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101.
污水处理厂低温等离子体恶臭治理技术 总被引:2,自引:1,他引:1
利用低温等离子体技术处理污水厂恶臭气体,是一种新的技术。介绍了该技术处理恶臭的机理和相关工程的工艺流程以及处理效果,实际应用表明该技术对污水处理厂恶臭气体的治理是十分有效的。 相似文献
102.
The decomposition of chloroform (CHCl3) diluted in air was studied. The experiment was carried out by using a gliding arc plasma. Different values of initial concentrations of chloroform, total gas flow rates, and input power frequencies have been used to investigate this effects on the conversion reaction products both qualitatively and quantitatively. Experimental results indicate that the maximum conversion of chloroform was 97% at a total gas flow rate of 180?L?h?1 containing 1% chloroform. Using air as carrier gas, decomposition of CHCl3 produces CCl4, CO2, CO, and Cl2 as the main products. Small amounts of HCl and COCl2 are also detected. Liquid products were also produced. 相似文献
103.
An automated method for the indirect determination of fluoride by inductively coupled plasma atomic emission spectrometry using discontinuous-flow analysis has been developed. A modified flow injection analysis system was used for sample preparation. The method is based on the determination of excess cerium(III) ion after precipitation of CeF3. Separation of the precipitate is performed online on a syringe membrane filter that is cleaned each analysis cycle by 1 M nitric acid, ensuring a long life-time for the filter. As a result of the short reaction time, a detection limit of 9.5 mg L?1 was obtained. The precision (RSD) of the proposed method is 1.02% at fluoride concentration of 28 mg L?1. The applicability of the technique for groundwater monitoring of fluoride-contaminated area is demonstrated. 相似文献
104.
Kebede Nigussie Mekonnen Bhagwan Singh Chandravanshi Mesfin Redi-Abshiro Robert Ian McCrindle 《毒物与环境化学》2013,95(10):1501-1515
For the determination of 15 potentially toxic elements (V, Cr, Fe, Mn, Co, Ni, Cu, Zn, As, Se, Ag, Cd, Sn, Hg, and Pb) in plant and sediment samples of the Akaki River, Ethiopia, inductively coupled plasma–mass spectrometry, inductively coupled plasma–optical emission spectrometry, and a RA-915+ mercury analyzer were applied. Sediment and plant samples were mineralized using a closed-vessel microwave-assisted digestion system. The elemental concentrations varied considerably in plant and sediment samples. The minimum concentration was observed for known toxic elements (As, Hg, and Cd) while the highest concentration was observed for the elements of relatively low toxicity Zn, Mn, and Fe. The concentration of Cr, Fe, Pb, Zn, and As in Swiss chard surpassed the maximum permissible levels at specific sites. At some of the sites, the sediment quality guidelines are surpassed for Cu, Zn, and Pb. 相似文献
105.
为了解CS2(二硫化碳)在介质阻挡放电反应器中的降解特性,提高其去除率,设计并制作了同轴圆柱介质阻挡放电反应器,研究了介质层数、外施电压、中心电极材料及直径、背景气氛种类和RH(相对湿度)对CS2去除率的影响. 结果表明:在外施电压(4.0~6.5kV)较低时,单介质反应器的CS2去除率高于双介质反应器;而在外施电压(6.5~9.0kV)较高时,双介质反应器对CS2的去除效果更好,增大外施电压有利于CS2的降解. 铜丝比不锈钢丝更适合用作反应器的中心电极,此外,增加中心电极的直径也可提高CS2去除率. 当中心电极直径从 3.2mm增至4.8mm时,CS2平均去除率由63%增至75%,但平均质量能耗由510kJ/mg增至611kJ/mg. 同等条件下,CS2在氧气中的平均去除率(74%)最大,空气(59%)中次之,氮气(48%)中最小;背景气氛中适量的RH(26%)有助于提高CS2去除率,但RH太大(大于50%)反而会降低CS2去除率. 相似文献
106.
Junhua LI Hong HE Chun HU Jincai ZHAO 《Frontiers of Environmental Science & Engineering》2013,7(3):302-325
This review reports the research progress in the abatement of major pollutants in air and water by environmental catalysis. For air pollution control, the selective catalytic reduction of NO x (SCR) by ammonia and hydrocarbons on metal oxide and zeolite catalysts are reviewed and discussed, as is the removal of Hg from flue gas by catalysis. The oxidation of Volatile organic compounds (VOCs) by photo- and thermal-catalysis for indoor air quality improvement is reviewed. For wastewater treatment, the catalytic elimination of inorganic and organic pollutants in wastewater is presented. In addition, the mechanism for the procedure of abatement of air and water pollutants by catalysis is discussed in this review. Finally, a research orientation on environment catalysis for the treatment of air pollutants and wastewater is proposed. 相似文献
107.
采用化学共沉淀法制备磁性钯钴水滑石催化剂(M-Pd/Co@CHT),用于吸附催化还原去除水中的高氯酸盐.同时,研究了不同溶液pH值、催化剂投加量、温度、共存离子和氢气流量等因素的影响,考察了吸附动力学和等温吸附过程.最后对反应前后材料进行表征,以明确吸附催化氢还原反应机理.结果表明:在较宽的pH范围(5~10)内,M-Pd/Co@CHT显示出对高氯酸盐较高、较稳定的吸附效率;伪二阶动力学模型和Langmuir模型能很好地拟合催化剂对高氯酸盐的吸附规律,说明该吸附过程是近似单层的化学吸附,最大单层吸附容量为172.65 mg·g-1;温度、投加量和供氢气量对M-Pd/Co@CHT加氢催化还原高氯酸盐有显著的影响,当高氯酸盐初始浓度为10 mg·L-1时,在最优实验条件下30 min可以去除约54%的高氯酸盐;利用XRD、FTIR、BET、XPS及VSM等手段对M-Pd/Co@CHT进行表征,结果表明,介孔M-Pd/Co@CHT可以有效吸附或催化高氯酸盐;高氯酸盐首先被吸附至M-Pd/Co@CHT上从而恢复其层状结构,而后在Pd/Co二元金属催化剂的作用下被氢还原去除;利用外加磁场能够实现材料的固液分离,可以有效地避免二次污染. 相似文献
108.
在光/电/化学协同催化反应器中,以离子交换膜代替盐桥连通阴、阳两室,以30 mg/L的甲基红溶液为目标降解物,考察了不同连通方式、初始pH和阴极电位对反应的影响. 结果表明:甲基红在阳离子膜型反应器中的表观反应速率常数明显高于盐桥型及阴离子交换膜型反应器,这是由于阳离子交换膜可以及时有效地将阳极室中产生的H+转移至阴极室中参与阴极反应. 甲基红在阳离子膜型反应器中的去除率随溶液初始pH的增高而降低,随阴极电位的增加先增大后减小,最佳反应条件为pH=2.0~3.0,阴极电位(-Ec)=0.6 V. 相似文献
109.
110.