等离子体技术在废旧塑料资源化中的应用

叙述了废旧塑料回收利用对环境的影响，介绍了废旧塑料资源化几种重要的方法及资源化中存在的问题，分析了等离子体技术在废旧塑料资源化中的特点及存在的问题，并提出了解决方法。     

Modification of Soy Protein Plastic with Functional Monomer with Reactive Extrusion

Chemical modification of soy protein with monomers such as maleic anhydride, glycidyl methacrylate and styrene was accomplished using reactive extrusion technology. Thermal and mechanical properties of the modified soy protein plastics were characterized with differential scanning calorimetry (DSC), a dynamic mechanical analyzer (DMA) and a United Testing System load frame. It was found that the denaturation temperature and the glass transition temperature of soy protein plastic changed. In addition, the tensile properties of modified soy protein plastic improved. Attenuated total reflection Fourier transform infrared (ATR-FTIR) and X-ray photoelectron spectroscopy (XPS) were used to characterize the structure of modified soy proteins. A suggestion of the interaction between soy protein and functional group in functional polymers is given. Through the in-situ interaction between the polymer and soy protein plastic, the mechanical properties of the soy protein plastic can be adjusted and controlled.     

基于强度折减与刚度退化小净距隧道围岩稳定性研究

运用刚度退化的基本原理和方法,将泊松比ν和弹性模量E进行调整,提出变刚度隧道围岩强度折减法。以某小净距隧道为例,在只调整ν或E、同时调整ν和E、保持ν和E不变4种情况下,探讨了刚度退化对小净距隧道围岩稳定性的影响。结果表明:ν对隧道拱顶下沉、拱底沉降、最大主应力的影响要强于E;隧道两拱脚向内位移随折减系数的增大而增大,内侧拱脚向内位移比外侧拱脚的要大,且在刚度调整时拱脚位移要比保持刚度不变时大;等效塑性应变随折减系数的增大而增大,刚度调整导致等效塑性应变区减小,考虑刚度退化推迟了中夹岩柱塑性区贯通;将变刚度隧道围岩强度折减法应用于小净距隧道工程围岩稳定性评价,可依据安全系数的大小来评判设计的合理性,为支护参数及施工技术的选用提供参考。     

断层影响下合理煤柱尺寸留设数值模拟分析

针对潘三矿1642(1)工作面回采受F24大型逆断层影响,利用FLAC3D软件研究留设不同尺寸断层煤柱情况下,应力场、位移场和塑性区演化规律,从而提出合理的断层煤柱留设尺寸。研究发现,随着煤柱的减小,应力集中区域逐渐向断层上盘转移;在断层影响下,顶板最大下沉位置发生在靠近断层一侧;当煤柱尺寸减小到一个临界值时,采空区上方塑性区发育高度会突然增大。留设合理的断层煤柱就是确保塑性区不与断层接触的情况下,尽量减小煤柱尺寸。     

天然气管道局部等效应力及塑性变形评估

为了研究腐蚀及地面运动对埋地天然气管线安全性的协同影响,以X80管道为研 究对象,模拟腐蚀缺陷及土壤力作用于管道之上,利用有限元方法对有腐蚀缺陷与预应 变情况下的管道局部等效应力及塑性变形进行评估,结果表明腐蚀缺陷的深度对局部应 力和应力分布影响非常明显,在失效压力预测中起着决定性作用。随着腐蚀深度的增加 ,应力集中增强,导致内表面和外表面的等效应力大小进一步分化,腐蚀深度的增加对 管道内表面的等效应力的影响很大,但对有效塑性应变的影响却不大。模拟管道上施加 有纵向应变的土壤力,不论拉伸与压缩的情况下,都会降低管道的失效压力,在施加拉 伸预应变下的管道失效压力小于压缩预应变下的。塑性变形首先发生在外表面处,并扩 展到腐蚀缺陷相邻区域,管道内表面也具有一定的塑性变形,但强度低。     

