Relation between mechanochemical dechlorination rate of polyvinyl chloride and mill power consumption

A sample of polyvinyl chloride (PVC) powder was milled with CaO powder in a planetary mill for various mill operational parameters. The milled product consisted of dechlorinated hydrocarbon and water-soluble CaOHCl. The dechlorination rate of PVC was determined by the concentration of Cl⁻ ions measured in solution after dispersing the milled product in water. To evaluate the power consumption during PVC dechlorination, the mill power consumption was measured during each experimental run. In addition, media motion during planetary milling was simulated using the discrete element method (DEM), enabling calculation of the mill power consumption. The power consumption calculated by the DEM simulation compared well with the power consumption measured experimentally. The dechlorination rate correlated well with the specific mill power consumption, regardless of the sample weight. The dechlorination rate of PVC when milled with oyster shells (CaCO₃) was observed to be faster than that of the PVC/CaO system, and oyster shells could be used as a reactant for the treatment of PVC wastes. This work should be useful for the design of a reactor for the dechlorination of PVC. Chemical Feedstock Recycling & Other Innovative Recycling Techniques 6     

生物质能源发展的市场环境培育分析——以湖北省为例

生物质能源作为可再生能源的重要组成部分,其在替代能源、环境保护、减少碳排放,促进农民增效方面具有重要作用。以资源贫乏、能源短缺的湖北省作为生物质能源发展市场环境培育分析的研究对象,具有一定的代表性。通过深入分析生物质能源原料市场、产品市场、技术市场的发展现状,得知生物质能源发展的政策法规不完善、市场保障机制体系不健全、公众能源意识淡薄、投融资体制不顺畅、技术研发创新难是制约其产业发展的主要因素。因此对生物质能源发展的市场环境培育提出3方面建议：在政策法规层面,政府需要制定保护性政策来调控市场,以弥补市场力量的不足,并界定好生物质能源产业的发展方向;在监管体系层面,需要设立严格的生物质能源市场准入门槛和有效的定价机制,防止生物质能源过度发展;在企业经营层面,实施生物质能源企业集群带动战略,提升核心竞争力。     

金属改性碳脱除PH3和H2S动力学及反应机理研究

为综合利用黄磷尾气中的CO,通过计算平均活化能和测定XPS、TG/DTA和氮吸附特性的方法,研究了Cu²⁺和某金属离子Mn⁺改性碳脱除PH₃和H₂S的动力学和反应机理问题。结果表明：H₂S在金属改性碳上反应时平均活化能为134.4 J/mol为-0.76级反应,PH₃在金属改性碳上反应时平均活化能为1 247.6 J/mol为-0.8级反应;减小改性碳粒径增加流量可以显著提高其脱除PH₃和H₂S的速率;XPS、TG/DTA和孔径分布分析证明,改性碳净化H₂S和PH₃是一个催化吸附过程,H₂S和PH₃首先与氧在改性碳表面进行催化氧化反应,然后生成S和P₂O₅沉积吸附在改性碳表面。     

Effect of impeller type and mechanical agitation on the mass transfer and power consumption aspects of ASBR operation treating synthetic wastewater

The effect of flow type and rotor speed was investigated in a round-bottom reactor with 5 L useful volume containing 2.0 L of granular biomass. The reactor treated 2.0 L of synthetic wastewater with a concentration of 800 mgCOD/L in 8-h cycles at 30 degrees C. Five impellers, commonly used in biological processes, have been employed to this end, namely: a turbine and a paddle impeller with six-vertical-flat-blades, a turbine and a paddle impeller with six-45 degrees -inclined-flat-blades and a three-blade-helix impeller. Results showed that altering impeller type and rotor speed did not significantly affect system stability and performance. Average organic matter removal efficiency was about 84% for filtered samples, total volatile acids concentration was below 20 mgHAc/L and bicarbonate alkalinity a little less than 400 mgCaCO3/L for most of the investigated conditions. However, analysis of the first-order kinetic model constants showed that alteration in rotor speed resulted in an increase in the values of the kinetic constants (for instance, from 0.57 h(-1) at 50 rpm to 0.84 h(-1) at 75 rpm when the paddle impeller with six-45 degrees -inclined-flat-blades was used) and that axial flow in mechanically stirred reactors is preferable over radial-flow when the vertical-flat-blade impeller is compared to the inclined-flat-blade impeller (for instance at 75 rpm, from 0.52 h(-1) with the six-flat-blade-paddle impeller to 0.84 h(-1) with the six-45 degrees -inclined-flat-blade-paddle impeller), demonstrating that there is a rotor speed and an impeller type that maximize solid-liquid mass transfer in the reaction medium. Furthermore, power consumption studies in this reduced reactor volume showed that no high power transfer is required to improve mass transfer (less than 0.6 kW/10(3)m3).     

