全文获取类型
收费全文 | 3910篇 |
免费 | 509篇 |
国内免费 | 2636篇 |
专业分类
安全科学 | 308篇 |
废物处理 | 134篇 |
环保管理 | 404篇 |
综合类 | 4295篇 |
基础理论 | 744篇 |
污染及防治 | 723篇 |
评价与监测 | 280篇 |
社会与环境 | 128篇 |
灾害及防治 | 39篇 |
出版年
2024年 | 35篇 |
2023年 | 135篇 |
2022年 | 263篇 |
2021年 | 310篇 |
2020年 | 276篇 |
2019年 | 268篇 |
2018年 | 235篇 |
2017年 | 247篇 |
2016年 | 289篇 |
2015年 | 336篇 |
2014年 | 403篇 |
2013年 | 444篇 |
2012年 | 468篇 |
2011年 | 487篇 |
2010年 | 348篇 |
2009年 | 339篇 |
2008年 | 261篇 |
2007年 | 358篇 |
2006年 | 313篇 |
2005年 | 218篇 |
2004年 | 187篇 |
2003年 | 153篇 |
2002年 | 117篇 |
2001年 | 110篇 |
2000年 | 80篇 |
1999年 | 66篇 |
1998年 | 40篇 |
1997年 | 41篇 |
1996年 | 32篇 |
1995年 | 32篇 |
1994年 | 32篇 |
1993年 | 19篇 |
1992年 | 14篇 |
1991年 | 25篇 |
1990年 | 12篇 |
1989年 | 10篇 |
1988年 | 6篇 |
1987年 | 10篇 |
1986年 | 4篇 |
1983年 | 3篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1976年 | 2篇 |
1974年 | 2篇 |
1973年 | 2篇 |
1972年 | 2篇 |
1971年 | 2篇 |
1970年 | 2篇 |
排序方式: 共有7055条查询结果,搜索用时 15 毫秒
231.
安徽省升金湖湿地土壤有机碳储存及分布 总被引:7,自引:0,他引:7
文章研究了安徽省升金湖湿地土壤有机碳储存和分布特征及其与土壤氮素的关系。结果表明,供试湿地土壤全土1m深有机碳密度达10.82±1.90kg.m-2,表层土壤(0—30cm)有机碳密度为5.19±0.68kg.m-2,高于报道的人工湿地——水稻土的碳密度;有机碳(SOC)含量分布随土壤深度(H)的递降符合幂函数方程,湿地土壤有机碳的表层积累强度和积累深度高于稻田;湿地土壤氮素是土壤固碳的有利因子,其氮素对土壤有机碳积累的效应高于水稻土;因湖泊沉积受河流动力学、土壤水分和植物生长条件的影响,湿地土壤有机碳含量存在显著的水平空间变异性。看来,长江中下游淡水湿地在陆地生态系统碳氮储存上具有重要意义。 相似文献
232.
底泥中营养物质及其他污染物释放机理综述 总被引:8,自引:0,他引:8
水体底泥(沉积物)污染,是世界范围内的一个重要环境问题.其污染物主要通过大气沉降、废水排放、水土流失、雨水淋溶与冲刷进入水体,最后沉积到底泥中并逐渐富集,使底泥受到严重污染.总结了底泥中氨氮、重金属的影响因素及释放机理,也指明了持久性有机污染物释放机理研究不足的现状,提出对其释放机理研究的重要性. 相似文献
233.
NH3-N在大连湾的水环境行为模拟研究 总被引:2,自引:0,他引:2
应用三维水质模型对大连湾中的主要污染物NH3-N的行为进行了模拟,对NH3-N浓度的时空变化规律以及其影响因素进行了研究,选择主要的模型参数进行了灵敏度分析。由空间分布的模拟结果可知,在大连湾,NH3-N浓度主要集中在排污口附近区域,灵敏度分析显示,在排污口区水体的扩散能力对NH3-N浓度的影响较大。由季节变化模拟结果可知,在湾顶部的排污口区NH3-N浓度显示明显的季节变化趋势。在湾中部和朝海边界的湾口区NH3-N浓度较低,变化平缓。模拟结果可以为大连湾的污染控制、水质规划和管理提供科学依据。 相似文献
234.
采用实验室压缩气体泡沫系统,通过缩尺油盘火试验,分别考察基于不同气源的压缩气体泡沫对于石油醚火灾的灭火性能,分析探讨适用于低沸点的石油醚类燃料火灾扑救的气源类型和供气方案。结果表明,在泡沫溶液供给强度为2.5 L/(min·m2)的条件下,压缩氮气泡沫和压缩空气泡沫均可扑灭石油醚火灾,具有良好的抗烧性能;二者相比,压缩氮气泡沫比压缩空气泡沫的控灭火性能和抗烧性能均有一定提升;对于石油醚类的低沸点易燃液体火灾,建议采用以氮气作为气源的压缩氮气泡沫系统;该研究可为压缩气体泡沫系统在石油化工行业工程应用提供技术支撑。 相似文献
235.
低温液氮与泡沫混合液直接接触产生氮气泡沫是一种新型的掺混形式,利用液氮高汽化比的特点,搭建液氮泡沫可视化实验装置,进行氮气-水两相流及液氮泡沫流动特性的研究。结果表明,液氮相变产生大量氮气,其与泡沫液混合产生泡沫,温度有所回升,最终趋于泡沫混合液温度;管路沿程压降较小;液氮射流破碎及流动过程可分为6个区域:低温液氮区、向上循环翻滚区、滞留区、泡沫与泡沫混合液混合区、致密泡沫区、泡沫混合液区。流体向下游流动过程中持续发泡;为防止管路结冰,需合理控制泡沫混合液与液氮流量。 相似文献
236.
