密封充氢环境条件下固态电化学氢气传感器效应试验研究

目的研究密闭充氢环境下固态电化学氢气传感器效应。方法设计能模拟低氧、低氢和压力变化的密闭充氢环境,并在此环境中进行一系列氢气传感器效应试验,分析、评定试验数据。结果得到了不同环境下氢气、氧气浓度随时间变化的规律,提出固态电化学氢气传感器的有效工作环境,并预测了其在不同贮存环境下的工作寿命。结论密闭充氢环境内压力和温度的变化对固态电化学氢气传感器影响较大,湿度影响较小,注气检定合格的氢气传感器,在密封容器内扩散式检定,不合格率高,检定数据误差大于±5%FS。     

Research on whole life cycle carbon emission model of typical buildings

Based on the theory of life cycle assessment (LCA), this article analyzes the influence factors on carbon emissions from residential buildings. In the article, the life cycle of residential buildings has been divided into five stages: building materials production period, construction period, operation and maintenance period, demolition period, and solid waste recycle and disposal period. Based on this definition, the authors provide a theoretical model to calculate carbon emissions of residential building life cycle. In particular, the factor of human activities was introduced in the calculation of carbon emissions from the buildings. Furthermore, the authors put forward a model for calculation with the unit of carbon emissions for per-capita living space.     

蒙脱土原位生长MoS2复合材料光催化降解罗丹明B的机理研究

通过在Na⁺-MMT表面生长MoS₂来提高窄带隙半导体光生电子分离速率及稳定性.利用阳离子填充法及水热法成功制备了复合光催化剂Na⁺-MMT/MoS₂,并通过FT-IR、SEM、TEM、Raman、XRD、TG、XPS、UV-DRS和ESR等表征进一步证明了材料的成功负载及光、电化学性能. 同时,以有机染料罗丹明B为待降解染料来评价光催化剂的催化性能,发现其在80 min可有效降解罗丹明B,降解率达96%.经过5次循环使用后,Na⁺-MMT/MoS₂复合光催化剂仍具有较好的光催化性能.因此,利用MMT的表面电负性及稳定的片层结构负载MoS₂,可形成光生电子迁移通道进一步提高电荷迁移速率及光催化剂的稳定性.本研究可为黏土材料调控窄带隙半导体制备环境友好型光催化剂提供新思路.     

Transitions of municipal solid waste management. Part II: Hybrid life cycle assessment of Swiss glass-packaging disposal

In policy support of municipal solid waste (MSW) management, life cycle assessment (LCA) can serve to compare the environmental or economic impacts of two or more options for waste processing. The scope of waste management LCAs generally focuses less attention on future developments, e.g., where will recycling take place, and more on the environmental performance of prototypes, e.g., the incineration of all waste compared to recycling. To provide more robust support for Swiss waste glass-packaging disposal, scenarios of Swiss waste glass-packaging are assessed from a life cycle perspective. The scenarios consist in schemes for the disposal of the total amount of Swiss waste glass-packaging, i.e., different combinations of recycling and downcycling in Switzerland or abroad developed in Part I, Meylan et al. (2013). In this article (Part II), the disposal schemes are assessed with respect to eco-efficiency, an indicator that combines total environmental impacts and gross value added in Switzerland. Results show that no policy alternative guarantees environmental impact reductions and gross value added gains under all developments of exogenous constraints. Downcycling to foam glass in Switzerland is not only an environmentally sound disposal option, but it also buffers gross value added losses in case domestic recycling (and thus glass-packaging production in Switzerland) ceases in the future. The substitution of products based on raw materials other than Swiss cullet is the main responsible for change in environmental and economic impacts. Hence, an eco-efficiency maximizing policy should consider the products of disposal schemes. The combination of scenario analysis and eco-efficiency assessment as presented in this paper can be applied to other contexts (i.e., countries, waste fractions).     

