全文获取类型
收费全文 | 10967篇 |
免费 | 1780篇 |
国内免费 | 6080篇 |
专业分类
安全科学 | 1911篇 |
废物处理 | 360篇 |
环保管理 | 914篇 |
综合类 | 9783篇 |
基础理论 | 3095篇 |
环境理论 | 2篇 |
污染及防治 | 1648篇 |
评价与监测 | 514篇 |
社会与环境 | 350篇 |
灾害及防治 | 250篇 |
出版年
2024年 | 60篇 |
2023年 | 424篇 |
2022年 | 626篇 |
2021年 | 709篇 |
2020年 | 691篇 |
2019年 | 700篇 |
2018年 | 666篇 |
2017年 | 668篇 |
2016年 | 748篇 |
2015年 | 853篇 |
2014年 | 769篇 |
2013年 | 1219篇 |
2012年 | 1236篇 |
2011年 | 1256篇 |
2010年 | 925篇 |
2009年 | 1003篇 |
2008年 | 822篇 |
2007年 | 914篇 |
2006年 | 889篇 |
2005年 | 649篇 |
2004年 | 534篇 |
2003年 | 434篇 |
2002年 | 335篇 |
2001年 | 293篇 |
2000年 | 254篇 |
1999年 | 204篇 |
1998年 | 144篇 |
1997年 | 151篇 |
1996年 | 108篇 |
1995年 | 115篇 |
1994年 | 79篇 |
1993年 | 78篇 |
1992年 | 54篇 |
1991年 | 21篇 |
1990年 | 28篇 |
1989年 | 22篇 |
1988年 | 16篇 |
1987年 | 5篇 |
1986年 | 13篇 |
1985年 | 7篇 |
1984年 | 7篇 |
1983年 | 12篇 |
1982年 | 13篇 |
1981年 | 9篇 |
1980年 | 7篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1973年 | 5篇 |
1972年 | 5篇 |
1971年 | 33篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
171.
Yongfeng Ji Zidan Yuan Guoqing Zhang Xing Wu Xu M Jinru Lin Shaofeng Wang 《环境科学学报(英文版)》2023,35(2):31-41
An advanced cost-saving method of removal of high-As(Ⅲ) from SO4(-Ⅱ)-rich metallurgi cal wastewater has been developed by diluting the SO4(-Ⅱ) content with As(Ⅲ)-Cl(-Ⅰ)-rich metallurgical wastewater and then by the direct precipitation of As(Ⅲ) with Fe(Ⅲ) at pH2.3.As(Ⅲ) removal at various SO4(-Ⅱ)/Cl(-Ⅰ) molar ratios and temperatures was investigated The results showed that 65.2–98.2%of As(III) immobilization into solids occurred at the SO4(Ⅱ)/Cl(-Ⅰ) mo... 相似文献
172.
《环境科学学报(英文版)》2023,35(3):388-400
Removing large concentrations of organic pollutants from water efficiently and quickly under visible light is essential to developing photocatalytic technology and improving solar energy efficiency. This study used a simple hydrothermal method to prepare a non-metallic, S-doped NaTaO3 (S-NTO) photocatalyst, which was then loaded onto biochar (BC) to form a S-NTO/BC composite photocatalyst. After uniform loading onto BC, the S-NTO particles transformed from cubic to spherical. The photogenerated electron-hole pair recombination probability of the composite photocatalyst was significantly lower than those of the NTO particles. The light absorption range of the catalyst was effectively widened from 310 nm UV region to visible region. In addition, a dual-effect catalytic system was constructed by introducing peroxymonosulfate (PMS) into the environment of the pollution to be degraded. The Rhodamine B, Methyl Orange, Acid Orange 7, tetracycline, and ciprofloxacin degradation efficiency at 40 mg/L reached 99.6%, 99.2%, 84.5%, 67.1%, and 70.7%, respectively, after irradiation by a 40 W lamps for 90 min. The high-efficiency visible-light catalytic activity of the dual-effect catalytic system was attributed to doping with non-metallic sulfur and loading of catalysts onto BC. The development of this dual-effect catalytic system provides new ideas for quickly and efficiently solving the problem of high-concentration organic pollution in aqueous environments, rationally and fully utilizing solar energy, and expanding the application of photocatalytic technology to practice. 相似文献
173.
