全文获取类型
收费全文 | 654篇 |
免费 | 94篇 |
国内免费 | 283篇 |
专业分类
安全科学 | 52篇 |
废物处理 | 174篇 |
环保管理 | 47篇 |
综合类 | 478篇 |
基础理论 | 120篇 |
污染及防治 | 128篇 |
评价与监测 | 29篇 |
社会与环境 | 2篇 |
灾害及防治 | 1篇 |
出版年
2024年 | 2篇 |
2023年 | 6篇 |
2022年 | 4篇 |
2021年 | 18篇 |
2020年 | 15篇 |
2019年 | 24篇 |
2018年 | 20篇 |
2017年 | 15篇 |
2016年 | 31篇 |
2015年 | 51篇 |
2014年 | 41篇 |
2013年 | 75篇 |
2012年 | 70篇 |
2011年 | 68篇 |
2010年 | 43篇 |
2009年 | 39篇 |
2008年 | 36篇 |
2007年 | 53篇 |
2006年 | 54篇 |
2005年 | 50篇 |
2004年 | 51篇 |
2003年 | 34篇 |
2002年 | 30篇 |
2001年 | 26篇 |
2000年 | 38篇 |
1999年 | 23篇 |
1998年 | 26篇 |
1997年 | 19篇 |
1996年 | 16篇 |
1995年 | 15篇 |
1994年 | 17篇 |
1993年 | 8篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1986年 | 2篇 |
1984年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1978年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有1031条查询结果,搜索用时 296 毫秒
51.
用蒽醌生产中的废硫酸制备硫酸钾 总被引:2,自引:0,他引:2
研究了以蒽醌生产中的废硫酸为原料,通过缔合,置换,解缔等步骤,制备硫酸钾的最佳工艺条件。在最佳条件下,可使废硫酸中H2SO4的质量分数从23%降至0.60%,废硫酸成盐率为89.01%,硫酸钾纯度为95.85%。 相似文献
52.
As one of the biodegradable polymers, the blend of poly(butylene succinate) and poly(butylene terephthalate) is dealt with in this study. In our previous work, it was demonstrated that PBS and PBT are immiscible not only from the changes of T
g but also from logG–log G plots. It is expected that the biodegradability of the blends could be improved by enhancing the miscibility. We tried to induce the transesterification reaction between two polyesters with various time intervals to enhance the miscibility of the blends. The extent of transesterification reaction was examined by 1H-NMR. We utilized a dynamic mechanical thermal analyzer and a rotational rheometer to investigate the changes in miscibility. We also verified the biodegradability of PBS/PBT blends after the transesterification reaction by the composting method. 相似文献
53.
Azotobacter vinelandii UWD, ATCC 53799, an engineered strain derived from Azotobacter vinelandii UW was used in the poly(ethylene glycol) (PEG)-modulated synthesis of poly(-hydroxybutyrate) (PHB). To the best of our knowledge, this is the first report on modulating the production of PHB by amending the fermentation broth with PEG using A. vinelandii UWD. It was determined that A. vinelandii UWD is prone to back-mutation to the parent strain; hence fermentation experiments require the use of the antibiotic rifampicin. Diethylene glycol (DEG) and PEGs with molecular weights of 400, 2000, and 3400 Da and pentaerythritol ethoxylate (PEE) were used in the modulated fermentation experiments in a concentration of 2% (w/v). The molecular weight of the resulting polymers was reduced by up to 78%. No impact on the productivity of the strain was observed. Spectroscopic evidence showed that PEG-modulated synthesis resulted in the covalent attachment of the ethylene glycol moiety only when a small molecule, DEG, was used. PEGs had the same effects on the polymer formation in terms of molecular weight reduction as DEG, but no spectroscopic evidence was found for the formation of a covalent linkage between PHB and higher molecular weight PEGs. 相似文献
54.
Wunsam Sybille Kamenik Christian Schmidt Roland 《Water, Air, & Soil Pollution: Focus》2002,2(4):93-108
Traunsee, a 191 m deep Alpine lake in Austria, is affected by industrial tailings from the soda and salt mining industries since 1883. In 1998 littoral water chloride concentrations ranged between 40 and 85 mg L-1 and the highest conductivity was 560 S cm-1, which is almost double as high as the values reported from the two nearby reference lakes. Chloride concentrations increased towards the location of the industrial salt and soda emission into the lake. Analogously to the chloride gradient, the epilithic littoral diatom flora changes towards the waste inlet. Shifts in the species percentages towards the emission source, a high percentage of taxa with large conductivity tolerances, the presence of a small Achnanthes minutissima Kützing morphotype, and occurrences of taxa focused at habitats of higher electrolyte content, indicate subtle impacts on the epilithic diatom flora. An analysis of the seasonal succession of the epilithic diatoms at the waste inlet compared to a lake intern reference site, reveals that only during the late summer period in 1998 the diatom assemblage at the waste inlet became significantly different, indicating seasonally restricted effects of the industrial emissions. 相似文献
55.
一氯二乙基铝装置为甲类火灾危险装置。通过对一氯二乙基铝装置工艺流程及各单元工艺特点的详细分析,危险源的辨识从物料危险性、工艺过程危险性、工艺操作危险性等角度展开,从而确定出该装置的重大风险因素。在对一氯二乙基铝装置危险源辨识和分析的基础上,对各工艺单元提出相应的控制措施,预防事故发生。 相似文献
56.
研究了用聚合氯化铝(PAC)、聚合硫酸铁(PFS)、聚丙烯酰胺(PAM)及改性蒙托石等不同无机—有机高分子絮凝剂复配使用处理炼钢厂连铸含油废水的除油效果,考察了不同絮凝剂的复配以及絮凝剂的不同复配比例对处理效果的影响。试验结果表明,用聚合氯化铝(PAC)+聚合硫酸铁(PFS)+聚丙烯酰胺(PAM)3种絮凝剂复配使用除油效果最佳,当3种絮凝剂的复配比为2∶2∶3时除油效果最好,除油率达到88.2%,达到国家排放标准。 相似文献
57.
58.
ABSTRACT: Following an enclosure of a sink-hole connecting Lake Tarpon to the Gulf of Mexico, the chloride concentration of lake waters decreased. Water and chloride budgets for the lake in 1975 were prepared, and predictions using the model of Lerman and Brunskill (1971) were made as to the time required for the lake to achieve fresh water status. Model verification indicated good agreement with predictions in 1976; however, data on [C1-] for 1977 and 1978 are not as supportive of the model used. The information concerning the Lake Tarpon watershed provided by this latter fact is discussed. 相似文献
59.
60.
Chloride ingress and freeze-thaw cycles are the most important mechanisms for deterioration of concrete in cold areas. In this study, chloride ingress into concrete that has been exposed to freeze-thaw cycles was investigated. Data demonstrated that freeze-thaw cycles allow for a larger effective diffusion coefficient. Based on our findings, the concept of a developing coefficient was defined to obtain the evolution equation of the effective diffusion coefficient. Together with considering the effect of aging of concrete on the effective diffusion coefficient, the time-dependent diffusion coefficient was also obtained. Based on Fick's second law and time-dependent diffusion coefficient, chloride ingress model of concrete in cold regions was derived. Finally, the model was tested by comparing predicted results, lab results, and in situ inspection data. 相似文献