氨/硫铵法烟气脱硫技术特点及市场前景分析

通过对我国二氧化硫污染现状及控制要求的分析,提出了氨/硫铵法作为一种资源回收型脱硫方法,具有反应速度快、工艺流程简单、吸收剂利用率高、适用范围广及可实现资源回收利用的特点;以工程案例的形式分析了氨/硫铵法的技术经济指标,并对氨/硫铵法的应用前景和市场需求进行了预测。     

无汞开管法快速测定工业废水中的COD

文章对化学需氧量的几种测定方法进行对比,研究了无汞开管法快速测定方法的实验条件与干扰因素,并与标准方法进行对照,总结出炼油废水应用无汞开管法监测COD的适用范围与注意事项,可供同类企业应用该方法时借鉴。     

中原油田开展清洁生产工作的几点体会

中原油田自2008年以来全面推行清洁生产工作,取得了丰硕的成果。文章结合中原油田实施清洁生产的实际,论述了中原油田有效开展清洁生产审核、建立清洁生产长效机制的一些经验和实际做法。中原油田经过努力,油区环境质量得到改善,为构建资源节约型、环境友好型企业奠定了基础。     

海上平台采油工艺设计浅析

文章通过实例,简要阐述了滩海、浅海、深海三种开发模式的特点、主要工艺及其适用性。指出各自存在的问题,并提出相应的建议,为海上勘探开发提供借鉴。     

唐山排污权交易模式浅析

对开展排污权交易的目的、意义、关键因素进行了分析,对唐山排污权交易的工作进程以及交易指标、交易主体、交易程序、指导价格、申购数量、交易范围、优先及限制条件等模式特点进行了阐述,以期为同类型城市开展排污权交易提供参考。     

秦皇岛市“创模”对策研究及效益分析

介绍了秦皇岛市创建国家环境保护模范城市的意义,重点阐述了完成创模任务的主要对策,包括:构建以旅游业为中心、特色产业互融互促的现代产业体系;加快城乡一体化建设;提升城镇发展质量和水平;加强重大基础设施建设;积极推广清洁能源,深入开展工程节能;积极推进循环经济发展等。秦皇岛市创建国家环境保护模范城市,将会在环境、经济和社会三方面产生明显的综合效益。     

Treatment of coking wastewater by an advanced Fenton oxidation process using iron powder and hydrogen peroxide

In this study the treatment of coking wastewater was investigated by an advanced Fenton oxidation process using iron powder and hydrogen peroxide. Particular attention was paid to the effect of initial pH, dosage of H₂O₂ and to improvement in biodegradation. The results showed that higher COD and total phenol removal rates were achieved with a decrease in initial pH and an increase in H₂O₂ dosage. At an initial pH of less than 6.5 and H₂O₂ concentration of 0.3 M, COD removal reached 44-50% and approximately 95% of total phenol removal was achieved at a reaction time of 1 h. The oxygen uptake rate of the effluent measured at a reaction time of 1 h increased by approximately 65% compared to that of the raw coking wastewater. This indicated that biodegradation of the coking wastewater was significantly improved. Several organic compounds, including bifuran, quinoline, resorcinol and benzofuranol were removed completely as determined by GC-MS analysis. The advanced Fenton oxidation process is an effective pretreatment method for the removal of organic pollutants from coking wastewater. This process increases biodegradation, and may be combined with a classical biological process to achieve effluent of high quality.     

Whole effluent toxicity assessment at a wastewater treatment plant upgraded with a full-scale post-ozonation using aquatic key species

Ozonation as final wastewater (WW) polishing step, following conventional activated sludge treatment is increasingly implemented in sewage treatment for contaminant degradation to prevent surface water pollution. While the oxidative degradation of chemicals has been extensively investigated, the in vivo toxicological characteristics of ozonated whole effluents are rarely a matter of research.In the present study, whole effluents were toxicologically evaluated with an in vivo test battery before and after full-scale ozonation and subsequent sand filtration on site at a treatment plant. One aquatic plant (duckweed, Lemna minor) and five invertebrate species of different systematic groups (Lumbriculus variegatus, Chironomus riparius, Potamopyrgus antipodarum, Daphnia magna) were exposed to the effluents in a flow-through-designed test system with a test duration of 7-28 d.None of the considered toxicity endpoints correlated with the pollutant elimination. A tendency towards an increased toxicity after ozonation was apparent in three of the test systems showing [statistically] significant adverse effects in the L. variegatus toxicity test (decrease in reproduction and biomass). After sand filtration, adverse effects were reduced to a similar level like after conventional treatment. Solely the Daphnia reproduction test revealed beneficial effects after ozonation in combination with sand filtration.Results of the test battery indicate the formation of adverse oxidation products during WW ozonation. L. variegatus appeared to be the most sensitive of the five test species. Sand filtration effectively removes or detoxifies toxic oxidation products, as toxic effects were subsequently reduced to the level after conventional treatment.     

响应面法优化超临界水氧化处理农药废水

在间歇式超临界水氧化系统中对草甘膦农药废水进行降解实验。选取温度、反应时间、过氧量3个量为因素量,总有机碳(TOC)去除率为响应量进行中心组合设计（CCD）。在实验的基础上,利用响应面分析法（RSM）对实验结果进行分析及参数优化：建立了TOC去除率与各个因素关系的二次多项式数学模型;分析了各个因素单独的及相互作用对TOC去除率的影响;优化结果表明,在温度483℃、反应时间29.2 min、过氧量148.4%的条件下,达到了最佳效果,此时TOC的去除率为100%。     

利用二维表对活性污泥工艺模拟时的流量进行平衡的方法

多点进水和多重回流成为提高活性污泥工艺去除污染物能力的常用方法,这导致活性污泥工艺流程较为复杂。对工艺进行模拟计算时,由于模拟池体数量比实际池体数量更多,流量平衡较为困难。根据工艺流程特征提出了主流线、副流线等概念,结合流量分配比、循环流量等参数,利用二维表进行流量平衡计算,简捷明了,便于检验,大大提高了进行流量平衡的准确性和效率。