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841.
In this study, sulfuric acid and potassium hydroxide are used as the electrolytes, separated by proton exchange membrane, to produce hydrogen. The effects of electrolyte concentrations, applied voltage, single or dual cells, and temperature on the hydrogen production rate and energy efficiency are investigated. Experimental results show that the amount of hydrogen production increases with voltage, and the dual electrolytes and cells can yield the best hydrogen production rate and energy efficiency. With 1-M KOH plus 1-M H2SO4 as electrolytes in separated cells, the highest hydrogen production rate is about 0.95 L/hr. Results also show that the rise of electrolyte temperature can significantly increase the hydrogen production rate up to 50%, and the energy efficiency up to 20%. Keeping a low PH value in cathodeand high anode PH value in anode indeed enhances the efficiency of hydrogen production rate. 相似文献
842.
该文采用ABAQUS有限元软件建立了火灾后内配H型钢的矩形钢管混凝土柱模型,计算了常温下与火灾后该构件的轴向荷载-位移关系曲线,对火灾后的受力性能进行了分析;此外与相同含钢率的钢管混凝土柱构件火灾后剩余承载力进行了对比,发现内配型钢钢管混凝土柱剩余承载力较钢管混凝土柱得以增强,且构件延性优于钢管混凝土;同时对比了强、弱轴两种加载方式下该类构件火灾后剩余承载力,最后对影响火灾后该类构件剩余承载力的主要因素进行了参数分析,发现升温时间、截面周长和长细比对其影响较为显著。 相似文献
843.
844.
845.
To develop a depth filter based on the electrostatic adsorption principle, positively charged microporous ceramic membrane was prepared from a diatomaceous earth ceramic membrane.The internal surface of the highly porous ceramic membrane was coated with uniformly distributed electropositive nano-Y_2O_3 coating. The dye removal performance was evaluated through pressurized filtration tests using Titan Yellow aqueous solution. It showed that positively charged microporous ceramic membrane exhibited a flow rate of 421 L/(m~2·hr) under the trans-membrane pressure of 0.03 bar. Moreover it could effectively remove Titan Yellow with feed concentration of 10 mg/L between pH 3 to 8. The removal rate increased with the enhancement of the surface charge properties with a maximum rejection of 99.6%. This study provides a new and feasible method of removing organic dyes in wastewater. It is convinced that there will be a broad market for the application of charged ceramic membrane in the field of dye removal or recovery from industry wastewater. 相似文献
846.
S. Shiva Kumar S.U.B. Ramakrishna B. Rama Devi 《International Journal of Green Energy》2018,15(10):558-567
PEM water electrolysis is one of the most efficient methods for the production of hydrogen because of produced high purity of the gases and environmentally friendly. In the present study, Phosphorus-doped Graphene (PG) was synthesized by thermal annealing of triphenylphosphine (TPP) and graphene oxide (GO). The PG supported palladium (Pd/PG) electrocatalysts were synthesized by chemical reduction method and used as the cathode for hydrogen evolution reaction (HER) electrode. Structural properties and electrochemical performances of the synthesized Pd/PG electrocatalyst were studied by FE-SEM, EDS, ICP, FT-IR, XRD, and Cyclic voltammetry (CV) methods, respectively. The membrane electrode assemblies (MEA’s) were fabricated using Pd/PG as cathode for HER electrode and RuO2 as anode for OER electrode. Also, their electrochemical performances along with the corresponding hydrogen yields were evaluated in single cell PEM water electrolyzer at various experimental conditions such as different current densities from 0.1 to 2.0 A cm?2 and temperatures (28–80°C). The synthesized Pd/PG electrocatalyst was observed a current density of 1 A cm?2 with 1.95 V at 80°C. Further, long-term stability studies were carried out continuously up to 2000 h which showed a reasonable stability. Hence, the synthesized Pd/PG can be used as an alternative to Pt-based electrocatalysts for the HER in PEM water electrolysis. 相似文献
847.
Tatiana V. Komarova Michael E. Bartkow Steve Carter 《Environmental pollution (Barking, Essex : 1987)》2009,157(3):731-736
Semipermeable membrane devices (SPMDs) were deployed in water using four different methods: a typical SPMD cage with and without a mesh cover, a bowl chamber and without any protection. In addition to routinely used performance reference compounds (PRCs), perdeuterated dibenz[a,h]anthracene was added. Due to its high sampler to water partition coefficient no measurable clearance due to diffusion was expected during the deployment period, hence any observed loss could be attributed to photodegradation. The loss of PRCs was measured and SPMD-based water concentrations determined. Results showed that a typical SPMD deployment cage covered with mesh provided the best protection from photodegradation. Samplers which had undergone the highest photodegradation underestimated PAH water concentrations by up to a factor of 5 compared to the most protected SPMDs. This study demonstrates that the potential for photodegradation needs to be addressed when samplers are deployed in water of low turbidity. 相似文献
848.
反渗透与超滤及其在水处理中的应用 总被引:6,自引:0,他引:6
反渗透与超滤是水处理中广泛应用的膜分离技术,给水处理中反渗透应用较多,废水处理中超滤应用较广泛。 相似文献
849.
850.
以不同分子量聚乙二醇 (PEG)作为PSf/A共混超滤膜的添加剂 ,测定所制备膜的水通量、截留率 .结果表明 ,膜的水通量随PEG分子量的变化呈现非线性关系 .当PEG分子量为4000时 ,水通量达到最大值115.2mL·(cm2·h)-1,是不加PEG时的6倍 .通过超滤实验结果以及膜结构的电镜照片的观察 ,研究了PSf/A共混超滤膜体系中PEG作用的规律 .PEG分子量的增加改变了PSf/A铸膜液体系的相平衡关系 ,使铸膜液成为热力学不稳定体系 ,加速了相分离的发生 ;另外 ,PEG分子量的增加提高了铸膜液的粘度 ,引起相分离的延迟,这2种作用影响了膜的最终结构和性能. 相似文献