利用废泡沫塑料制备防水涂料

介绍了利用废聚苯乙烯泡沫塑料制备水乳型防水涂料的工艺流程、配方及其性能测试方法。     

Formation of recycled plastics from depolymerized monomers derived from waste fiber-reinforced plastics

To develop a new method for the chemical recycling of plastics, we examined the formation of recycled polymers from the recovered monomeric materials of solubilized waste fiber-reinforced plastics (FRP) under supercritical alcoholic conditions. Treatment of waste FRP with supercritical MeOH resulted in the formation of monomeric organic compounds that mainly contained dimethyl phthalate (DMP) and propylene glycol. The presence of these materials was confirmed by gas chromatography and nuclear magnetic resonance analyses and they were mixed with new DMP and glycols in various ratios to form unsaturated polyesters. The polymerization progressed successfully for all mixing ratios of the recovered and new DMP. Hardness tests on these recycled polymers indicated that the polymer made from a 1:1 mixture of recovered and new dimethyl phthalate had almost the same level of hardness as the polymers made from new materials. We also examined the formation of recycled FRP by using glass fibers and monomeric materials recovered through the present depolymerization method. Chemical Feedstock Recycling & Other Innovative Recycling Techniques 6     

Wood Modification Effects on Weathering of HDPE-Based Wood Plastic Composites

The effects of weathering on the constituents of wood and polymer matrix behavior in wood plastic composites (WPCs) were investigated. WPCs were produced from pine, extractives-free pine, and pine holocellulose fibers (60%) together with HDPE (40%). These composites were subjected to xenon-arc accelerated and outside weathering for a total of 1200 h and 120 days, respectively. The color and chemical changes that occurred on the surface of the WPCs were analyzed using a set of analytical techniques. For pine and extractive-free pine filled composites, the results showed that the total color change, lightness, and oxidation increased, while the lignin content decreased. In addition, the weight average molecular weight (Mw) and number average molecular weight (Mn) of extracted HDPE decreased with an increase in exposure time of the composites. However, HDPE crystallinity increased with longer exposure time. Lightness of holocellulose-based WPC changed the least while the change in its HDPE crystallinity was not significant compared to the other composite types. Therefore, holocellulose-based WPC may be preferred for applications where color stability is of high priority.     

充填管道系统失效模式与影响分析(FMEA)及失效影响模糊评估

根据金川矿区充填管道系统的运行情况,结合充填实践经验,建立了充填管道系统的失效模式与影响分析法(FMEA)分析表,得出系统存在10种失效模式。针对FMEA分析表中失效影响存在较大模糊性而难以有效估计的特点,引入模糊评估方法来进行分析。通过该矿区充填管道系统各失效模式产生失效影响的模糊评估,得到不同失效模式对系统可靠性影响的排序结果。结果表明:该方法的评估结果与实际情况比较吻合;可以使分析定量化,有助于工程人员充分利用系统模糊信息;该方法也能用于其他系统失效模式影响的模糊评估。     

桥式起重机结构可靠性失效准则与剩余寿命评估准则

针对确定可靠性失效准则和剩余寿命评估准则时,未与起重机结构实际相结合的特点,笔者将机电类特种设备钢结构系统的可靠性分析失效准则与结构剩余寿命评估准则有机的统一起来,以桥式起重机结构系统为研究对象,确定了桥式起重机钢结构系统的具体失效准则,即从静强度、疲劳强度、刚度、整体稳定性、局部稳定性以及最大失效路径长度等多方面进行评价。通过对桥式起重机起重量摄动引起刚度失效比重变化结果对比,验证了结果的正确性。该方法可为起重机可靠性与剩余寿命评估做好前期准备,为机电类特种设备安全评估方法提供一条新理论新思路。     

不同变形失稳模式下隧道围岩稳定性判据研究的进展

计算机模拟隧道围岩失稳研究的困难在于失稳模型不清楚、失稳判据不明确。本文综合分析了目前国内外应用的隧道稳定性判别方法,总结了不同变形失稳机制下的计算模型及其量化的破坏判据,分析了各种方法的研究进展和存在局限,为围岩稳定性数值模拟提供快速、合理、可操作的判据。     

高陡岩质边坡抗震稳定性的三维有限元分析

岩质边坡在地震作用下稳定性的计算一般采用拟静力法和有限单元法,拟静力法因应用简便而得到大量应用,至今广泛应用于边坡的抗震计算。建立了某溢洪道引渠左侧整体边坡三维有限元模型,选用ADINA软件并采用拟静力法对三维模型进行了抗震稳定性计算和分析,结合有限元分析的结果,提出溢洪道引渠左侧整体边坡抗震措施和建议。     

Phthalates and perfluorinated alkylated substances in Atlantic bluefin tuna (Thunnus thynnus) specimens from Mediterranean Sea (Sardinia,Italy): Levels and risks for human consumption

Atlantic blue fin tuna (Thunnus thynnus) is a species of great importance for Mediterranean Sea area, from both ecological and commercial points of view. The scientific literature reports few data on the contamination of this fish by emerging organic compounds such as perfluorinated alkylated substances(PFASs) and phthalates, being the latter never been studied in tuna. This study therefore investigated the presence of the PFASs perfluorooctane sulphonate (PFOS) and perfluoroctanoic acid (PFOA) and the phthalate di-2-ethylhexyl phthalate (DEHP), also monitored by its metabolite mono-2-ethylhexyl phthalate(MEHP), to assess both the state of contamination of Atlantic bluefin tuna specimen and the risk due to the toxicity of these compounds for human consumption. While PFOA was never found, detectable levels of PFOS (0.4–1.88 ng/g), DEHP (9–14.62 ng/g) and MEHP (1.5–6.30 ng/g) were found. The results were elaborated relating the accumulation to the size and age of the individuals and showed a correlation between the levels of different pollutants investigated.     

战术通信网络故障模式研究

对战术通信网络的故障进行了定义,结合常见的故障给出了战术通信网的故障模式及对战术通信网故障产品的原因及影响进行分析,最后对战术通信网络按照不同层次分别给出了故障的类别及判决标准,为在不同层面故障的判决奠定基础。     

光纤传导可见光降解亚甲基蓝

针对浓度大、色度高的印染废水难以处理的情况,选用加入光纤的光催化体系进行研究。采用溶胶凝胶法制备了Ag+/TiO2粉体光催化剂,用固体紫外可见光谱、X射线衍射对其进行表征。选用亚甲基蓝溶液作为目标降解物,评价了Ag+/TiO2在可见光下的光催化活性。分别考察了加入石英芯侧光光纤与塑料侧光光纤反应体系下,催化剂量、光纤数量、光照强度和pH值等因素对亚甲基蓝降解实验的影响。结果表明,选用20 mg/L的亚甲基蓝,采用催化剂量为11.67 g/L,500根侧光光纤,300 W的外部光源,pH值约为11时,光催化降解效果最佳,均能达到90%以上。