硝酸甲胺反应过程的安全性研究

用反应量热仪(RC1e)对硝酸溶液与一甲胺溶液在反应过程中的热安定性进行初步研究,分别测试不同反应温度、加料速度和初始硝酸浓度下反应的放热情况。实验结果表明:该中和过程反应迅速,在室温就能进行;与反应温度、加料速度相比,起始硝酸浓度对反应安全性影响最大,且硝酸浓度越高,反应的速度和反应的完全程度也越高。实验还表明:RC1e是研究反应过程中热安定性情况的有效工具,能通过反应过程的热量变化体现反应速率,所得结果对硝酸甲胺的工业化生产具有重要的参考价值。     

城市污水除磷技术发展

磷是水体富营养化的一个主要限制因素，控制出水中磷的浓度尤其重要。污水除磷方法有生物除磷、化学除磷及生态除磷，也可将各种方法组合使用，如生物一化学除磷、生物一生态除磷等，实际应用中应根据具体情况选择适宜的除磷方法。     

美国油气开发钻井废物排放管理法规浅析

钻井是石油天然气勘探开发过程中的重要环节,钻井过程中污染物的排放管理也受到各国普遍的重视。对钻井污染物的特点进行了分析,在此基础上概括地介绍了美国的相关环境管理法规体系。重点论述了与钻井排污有关的资源保护与补偿法、安全饮用水法、清洁水法等,总结了可供我国借鉴的若干法规、标准制定的理念和方法。     

抚顺石化公司硫磺回收装置的扩建和改造

抚顺石化分公司石油三厂原有硫磺回收装置的处理能力已经不能满足生产的需要,2002年对硫磺回收装置进行了扩建和改造。该装置采用了一段高温转化、二级催化转化的克劳斯工艺,采用揝SR敾乖?吸收工艺处理尾气。扩能改造后,新增的尾气处理能力与硫磺回收能力相配套,排放的废气符合国家现行的环保标准。该装置工艺路线合理、可靠,硫回收率高。     

环评中锅炉房大气污染源强的确定

在环境评价中,污染源强的确定对环境影响因素评价的分析结果有重要作用。对锅炉房污染物排放的分析表明,影响锅炉房大气污染物的主要因素有燃料的构成、发热量和燃烧方式等。确定锅炉房大气污染物的方法主要有物料衡算法、实测法和经验系数法。在这三种方法中,物料衡算法被普遍采用。在确定锅炉房大气污染物的排放量时,也可以采用物料衡算法和实测法相结合的方法。     

延边地区公路沿线边坡失稳试验分析

延边地区公路沿线分布着大量软岩，其岩性具有强膨胀性，致使这一地区公路边坡出现了多处滑坡现象。为了合理地处理这一工程地质问题，需要认真研究该种软岩的膨胀特性。选取滑坡体软岩为研究对象，定量分析了其自由膨胀率、无荷膨胀率和有荷膨胀率，并具体测定了其膨胀力，探讨了其膨胀率和膨胀力的变化规律，揭示了研究区软岩的膨胀特性，为公路建设中软岩边坡加固参数的选取提供了科学的依据。     

改性沸石用于饮用水除氟的试验研究

试验针对存在的氟污染饮用水问题,将天然沸石用NaOH和Al2（SO4）3溶液改性制成除氟材料.静态试验研究表明：改性沸石除氟吸附反应快,其最佳pH值范围为5～9,而且对氟离子具有较好的离子选择性能.通过动态试验研究发现,降低进水流量和原水浓度可以增大滤层的吸附容量.两种再生方式对比试验表明：用Al2（SO4）3溶液再生效果优于用NaOH和Al2（SO4）3溶液联合再生.     

污染物排放相关指标计算方法的研究

针对传统的污染排放数据指标计算方法存在的问题,提出污染物排放指标应根据排污强度和经济指标确定的新思路,同时提出污染物排放指标数据的快速测算模型设计.建议通过环境监测数据或物料衡算数据确定每个排污单位的平均排污强度,作为计算机处理的参数,再由该排污单位申报每月的经济指标(产量或产值),输入计算机计算其产污量、排污量和去除量.实施计算机管理的关键是选取适当的数据计算模型.新思路应该能够规范计算程序,建立污染源动态数据库,对排污数据实行有效的统计分析.     

A Parallel Study of SAR Levels in Head Tissues for Three Antennas Used in Cellular Telephones: Monopole, Helix and Patch

Summary This paper is a comparative study of several antennas commonly used in cellular telephones. These include a monopole, a helix-monopole and a patch antenna. Each one of these structures is modeled and numerically tested using finite-difference time-domain simulation and human models based on magnetic-resonance images, which allow for inclusion of details of the human body in the simulation. The testing procedure involves antenna simulation in the proximity of the human head. The behavior of each antenna is evaluated for variable distances from the head geometry (0, 1, 2, 4, 8 and 16 mm). Continuous waveform, representative of the sources used in mobile telephones, (250 mW, 1.8 GHz) is used as the form of the antenna excitation. The simulation outputs used as measures for this comparative study include transmitting and receiving antenna characteristics and the specific absorption rate (SAR). The SAR levels for the head tissues are calculated for and with accordance to the two currently accepted standards: Federal Communications Commission (FCC) and International Commission on Non-Ionizing Radiation Protection (ICNIRP). The computed SAR levels within each of the considered tissues vary for the three antennas under investigation and are within the determined health safety standards. Results suggest that the patch antenna may be the structure of choice when considering safety standards, as its radiation yields the lowest local SAR in the head tissues.     

The rise of glyphosate and new opportunities for biosentinel early‐warning studies

Glyphosate has become the most commonly used herbicide worldwide and is reputedly environmentally benign, nontoxic, and safe for use near wildlife and humans. However, studies indicate its toxicity is underestimated and its persistence in the environment is greater than once thought. Its actions as a neurotoxin and endocrine disruptor indicate its potential to act in similar ways to persistent organic pollutants such as the organochlorines dichlorodiphenyltrichloroethane (DDT) and dioxin. Exposure to glyphosate and glyphosate‐based herbicides for both wildlife and people is likely to be chronic and at sublethal levels, with multiple and ongoing exposure events occurring in urban and agricultural landscapes. Despite this, there has been little research on the impact of glyphosate on wildlife populations, and existing studies appear in the agricultural, toxicology, and water‐chemistry literature that may have limited visibility among wildlife biologists. These studies clearly demonstrate a link between chronic exposure and neurotoxicity, endocrine disruption, cell damage, and immune suppression. There is a strong case for the recognition of glyphosate as an emerging organic contaminant and substantial potential exists for collaborative research among ecologists, toxicologists, and chemists to quantify the impact of glyphosate on wildlife and to evaluate the role of biosentinel species in a preemptive move to mitigate downstream impacts on people. There is scope to develop a decision framework to aid the choice of species to biomonitor and analysis methods based on the target contaminant, spatial and temporal extent of contamination, and perceived risk. Birds in particular offer considerable potential in this role because they span agricultural and urban environments, coastal, inland, and wetland ecosystems where glyphosate residues are known to be present.