Many release problems involve two-phase releases of hazardous materials of superheated liquids with high energy into the atmosphere. Such accidents are accompanied by violent phase transition and form catastrophic flashing jets. In this work, experimental and theoretical analyses were conducted to investigate dynamic characteristics of flashing jet morphology and their dependence on pressure-decay dynamics under different storage pressures, superheats, and nozzle diameters. Flashing jet morphology and angle throughout two-phase releases were captured by a high-speed camera, and the corresponding source pressure in the superheated liquid tank was measured simultaneously. Results show that three typical phases, expansion, stabilization, and decay, are characterized throughout two-phase release based on the evolution of flashing jet morphology. The jet initially expands gradually due to the enhancement of phase transition intensity, and then keeps stable when the intensity reaches its maximum, and terminally decays rapidly due to the depletion of superheated liquid. Phase transition intensity at the nozzle exit is mainly controlled by the pressure-decay dynamics. Bubbles nucleation inception sites gradually move upstream of the nozzle during the pressure decay process increasing the phase transition intensity. The increase of storage pressure, superheat and nozzle diameter promotes the mechanical and thermodynamic effects on the jet breakup. The significant increase of mechanical and thermodynamic effects effectively accelerates droplets evaporation and further affects flashing jet morphology. 相似文献
237.
In recent years, significant progress has been made to ensure that process industries are among the safest workplaces in the world. However, with the increasing complexity of existing technologies and new problems brought about by emerging technologies, a strong need still exists to study the fundamentals of process safety and predict possible scenarios. This is attained by conducting the corresponding consequence modeling and risk assessments. As a result of the continuous advancement of Computational Fluid Dynamics (CFD) tools and exponentially increased computation capabilities along with better understandings of the underlying physics, CFD simulations have been applied widely in the areas of process safety and loss prevention to gain new insights, improve existing models, and assess new hazardous scenarios. In this review, 126 papers from 2010 to 2020 have been included in order to systematically categorize and summarize recent applications of CFD for fires, explosions, dispersions of flammable and toxic materials from accidental releases, incident investigations and reconstructions, and other areas of process safety. The advantages of CFD modeling are discussed and the future of CFD applications in this research area is outlined. 相似文献
238.
AbstractThe roles of PM2.5-induced mitochondrial damage and oxidative stress on mast cell degranulation were examined in vitro. Mast cells were treated with suspensions of PM2.5 in Dulbecco’s modified Eagle’s medium at concentrations from 25 to 200?mg/L in the absence or presence of 10?mmol/L N-acetyl-L-cysteine. Biological effects and mitochondrial function were assessed by determining cell viability, β-hexosaminidase release, interleukin-4 secretion, reactive oxygen species generation, adenosine triphosphate production, potential alteration of mitochondrial membrane, and activities of mitochondrial electron transport chain complexes I and III. Exposure of mast cells to PM2.5 induced reduction of adenosine triphosphate production, collapse of mitochondrial membrane potential, and inhibition of the activity of complex III. Co-treatment of mast cells exposed to PM2.5 with N-acetyl-L-cysteine attenuated cytotoxicity and the production of reactive oxygen species, and decreased the release of β-hexosaminidase and interleukin-4. Evidently, PM2.5-induced oxidative stress plays an essential role in mitochondrial toxicity and mast cell activation. 相似文献
239.
植物根系分解是养分元素进入土壤的重要途径之一.为了解径级对根系分解过程中养分元素释放的潜在影响,以川西亚高山针叶林中的粗枝云杉(Picea asperata)为对象,采用原位分解试验,研究云杉3个径级(0-2 mm,2-5 mm和5-10 mm)根系分解过程中钾(K)、钠(Na)、钙(Ca)和镁(Mg)元素的浓度、残留... 相似文献
240.
Using Ion-Exchange Resins to Study Soil Response to Experimental Watershed Acidification 总被引:1,自引:0,他引:1
Szillery JE Fernandez IJ Norton SA Rustad LE White AS 《Environmental monitoring and assessment》2006,116(1-3):383-398
Ion-exchange resins (IER) offer alternative approaches to measuring ionic movement in soils that may have advantages over
traditional approaches in some settings, but more information is needed to understand how IER compare with traditional methods
of measurement in forested ecosystems. At the Bear Brook Watershed in Maine (BBWM), one of two paired, forested watersheds
is treated bi-monthly with S and N (28.8 and 25.2kgha−1yr−1 of S and N, respectively). Both IER and ceramic cup tension lysimeters were used to study soil solution responses after ∼11
years of treatment. Results from both methods showed treatments resulted in the mobilization of base cations and Al, and higher
SO4—S and inorganic N in the treated watershed. Both methods indicated similar differences in results associated with forest
type (hardwoods versus softwoods), a result of differences in litter quality and atmospheric aerosol interception capacity.
The correlation between lysimeter and IER data for individual analytes varied greatly. Significant correlations were evident
for Na (r=0.75), Al (r=0.65), Mn (r=0.61), Fe (r=0.57), Ca (r=0.49), K (r=0.41) and NO3—N (r=0.59). No correlation was evident between IER and soil solution data for NH4—N and Pb. Both IER and soil solution techniques suggested similar interpretations of biogeochemical behavior in the watershed. 相似文献