泥石流滩地农业资源化开发与利用——以蒋家沟为例

泥石流滩地是山区宝贵的土地资源,其农业资源化开发与利用对促进当地社会经济发展和生态环境改善具有重要意义。以蒋家沟流域为例,在野外调查、遥感解译和实验分析的基础上,阐述了泥石流滩地农业资源化的原则和依据,建立了人畜 土地载荷平衡模型,分析了滩地开发利用的依据、效益和途径,并探讨了泥石流滩地未来农业资源化的思路和对策。研究结果表明：（1） 建立的人畜 土地载荷平衡模型反映了流域生态环境特征,能有效评价滩地开发利用的生态效益;（2）流域滩地农业资源化每年可产生500多万元的经济效益,除满足全流域6 418人的粮食需求外,还可提供338 t商品粮,是促进当地脱贫致富和社会经济发展的重要途径;（3）泥石流滩地既是宝贵的土地资源又是灾害的场所,其开发与利用可有效缓解山区人地矛盾,具有良好的生态效益,但需要在加强灾害防治和防灾减灾意识的基础上,进行深度农业资源化开发.     

水资源价值理论研究进展与展望

水资源价值理论是价值核算的基础,在水资源价值研究中举足轻重。水资源价值研究是在对传统自然资源价值观反思的基础上开展起来的,伴随着现代经济的迅速发展,人们已认识到传统的价值观念难以适应现代化经济发展的需要,水资源价值理念必须进行重新认识并加以完善。旨在分析水资源价值理论的研究进展,提出未来发展的方向,给水资源价值理论研究以启示。首先分析了水资源价值的构成和内涵,指出水资源价值是经济、社会、生态环境价值的统一;接着详细介绍了各价值论的主要观点,并分析提出了目前存在的主要问题;最后在展望部分从生态经济学角度出发,将能值价值论引入水资源价值研究中,提出水资源能值价值理论的想法,以期为水资源价值评估提供有启发意义的思路与方法。     

长江流域能源利用效率研究

考察长江流域四川、重庆、湖南、湖北 、江西、安徽、浙江、江苏、上海七省二市能源利用效率,比较分析其差异以及原因,寻求提高能源利用效率的途径。首先定义能源利用效率为能源通过要素优化配置产生的技术效率,然后利用数据包络DEA和全要素效率SFA方法进行测度,最后通过比较拉氏指数与迪氏指数的优劣,采用迪氏指数法对能源利用效率影响因素进行分解。计算出七省二市及六部门1997~2006年GDP能耗、能源技术效率和能源利用效率,并分析了结构调整、技术进步和制度进化对能源效率的影响程度。研究表明：（1）结构调整是提高能源利用效率的有力措施;（2）技术进步和制度进化是提高能源利用效率的关键;（3）能源利用效率研究方法应尽量统一并不断改进.     

Elasticity Ratio of Resource Consumption and the Resource Consumption

Today the resources are becoming scarcer, which should not be regarded as unexhausted any more. Correspondingly, the production would be constrained by the scarcity of resources clearly. Then the economic researchers would pay much more attention to reducing the consumption of natural resources in the future. Therefore this paper brings foreword the conception of elasticity ratio of resource consumption based on the concept of elasticity and analyzes the relationship between the parameters. For the certain relationships between the elasticity ratio of resource consumption and resource consumption, this paper will try to reveal, to keep economy growing while resource consumption reducing, what conditions should be met as to the relationships among resource productivity, its growth rate, energy saving efficiency, economic growth rate and elasticity ratio of resource consumption. This paper proves the relationship between the China＇s energy consumption and economy growth using statistic data from 1978 to 2003.     

Recycling and Reusing Heat Energy During the Production of Powdery Phospholipid

The temperature is 56.5℃when acetone gas is rectified during the production of powdery phospholipid. If heat exchanger is added, heat energy that is reclaimed can be used by other heaters. On the basis of exchange hot water （51℃） 4m3 every minute, a factory with the productivity of powdery phospholipid being 10 ton a day can save 533.2 ton standard coal which is equivalent to 746.48 ton common coal. If this technique of saving energy and reducing emission could be widely used in correlative industries of all over the country, economic benefits will be prominent.