Thermal research on the uncontrolled behavior of styrene bulk polymerization

Thermal runaway can occur during the styrene bulk polymerization process because of easily formed local hotspots resulting from the high viscosity of reactants and the difficulty of heat dissipation. To obtain the thermal hazard characteristics, the polymerization behavior of styrene was investigated using differential scanning calorimetry (DSC) at a scanning rate of β = 2 °C/min. Experimental results showed that the exothermic peaks obtained for heat initiation were different from those obtained when initiator was added. The exothermic peak changed from one to two after the initiator was added. The exothermic onset temperature (T₀) was also reduced. Phi-tech II was utilized to study the bulk polymerization of styrene in an adiabatic environment. The adiabatic temperature rise (ΔT_ad), starting temperature of uncontrolled polymerization (T_star), maximum temperature (T_end), and heat of polymerization (ΔH) under different conditions were acquired. When the dose of the additive was increased, the starting temperature of uncontrolled polymerization (T_star) decreased and the adiabatic temperature rise (ΔT_ad) increased gradually. Severity grading was performed based on the severity evaluation criteria of runaway reaction. The results can help designers decide whether it is necessary to take certain measures to reduce risk.     

人员密度和出口宽度的不确定性对疏散行动时间的影响

基于Kikuji Togawa所提出的常用人员疏散行动时间经验公式，使用拉丁超立方抽样法，研究房间人员密度和出口宽度的不确定性对疏散行动时间的影响。得出二者服从均匀分布和正态分布条件下，疏散行动时间的概率密度直方图和累积概率曲线。结果表明，人员密度和出口宽度的不同分布形式对疏散行动时间都有显著影响，二者服从正态分布时，计算得到的疏散行动时间范围比服从均匀分布小，且较为集中。而服从均匀分布时，计算得到的疏散行动时间在其范围内则较为均匀、分散。在小概率0～0．1区间范围内，人员密度和出口宽度服从正态分布时，计算得到的疏散行动时间累计概率值明显较均匀分布小，说明二者服从正态分布得到的疏散行动时间值偏于保守。二者均为不确定参数时，假定人员密度服从均匀分布，出口宽度服从正态分布时计算得出的疏散行动时间值偏于保守。     

暴露与养护时间对混凝土氯离子扩散性能的影响

随着暴露于实际环境中时间的延长,氯离子在混凝土中的扩散性能逐渐衰减。获取氯离子扩散性能与时间的关系是困难的,而养护时间对混凝土氯离子扩散性能也有影响。通过设计的人工气候环境下暴露和养护时间因素试验,测定了不同配合比、不同养护时间和暴露时间的混凝土中自由氯离子的浓度,并利用Fick第二定律分析了试验混凝土的氯离子扩散系数。分析和试验的结果表明,混凝土扩散系数随着暴露时间和养护时间的延长而降低,而暴露时间对混凝土氯离子扩散性能的影响更加明显,且扩散系数的降低幅度有减缓的趋势。     

Polychlorinated Biphenyls (Pcbs) Pollution in Sea of Japan

Deep waters of the Sea of Japan and surface waters of the Pacific Coast of Honshu and the northeast Sea of Japan were analysed for polychlorinated biphenyls (PCBs) pollution. the ΣPCB concentrations in solution in the Sea of Japan (50-3000 m) were between 140 and 1230 fg dm_-3. the space-integrated surface water concentration near the Pacific coast of northern Honshu was 140 fg dm_-3and for the surface water of the Sea of Japan was 230 fg dm_-3. Based on these analyses four water masses were deduced in the Sea of Japan during the summer months. It is shown for the first time in the Sea of Japan that polychlorinated biphenyls are excellent chemical indicators of not only the anthropogenic pollution, but also water masses.     

汶川地震灾区小流域洪水计算方法初探

汶川地震灾区小流域山洪不仅造成巨大损失,同时也是泥石流等灾害的激发因素,探寻一种准确且可操作的洪水峰值流量计算方法对防灾减灾具有重要意义。本文选择不同产流和汇流计算方法,组合成不同水文模型,进行小流域洪水过程计算,对模拟结果和参数选择进行对比,旨在探究最适合该地区的小流域水文计算方法。分别选择SCS曲线法、Green-Ampt入渗法、初损稳渗法进行坡面产流计算,应用SCS单位线法、Snyder单位线法和运动波方程进行坡面和沟道汇流计算,组合成5种小流域产汇流计算模型,利用6场洪水进行参数率定和结果验证。模拟结果对比分析,得出SCS曲线法是最适宜的产流模型,其与SCS单位线、运动波汇流计算方法组合而成的SCS和SKK模型,峰现时间的模拟误差最小,在0~25 min之间;洪峰流量模拟的相对误差较小,平均误差不超过4%;洪水总量模拟误差在10%左右。另外,这两种模型参数设置及确定较简单,更适合在数据稀缺的小流域中进行洪水模拟应用。研究可为汶川地震灾区小流域山洪和泥石流等灾害的流量估算提供方法和参数借鉴。     

