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121.
The graft copolymerization of the starch and acrylic were used to prepare the superabsorbent, and the high oil-absorbing resin was also studied preliminarily. In addition, following the method of the emulsion polymerization, the cerium nitrate amine was regarded as the initiator, the acrylic amide and the methyl methacrylate functioned as the monomer. There are several significant parameters taken into consideration such as the factors that influence the performance of the superabsorbent and the high oil-absorbing resin, the dosage of the initiator amount, the ratio of the starch and the monomer and the dosage of crosslinking agent. 相似文献
122.
Jurkka Kuusipalo 《Journal of Polymers and the Environment》2001,9(3):125-135
The starch-based polymers exhibited shear thinning and elastic nature in rheological characterizations. Thin coatings with narrow neck-in could be produced at fairly high extrusion coating line speeds. Adhesion between the starch-based polymers and paperboard was typically weak. Water vapor barrier of starches was very poor. Soft starch grades had a good pinhole resistance and a good heat sealing performance. Brittle nature of starch caused cracking as the coated paperboards were creased. 相似文献
123.
采用生命周期分析方法,以1 000 L甘薯乙醇为单位功能单元,将甘薯乙醇生产体系分成作物种植、原料运输和乙醇转换等3个单元,对其生命周期能耗与环境排放进行清单分析和影响评价,比较习惯施肥与测土配方施肥下甘薯乙醇生命周期9类环境影响潜力的差异。结果表明:两种施肥模式下甘薯乙醇生产体系的生命周期能源效率分别为1.41和1.43。习惯施肥模式下甘薯乙醇生命周期主要环境影响类型包括人体毒性、富营养化、酸化、淡水生态毒性、能耗和全球变暖,其环境影响潜力分别相当于2000年世界人均影响潜力的40%、40%、31%、29%、25%和20%。测土配方施肥降低了化学氮肥和磷肥使用量,提高了肥料利用效率和甘薯单产,使富营养化、淡水生态毒性、酸化和全球变暖潜力分别降低了31%、15%、9%和7%。可见,测土配方施肥模式可改善甘薯乙醇生命周期的能源效率并显著缓解其负面环境影响。 相似文献
124.
125.
Dae-lyoung Lim Seung-soon Im Jeong-seok Han Sang-hyun Yim Jin-sung Kim Young-mok Lee 《Journal of Polymers and the Environment》1997,5(4):191-197
Extrusion with an intermeshing corotating twin-screw extruder with a limited amount of water caused structural changes in
corn starch. The structural changes resulted in a transformation-from a semicrystalline to an amorphous state and the development
of orientation of molecular chains in the amorphous region during extrusion. These structural changes, in turn, caused an
increase in theT
g, tensile strength, and resilience of the extruded corn starch. Our experimental results showed that the tensile properties
and resilience of the expanded corn starch extruded at 240‡C were the best: tensile strength, 1.7 kPa; tensile modulus, 40.4
kPa; and resilience, 57.2%. Extrusion produced an expanded corn starch suitable for protective loose-fill. 相似文献
126.
Ranjith Jayasekara Ian Harding Ian Bowater Gregor B. Y. Christie Greg T. Lonergan 《Journal of Polymers and the Environment》2003,11(2):49-56
Several starch/PVA/glycerol polymer blends were prepared by a solution casting technique and examined for biodegradation by composting over 45 days. Within this time frame, the starch and glycerol components were fully degraded, leaving the PVA component essentially intact. The lowest PVA content film (20%) was selected as a polymer with enough PVA to impart important physical characteristics, but also enough starch to be considered biodegradable. The film characteristics were further improved by surface modification with chitosan. This modification did not interfere with the biodegradation of the starch component. Furthermore, there was slight evidence that PVA biodegradation had been initiated in composted, surface modified starch/PVA blends. 相似文献
127.
Photodegradation and Biodegradation Study of a Starch and Poly(Lactic Acid) Coextruded Material 总被引:1,自引:0,他引:1
Alain Copinet Céline Bertrand Antoine Longieras Veronique Coma Yves Couturier 《Journal of Polymers and the Environment》2003,11(4):169-179
To simulate the behavior of agricultural mulch coextruded poly(lactic acid)(PLA)/starch films, two stages were carried out. The first was an ultraviolet treatment (UV) at 315 nm, during which glass transition temperature Tg, weight, and molecular weight (MW) decreased and a separation between PLA and starch phase was observed. For the second stage, the mineralization of the carbon of the material was followed using the ASTM (D 5209–92 and 5338–92) and ISO/CEN (14852 and 14855) standard procedures. To measure the biodegradability of polymer material, the assessment of the carbon balance allowed determination of the distribution between the carbon rate used to the biomass synthesis or the respiration process (released CO2), as well as the dissolved organic carbon into the culture medium and the carbon in the residual insoluble material. The influence of the nature of the medium and the standardized procedures on the final rate of biodegradation was investigated. Whatever the standardized method, the biodegradation percentage was significantly stronger in liquid medium (92.4–93.4) than on inert medium (80–83%). In the case of the compost process, only released CO2 was measured and corresponded to 79.1–80.3%. 相似文献
128.
Vincent T. Breslin 《Journal of Polymers and the Environment》1993,1(2):127-141
The rate and extent of deterioration of starch-plastic composites were determined over a 2-year period for samples buried in a municipal solid waste landfill. The deterioration of the starch-plastic composites following exposure was determined by measuring changes in tensile properties, weight loss, and starch content of samples retrieved from the landfill. Elongation decreases of 92 and 44% were measured for starch-plastic composite LDPE and LLDPE films, respectively, while elongation decreases of 54 and 21% were measured for their corresponding control films following 2 years of burial. Starch loss of 25% for LLDPE and 33% for LDPE starch-plastic composite films was measured following 2 years of landfill burial. Starch-plastic composites did not fragment or lose mass during the 2-year landfill burial. The limited degradation observed for the starch-plastic composites was attributed to the ineffectiveness of the prooxidant additive to catalyze the thermal oxidation of the polyethylene or polypropylene component of the starch-plastic composite under the environmental conditions present within the landfill. 相似文献
129.
C. L. Swanson R. L. Shogren G. F. Fanta S. H. Imam 《Journal of Polymers and the Environment》1993,1(2):155-166
Recent starch-plastic research at the National Center for Agricultural Utilization Research is reviewed and related worldwide efforts are noted. Properties of starch that influence its formulation and performance in plastics are discussed. Methods are given for preparation of starch-poly(methyl acrylate) graft copolymer, starch-poly(ethylene-co-acrylic acid), and starch-poly(ethylene-co-acrylic acid)-polyethylene plastics. Their physical properties are discussed, as is degradability by enzymes or amylolytic organisms from soil, ponds, and streams.The mention of firm names or trade products does not imply that they are endorsed or recommended by the U.S. Department of Agriculture over other firms or similar products not mentioned. 相似文献
130.
马铃薯糖苷生物碱的生物学作用及开发利用 总被引:12,自引:0,他引:12
本文根据作者近年的研究成果及国外研究动态,简要介绍了马铃薯糖苷生物碱的种类,结构,含量及在植株中的分布;重点论述了糖苷生物碱的毒性,毒理及对块茎食用、饲用和加工品质的影响,糖苷生物碱与马铃薯植株自身的抗病,抗虫性及其抗病虫育种的关系,以及糖苷生物碱在医药学中的应用价值,为马铃薯的综合开发利用指出了新途径。 相似文献