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Liu Zhengchao Pan Xunxi Dong Wenbo Hou Huiqi Zhang Zhenman Hou Jian Yu Yong Li Changlin 《环境科学学报(英文版)》1997,9(1):95-99
In this paper pulsed corona discharge is shown to be effective for the decomposition of CF3Cl(Freon-13).The pressure of CF3Cl was 2.67×103Pa,after discharged for 2 min,39.5% of CF3Cl was decomposed.The products were mainly CF4,Cl2 and CF2Cl2.The yield increased by adding O2 or air.Under the same conditions,more than 94% decomposition yield was obtained if 5.32×103Pa O2 or air was added.The composition of products became CF2O,Cl2 and CF4.While the partial pressure of O2 or air reached 1 arm,the decomposition yield decreased to 54.5% and 48. 5% respectively. 相似文献
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简要介绍了等离子体的相关概念及其处理污染物的工作原理,阐述了等离子体技术在固体废弃物治理方面的应用研究概况,并对等离子体在固体废弃物治理中的应用作了市场前景分析,说明了该技术在固体废弃物治理中具有一定的应用前景。 相似文献
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This study mainly deals with the preparation of MgO/B2O3 coatings by plasma spraying on the SUS304 surface and the effects of heatresistant. The power materials of low thermal conductivity were selected to control the heat divergent performance of high temperature parts. The reticular micro-structure between the cover thermal layer and the substrate was prepared by using the plasma spraying method. The powder mixture of MgO and B2O3 were selected as spraying materials and the SUS304 was used as the substrate material. The MgO/B2O3 coating was prepared on the surface of the SUS304 to provide better cover thermal performance. The properties of the microstructures and the morphologies were studied by Optical Microscope, Scanning Electron Microscope, Electron Probe Microanalyzer, and X-ray Diffraction. The results showed that the cover thermal performance has been improved. 相似文献
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Supercritical water oxidation of polyvinyl alcohol and desizing wastewater:Influence of NaOH on the organic decomposition 总被引:1,自引:0,他引:1
Jie Zhang Shuzhong Wang Yang Guo Donghai Xu Yanmeng Gong Xingying Tang 《环境科学学报(英文版)》2013,25(8):1583-1591
Polyvinyl alcohol is a refractory compound widely used in industry. Here we report supercritical water oxidation of polyvinyl alcohol solution and desizing wastewater with and without sodium hydroxide addition. However, it is difficult to implement complete degradation of organics even though polyvinyl alcohol can readily crack under supercritical water treatment. Sodium hydroxide had a significant catalytic effect during the supercritical water oxidation of polyvinyl alcohol. It appears that the OH ion participated in the C-C bond cleavage of polyvinyl alcohol molecules, the CO2-capture reaction and the neutralization of intermediate organic acids, promoting the overall reactions moving in the forward direction. Acetaldehyde was a typical intermediate product during reaction. For supercritical water oxidation of desizing wastewater, a high destruction rate (98.25%) based on total organic carbon was achieved. In addition, cases where initial wastewater was alkaline were favorable for supercritical water oxidation treatment, but salt precipitation and blockage issues arising during the process need to be taken into account seriously. 相似文献
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绿色化学又称环境友好化学,它是在化学产品的设计、制造和应用过程中运用一套原理和理论来减少或者消除对有害物质的生产和利用的一门学科。绿色化学工艺的目标是用化学的技术和手段去减少或消除那些对人类健康有害的原料、产物、副产物、溶剂和试剂等的产生或应用。催化技术是绿色化学工艺研究及应用的重要手段,简要介绍了绿色化学与催化的关系、催化剂的研究进展及典型实例,并列举了几种新型绿色催化剂,详细分析了其环境友好特性。 相似文献
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