辛基酚的体内类雌激素活性评价 总被引:5,自引:0,他引:5
利用体内大鼠子宫增重试验检测辛基酚(OP)的类雌激素活性,并对其观测终点及影响因素进行了初步研究。结果显示,OP经大鼠体内染毒,可引起大鼠子宫湿重、子宫内皮细胞厚度、子宫腺数量明显增加,具有明显的类雌激素活性。三条染毒途径检测敏感度腹腔染毒>经皮下染毒>经灌胃染毒。 相似文献
174.
Effects of cycling and constant temperature on development and reproduction of the armyworm, Mythimna separata (Walker) were investigated by rearing the insects on the artificial diet under temperatures covering low(16-24℃ vs. 20 ℃ ), medial(20-28℃ vs. 24℃ ) and high(24-32 ℃ vs. 28 ℃) regions. In the low region, all the immature stages of the insect developed significantly faster under alternating temperatures than at corresponding constant temperatures. For the medial region, their development was little affected by variable temperatures. For the high region, developmental durations tended to be longer under cycling temperatures except egg stage.Mean fecundities of the adult moths markedly increased under cycling temperatures as compared with those at respective constant temperature in all regions.Possible reasons for effect of alternating temperatures on insect development are discussed in some details. 相似文献
175.
目的研究0Cr18Ni9(钝化)不锈钢与0Cr18Ni10Ti(钝化)不锈钢在酸性盐雾条件下的腐蚀行为,为发动机零件选材及防护措施的改进提供依据。方法按GJB150.11A—2009《军用装备环境试验方法盐雾试验》进行,调节溶液p H到3.5±0.5,以24 h喷雾润湿+24 h干燥为一个循环,分别开展2(96 h)、4(192 h)、5(240 h)个循环的酸性盐雾试验。采用目视、称量、X射线衍射(XRD)、扫描电子显微镜(SEM)及能谱仪(EDS)对盐雾腐蚀后试样进行观察及分析。结果 0Cr18Ni9(钝化)与0Cr18Ni10Ti(钝化)两种奥氏体不锈钢均发生了轻微的腐蚀,主要为局部腐蚀及均匀腐蚀。结论两种金属在酸性盐雾条件下耐蚀性良好,且可满足目前海军型发动机对材料耐酸性盐雾腐蚀的要求,0Cr18Ni9(钝化)略优于0Cr18Ni10Ti(钝化)。 相似文献
176.
《环境科学学报(英文版)》2023,35(4):517-530
Graphite carbon nitride has many excellent properties as a two-dimensional semiconductor material so that it has a wide application prospect in the field of photocatalysis. However, the traditional problems such as high recombination rate of photogenerated carriers limit its application. In this work, we introduce nitrogen deficiency into g-C3N4 to solve this problem a simple and safe in-situ reduction method. g-C3N4/CaCO3 was obtained by a simple and safe one-step calcination method with industrial-grade micron particles CaCO3. Cyano group modification was in-situ reduced during the thermal polymerization process, which would change the internal electronic structure of g-C3N4. The successful combination of g-C3N4 and CaCO3 and the introduction of cyanide have been proved by Fourier transform infrared spectroscopy and X-ray photoelectron spectrometer. The formation of the cyano group, an electron-absorbing group, promotes the effective separation of photogenic electron hole pairs and inhibits the recombination of photogenic carriers. These advantages result in the generation of more •O2− and 1O2 in the catalytic system, which increases the photocatalytic efficiency of nicotine degradation by ten times. Furthermore, the degradation process of nicotine has been studied in this work to provide a basis for the degradation of nicotine organic pollutants in the air. 相似文献
177.