贮存寿命评价工具箱设计研究

作为装备贮存可靠性与贮存寿命评价的关键技术,加速寿命试验和加速退化试验已在工程中广泛应用,基于物理分析的贮存寿命特征检测技术也逐步在贮存寿命评价工程中开展。贮存寿命评价技术已有一套完整的理论基础并积累了大量的工程实践经验,但行业内至今仍缺少专门针对贮存寿命评价的软件工具。本文通过对贮存寿命评价工具箱的需求分析研究工作,构建了工具箱的技术框架,并给出工具箱各主要模块的业务流程图和业务概念图,为贮存寿命工具箱的开发提供了支撑。     

Persistence of Bacillus thuringiensis deposits in a hardwood forest,after aerial application of a commercial formulation at two dosage rates

Abstract

A commercial formulation of Bacillus thuringiensis Berliner var. kurstaki (BTK), Foray® 48B, was sprayed aerially over four blocks B13, B14, B15A and B15B in an oak forest in Wayne County, Pennsylvania during May 1990. B13 and B14 were sprayed at 75 billion international units (BIU) in 5.91 litres/ha and the other two at 50 BIU in 3.94 litres/ha. Oak foliage was collected at different intervals of time after treatment. Three types of bioassays were conducted against fourth instar gypsy moth larvae, viz., direct feeding of sprayed foliage, feeding on diet containing homogenized foliage, and force‐feeding of foliar extracts. Larval mortalities were converted into international units of BTK activity per unit area (IU/cm²) of foliage. Foliar extracts were also subjected to enzyme‐linked immunosorbent assay (ELISA) to determine the concentration of delta‐endotoxin protein. Regardless of the type of bioassay used, bioactivity of BTK persisted in foliage for about a week in all the blocks. The half‐life of inactivation, DT₅₀, ranged from ca 12 to 22 h. The immunoassay data indicated a shorter duration of persistence (i.e., about 2 d) of the delta‐endotoxin protein, with DT₅₀ values ranging from 10 to 15 h. Formulation ingredients present in Foray 48B played a role in the toxicity of BTK to gypsy moth larvae.     

黑尾近红鲌人工繁殖研究

报道了2001~2003年对长江上游特有鱼类黑尾近红鲌开展人工繁殖试验的结果。黑尾近红鲌亲鱼来源于四川泸州长江上游一级支流龙溪河。催产剂为促黄体素释放激素类似物(LRH A)，绒毛膜促性腺激素(HCG) 与鲤鱼脑垂体(PG)。采用一次注射法，并用干法进行人工授精。共进行了23次人工催产，催产成功的占16次，有效的占3次，失败的占4次；共注射雌鱼70尾，其中46尾雌鱼排卵，平均催产率65.71%，受精率8.33%~100.0%，孵化率0.50%~94.71%，获得仔鱼29.3万尾。对亲鱼选择、催产方法、孵化与苗种培育等技术细节进行了讨论。     

浅海跃层底质对水下声的影响研究

本文针对海底底质对水下噪声传播具有显著影响的现象,选取典型负梯度温度跃层,加载三个典型海底底质,即细砂底质、粉砂底质及黏土-粉砂底质,声波参数为固定值。试验定性分析了浅海海底底质对水下声传播的影响,仿真计算了海底底质对声传播的影响,比较分析了不同底质条件下声波的衰减差异,总结了不同底质对水下声传播影响的特点,并同行参考。     

Sustainable cities: do political factors determine the quality of life?

The implementation of urban sustainability practices is affected by political obstacles, and diverse political ideologies may defend different city models. Sustainable policy design could also be affected by several factors that cause the deflection of resources initially allocated to other groups that are contrary to the concerns pursued and have the power to veto sustainable plans by exerting pressure on the party in power.In this sense, the aim of this paper is to show the impact that political factors have on cities’ sustainability, and the effect of both on cities’ economic development. To do so, we used the 78 Spanish cities with a population over 100,000 studied by MERCO (Spanish Corporate Reputation Monitor) as regards their levels of sustainability for the fiscal years 2008 and 2009. Both relationships have been tested empirically through two dependence models using linear regression techniques.The results obtained show that political competition improves cities’ sustainability, while a leftist ideology has an inverse impact. On the other hand, a significant direct relationship has been observed between urban sustainability and municipal economic activity.