Syntrophic co-culture of Bacillus subtilis and Klebsiella pneumonia for degradation of kraft lignin discharged from rayon grade pulp industry

In order to search the degradability of kraft lignin, the potential bacterial strains Bacillus subtilis (GU193980) and Klebsiella pneumoniae (GU193981) were isolated, screened and applied in axenic and co-culture conditions. Results revealed that mixed culture showed better decolorization efficiency (80%) and reduction of pollution parameters (COD 73% and BOD 62%) than axenic culture. This indicated syntrophic growth of these two bacteria rather than any antagonistic effect. The HPLC analysis of degraded samples of kraft lignin has shown the reduction in peak area compared to control, suggesting that decrease in color intensity might be largely attributed to the degradation of lignin by isolated bacteria. Further, the GC–MS analysis showed that most of the compounds detected in control were diminished after bacterial treatment. Further, the seed germination test using Phaseolus aureus has supported the detoxification of bacterial decolorized kraft lignin for environmental safety. All these observations have revealed that the developed bacterial co-culture was capable for the effective degradation and decolorization of lignin containing rayon grade pulp mill wastewater for environmental safety.     

注水站泵房噪声治理措施及效果

针对注水站泵房的噪声源及产生原因进行分析,就机械、电磁等噪声源,采取设备改造、隔声、消声、吸声等噪声控制措施,实施效果较好。     

近60a来中国洪涝灾情变化趋势持续性和周期性研究

本文利用Hurst指数和小波分析工具对洪涝灾情的1950~2010年的变化动态作了分析,揭示了灾情序列的趋势持续性、特征时间尺度、周期特征和突变点,同时还定性地预测了洪涝灾情的未来走势。研究结果发现:1)根据Hurst指数计算结果,受灾面积时间序列的Hurst指数为0.9338,具有很强的正持续性。未来有进一步增加的趋势。因灾死亡人口数时间序列的Hurst指数为0.4845,具有很弱的反持续性。而房屋倒塌间数时间序列的Hurst指数为0.6124,具有较弱的正持续性,未来有较弱的减少趋势。2)小波分析方法具有较好时空域特性,可以描述洪涝灾害灾情变化的多尺度特征,将隐含在灾情序列中随时间变化的周期震荡显现出来,并确定灾情序列中的突变点位置,为深入探索中国洪涝灾害的时空复杂性提供了全新的理论工具。3)中国洪涝灾害灾情都存在多时间尺度特征,不同的时间尺度表现为不同的循环交替,大尺度的周期变化嵌套着小尺度的周期变化。总体上表现为由小尺度的震荡剧烈,没有明显的规律到大尺度出现明显规律后继续增强或先升后降。4)60 a来,中国洪涝灾害受害面积总体上保持着增加的趋势。在9 a和25 a上分别存在着第1和第2主周期。中国洪涝灾害因灾死亡人口总体上保持着明显减少的趋势。在8 a和18 a上分别存在着第1和第2主周期。中国洪涝灾害倒塌房屋总数总体上保持着减少的趋势。在8 a、17 a和25 a上分别存在着第1、第2和第3主周期。     

贵州普定陈旗喀斯特泉的降雨-径流响应特征分析

本文以贵州省普定县陈旗喀斯特泉流量为研究对象,采用相关分析和谱分析方法,分析降雨-出口泉流量的响应特征,统计结果表明,该喀斯特流域出口处泉流量对降雨表现出三种响应滞时,分别为短时段、中等时段和长时段响应。对应的响应滞时长度分别为2~4 h、47~49 h和176~290 h。对比流域山坡上部和坡脚两处降雨-泉流量响应特征,结合野外水文地质调查与实验,分析了表层岩溶带发育厚度、多重裂隙渗透性等水文地质条件对降雨-泉流量响应特征的影响机制。山坡上部表层岩溶带厚度较薄,且表层裂隙更为发育,导致山坡上部泉对降雨的响应更迅速,各时段滞时均小于全流域对应时段滞时。     

环境因子对某新型延时起爆装置性能影响研究

目的研究环境因子对某火工元件延时性能和输出能量的影响。方法根据某型延时起爆装置的组成结构特点,依据火工品试验法、军械装备环境试验法,结合极限使用环境条件设计了高温高湿、温度冲击试验。结果高温高湿的延迟时间范围为260~630 ms;温度冲击的延迟时间范围为283~513 ms,高温高湿输出能力范围为13~17 mm,温度冲击输出能力范围为13~18 mm。结论高温高湿试验对延迟时间影响较大,出现超出指标的延迟时间。