基于瓦斯抽采关键封孔参数及新型封孔材料应用研究

针对煤层瓦斯抽采封孔参数选取不合理,传统封孔材料封堵钻孔周边裂隙效果差等主要问题,采用数值模拟、实验室试验及工程实践等多种手段,分析不同封孔方式的漏气效果,研究封孔时效性对瓦斯抽采的影响,完成最优实验配比及性能测试,验证了现场瓦斯抽采效果。结果表明:全封孔方式抽采效果优于半封孔,合理控制封孔时效性,钻孔周边围岩破坏减少,封孔效果提高;正交试验确定材料最优配比即复合早强剂0.3%、复合缓凝剂0.5%、膨胀剂0.03%、水灰比1.2;试样周围充斥着交叉、贯通的“网状结构”钙矾石,且呈现多而密的粗棒状结构;材料具备塑性变形特性,持续变形量大;与矿方原封孔材料相比,新型封孔材料封孔后瓦斯抽采浓度提高193.3%,抽采周期明显延长,抽采效果显著提高。     

我国塑料包装废物的产生和回收特性及管理对策

通过现场调查和资料调研,分析了塑料包装废物的流向和环境特征,总结了塑料包装废物回收的基本特点和经验教训,论述了塑料包装废物回收模式特点,深入分析了回收过程中存在的问题,并提出了加强塑料包装废物回收的管理对策. 结果表明:塑料包装是塑料制品中的重要构成部分,由于质量轻、回收体积大,不易回收,我国每年产生大量的塑料包装废物,城市生活垃圾填埋场成为塑料包装废物的主要流向和污染源. 目前我国塑料包装废物回收依托的是进城务工的个体回收者,与现阶段的国情相符合. 塑料污染问题不是短期内能解决的,必须采取长期的综合管理对策,如进行源头减量化、制定鼓励回收利用的经济政策、采取适宜的无害化处置方式等.      

Mechanical Property and Biodegradability of Cast Films Prepared from Blends of Oppositely Charged Biopolymers

Biodegradable cast films of about 50 m thickness were fabricated by blending oppositely charged biopolymers such as anionic starch–chitosan, and cationic starch–pectin. The tensile strength and elongation at break (%) of films were evaluated as well as their capacity to degrade in compost. Films recovered from soil every 48 h showed consistent degradation (weight loss), diminution of the polymers characteristic peak absorbance in the carbohydrate fingerprint region of the FTIR, and changes in the surface morphology via scanning electron microscopy (SEM). Anionic starch–chitosan films had much superior tensile strength and elongation compared to cationic starch–pectin, suggesting that the ionic bonds formed between anionic-starch and positively charged groups in chitosan polymer were much more stable and stronger. Initially, both films lost about 36% weight within 96 h, which also correlated well with the loss in the characteristic absorption peaks in the region of the infrared spectrum typical of biopolymers. The total mineralization of films by microorganisms in compost soil was also measured using respirometric techniques. Though the rate of mineralization differed for two formulations, total mineralization (extent) for both films were achieved within 45 days.     

汽车塑料电镀手柄起泡原因探讨

B公司为某跨国汽公司车A公司提供的汽车用塑料电镀手柄,在墨西哥地区经过夏季炎热高温后,部分塑料手柄电镀层出现严重起泡现象.我们受A公司委托对样件和生产工艺过程中的一些物品做了相关试验和分析,初步查明了原因,及时解决了问题.     

废塑料催化裂解烟气中污染物分析与解决方案

以河南某公司研发的日处理2t废塑料的催化裂解中试装置以例,对催化裂解烟气中污染物进行了监测与分析,认为裂解烟气中主要污染物为氯化氢、氮氧化物、苯并芘、苯及颗粒物,并提出了采用碱吸收+电捕焦油器+活性炭吸附+脉冲袋式收尘的环保解决方案.