草坪作为城市绿地的重要组成部分,其温室气体的吸收或排放不容忽视.然而当前对亚热带城市草坪温室气体通量的研究相对匮乏.采用静态箱-气相色谱法,对杭州市城区典型城市草坪的多种温室气体(CO2、CH4、N2O和CO)地气交换通量进行了连续观测研究.结果表明,城市草坪的温室气体月平均通量变化明显,而其日变化特征并不明显.城市草地和土壤(无植被生长的裸土)是大气N2O的源,平均通量分别为(0.66±0.17)μg·(m2·min)-1和(0.58±0.20)μg·(m2·min)-1;是CH4和CO的汇,其中CH4平均通量分别为(-0.21±0.078)μg·(m2·min)-1和(-0.26±0.10)μg·(m2·min)-1,CO分别为(-6.36±1.28)μg·(m2·min)-1和(-6.55±1.69)μg·(m2·min)-1.城市草地和土壤CO2平均通量分别为(5.28±0.75) mg·(m2·min)-1和(4.83±0.91) mg·(m2·min)-1.基于相关性分析研究发现,草地和土壤的CO2和N2O通量均与降水量呈显著的负相关,而CH4和CO通量与降水量呈显著的正相关;除草地CH4通量与土壤温度无显著相关、草地N2O通量与土壤温度呈显著负相关外,其余各温室气体通量与土壤温度均呈显著正相关.另外,城市草坪的草地和土壤CO2(R2为0.371和0.314)和N2O (R2为0.371和0.284)通量季节变化受降水量的影响要大于其它温室气体,而土壤温度对CO通量的影响(R2为0.290和0.234)要显著于其它温室气体. 相似文献
178.
报道了胡椒基丁醚生产中5-丙基-1,3-苯并二氧杂茂的氯甲基化的废水处理,该废水经蒸馏可回收94%的盐酸,此酸吸收氯化氢后浓度在36%以上,可再用于氯甲基化反应。蒸馏残液经分油、Fenton试剂处理和五次生炭柱吸附后CODCr等项指标均可国家二类污染物的一级排放标准。 相似文献
179.
几种重金属对紫背萍过氧化氢酶活性的影响 总被引:12,自引:0,他引:12
通过测定被暴露植物分解过氧化氢后放出氧气的体积,确定紫背萍过氧化氢酶(CAT)的活性。结果表明,紫背萍暴露在Hg、Pb、Cr、Ni、Fe的溶液中,其CAT活性除在Pb作用下明显降低外,在其它4种重金属的作用下都有不同程度的升高。这表明Pb对紫背萍 CAT活性有抑制作用,而其它4种重金属对紫背萍CAT均有刺激作用。紫背萍对5种重金属所表现出来的这种生态效应,是重金属水污染的植物潜在效应,植物的CAT 相似文献
180.
Klaassien J. Ganzeveld Annechien van Hagen Martin H. van Agteren Wim de Koning Anton J. M. Schoot Uiterkamp 《Journal of Cleaner Production》1999,7(6):690
Two types of fermented organic waste (trade and industry waste and fruit and vegetable waste) were successfully used as a sole carbon source to produce poly-3-hydroxybutyrate-co-valerate (PHBV) by Ralstonia eutrophus (formerly Alcaligenes eutrophus) via oxygen limitation.The production of PHBV could be optimized by optimizing the oxygen transfer through the fermentor. Thereby, a peak concentration of 1.1 g PHBV per liter cell suspension, 40 w% of cell dry weight, was obtained at an aeration rate of 0.24 mol O2/h·kg biomass. The yield of PHBV on the fatty acid concentration in the organic waste was 0.16 g polymer/g volatile organic matter. The process obtained, compares well with the commercial production process of PHBV based on glucose. 相似文献