建立了安全运行状况指标体系,通过构建物元可拓模型获得各指标在各评价等级上的关联度,将关联度与熵值法求得的指标权重合成得到加权综合关联度,继而确定核电站安全运行状况评价等级.在对核电站整体运行状况进行综合评价的同时,也能实现对安全运行状况各指标的分类评价.     

Research on transesterification parameters for producing plant sterols with supercritical methanol

The supercritical fluid method, regarded as a type of individual production process in the course of preparing plant sterols, has become a promising technology, which possesses advantages of high conversion rate without any pretreatment and need of a catalyst. This study examined the reaction process of the deodorizer distillate (DOD), which mainly included the direct transesterification of DOD to convert into free sterols. The effects of the ratio of methanol to DOD, reaction temperature and time on transesterification were studied. Furthermore, the interactions between different factors were also assessed using the response surface methodology. The optimal conditions obtained were as follows: reaction temperature 553 K, reaction time 80 min, and CH₃OH: DOD = 25:1 (mass ratio). Under these conditions, 36.42% sterol concentration was obtained, which is significantly higher in comparison with the initial sterols’ concentration in raw material (22.45%).     

富氧条件下等离子体协同改性NaY分子筛催化分解NO_x研究

用不同浓度的Cu、Ce和La离子交换Na Y分子筛,对比了不同改性条件下等离子体协同分解NO_x的性能.实验结果表明:Cu是NO_x催化分解的主要活性组分,对于8%Cu-Na Y催化剂,当放电电压为10 k V,放电功率为7.6 W时,NO_x转化率可达46.3%,反应产物中没有NO_2,只有11 ppm的N_2O.Ce的加入可以有效提高催化剂催化活性,对于5%Ce-8%Cu-NaY催化剂,当放电电压为7.8 kV,功率为3.6 W时,NO_x转化率可达67.3%.La的加入同样可以使催化剂活性上升,但不同La含量催化剂的NO_x转化率相差较小.     

Mercury adsorption characteristics of HBr-modified fly ash in an entrained-flow reactor

In this study, the mercury adsorption characteristics of HBr-modified fly ash in an entrained-flow reactor were investigated through thermal decomposition methods. The results show that the mercury adsorption performance of the HBr-modified fly ash was enhanced significantly. The mercury species adsorbed by unmodified fly ash were HgCl₂, HgS and HgO. The mercury adsorbed by HBr-modified fly ash, in the entrained-flow reactor, existed in two forms, HgBr₂ and HgO, and the HBr was the dominant factor promoting oxidation of elemental mercury in the entrained-flow reactor. In the current study, the concentration of HgBr₂ and HgO in ash from the fine ash vessel was 4.6 times greater than for ash from the coarse ash vessel. The fine ash had better mercury adsorption performance than coarse ash, which is most likely due to the higher specific surface area and longer residence time.