全文获取类型
收费全文 | 2256篇 |
免费 | 321篇 |
国内免费 | 691篇 |
专业分类
安全科学 | 378篇 |
废物处理 | 43篇 |
环保管理 | 274篇 |
综合类 | 1493篇 |
基础理论 | 525篇 |
污染及防治 | 227篇 |
评价与监测 | 86篇 |
社会与环境 | 156篇 |
灾害及防治 | 86篇 |
出版年
2024年 | 11篇 |
2023年 | 62篇 |
2022年 | 113篇 |
2021年 | 127篇 |
2020年 | 125篇 |
2019年 | 116篇 |
2018年 | 92篇 |
2017年 | 129篇 |
2016年 | 146篇 |
2015年 | 139篇 |
2014年 | 137篇 |
2013年 | 167篇 |
2012年 | 200篇 |
2011年 | 178篇 |
2010年 | 152篇 |
2009年 | 146篇 |
2008年 | 115篇 |
2007年 | 150篇 |
2006年 | 147篇 |
2005年 | 116篇 |
2004年 | 91篇 |
2003年 | 97篇 |
2002年 | 77篇 |
2001年 | 53篇 |
2000年 | 63篇 |
1999年 | 45篇 |
1998年 | 50篇 |
1997年 | 52篇 |
1996年 | 29篇 |
1995年 | 43篇 |
1994年 | 26篇 |
1993年 | 25篇 |
1992年 | 14篇 |
1991年 | 12篇 |
1990年 | 8篇 |
1989年 | 2篇 |
1988年 | 3篇 |
1987年 | 4篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有3268条查询结果,搜索用时 250 毫秒
161.
To investigate the effect of temperature on effective diffusion coefficients and retardation factors for Zn and Cd, combined
diffusion and sequential extraction analyses were conducted at 15 ˚C and 55 ˚C. The effective diffusion coefficients of the metals increased up to ten times according to the increased temperature. On
the other hand, the effect of temperature on the retardation factor depended on the retention mechanisms of the metals. The
distribution coefficient for Zn, which was mainly partitioned in the carbonate phase, increased up to two times with the increase
in temperature. On the other hand, the distribution coefficient for Cd, which was mainly partitioned in the exchangeable phase,
was hardly affected by the temperature change. Results of combined diffusion and sequential extraction analysis showed that
the effect of temperature on the heavy metals’ (Zn and Cd) migration through the compacted natural clay was influenced by
the combined effects of the diffusion coefficient and the retardation factor. Additionally, we could also observe the change
in retention mechanism for the metals with the change in pore water concentration. 相似文献
162.
通过扫描电镜(FE-SEM)、能谱分析(EDX)、X射线衍射(XRD)、LMS-30激光粒度分析等室内试验探究了尾矿库内存在的酸、碱离子对尾矿颗粒的沉降、微观形貌、物质组成以及粒径级配的影响;建立酸、碱影响下的孔隙比与渗透系数的数学关系模型,并将建立的模型用来表征尾矿库内的应力渗-流场两场耦合机制,实现代入有限元计算软件的目的。结果表明:化学因素的存在影响着尾矿颗粒的多项性状,酸性环境下尾矿颗粒发生溶蚀,部分金属元素流失;碱性环境下尾矿颗粒间生成胶结物质,孔隙出现以含氢氧化铁为主的絮状、团簇状堵塞物,改变了渗流速度;尾矿库内浸润线高度在碱性、中性、酸性环境下依次降低,而渗流速度依次升高。 相似文献
163.
为促进安全管理,提高效率与效果,对基于情感思维的安全管理进行研究,将情感思维融于安全管理,基于情感思维的定义、内涵及功能,具体分析安全管理中情感思维的功能及其功能综合作用,建立安全管理中情感思维功能作用理论模型;根据该理论模型分析情感思维驱动力及强化作用及其对安全目标实现的影响;建立基于情感思维的安全管理设计模式,最后提出优化安全管理的措施与方法,以促进安全管理的实施。研究表明:基于情感思维的安全管理研究,能较好地体现安全管理人本原理,发挥情感的能动作用,将理性融入其中与情感进行平衡,实现安全管理的优化。 相似文献
164.
剩余污泥减量化工艺条件优化研究 总被引:2,自引:1,他引:1
运用超声处理连续流活性污泥系统中不同种类的污泥,并将其回流至原系统中,研究其剩余污泥减量化效果。按正交实验设计并进行试验,确定最优工艺条件。结果表明:当声能密度为0.6 W/mL,作用时间为5 min,超声污泥为混合污泥,回流比为7∶120时,减量效果最佳。且在该条件下经一周期的运行,污泥减量效果达到96.24%,COD由进水的830 mg/L降至44 mg/L,NH4+-N和TN分别由进水的62.43 mg/L和103.19 mg/L,降解到2.31 mg/L和6.52 mg/L,达到《城镇污水处理厂污染物排放标准》(GB18918-2002)一级排放标准。 相似文献
165.
166.
Carbon dioxide emissions have accelerated since the signing of the Kyoto Protocol. This discouraging development may partly
be blamed on accelerating world growth and on lags in policy instruments. However, it also raises serious question concerning
whether policies to reduce CO2 emissions are as effective as generally assumed. In recent years, a considerable number of studies have identified various
feedback mechanisms of climate policies that often erode, and occasionally reinforce, their effectiveness. These studies generally
focus on a few feedback mechanisms at a time, without capturing the entire effect. Partial accounting of policy feedbacks
is common in many climate scenarios. The IPCC, for example, only accounts for direct leakage and rebound effects. This article
attempts to map the aggregate effects of different types of climate policy feedback mechanisms in a cohesive framework. Controlling
feedback effects is essential if the policy measures are to make any difference on a global level. A general conclusion is
that aggregate policy feedback mechanisms tend to make current climate policies much less effective than is generally assumed.
In fact, various policy measures involve a definite risk of ‘backfiring’ and actually increasing CO2 emissions. This risk is particularly pronounced once effects of climate policies on the pace of innovation in climate technology
are considered. To stand any chance of controlling carbon emissions, it is imperative that feedback mechanisms are integrated
into emission scenarios, targets for emission reduction and implementation of climate policy. In many cases, this will reduce
the scope for subsidies to renewable energy sources, but increase the scope for other measures such as schemes to return carbon
dioxide to the ground and to mitigate emissions of greenhouse gases from wetlands and oceans. A framework that incorporates
policy feedback effects necessitates rethinking the design of the national and regional emission targets. This leads us to
a new way of formulating emission targets that include feedback effects, the global impact target. Once the full climate policy feedback mechanisms are accounted for, there are probably only three main routes in climate
policy that stand a chance of mitigating global warming: (a) returning carbon to the ground, (b) technological leaps in zero-emission
energy technology that make it profitable to leave much carbon in the ground even in Annex II countries and (c) international
agreements that make it more profitable to leave carbon in the ground or in forests. 相似文献
167.
The importance of potentially interacting factors in organisms responses to a stress are often ignored or underestimated in ecotoxicology. In laboratory experiments we investigated how gender, temperature and age influence the behaviour and the physiology of the freshwater amphipod Gammarus roeseli under salinity stress. Our results revealed a significant higher sensitivity of females in survival, ventilation and ionoregulation whereas no inter-age differences were reported. Water temperature also exerted a significant effect in survival and ventilation of G. roeseli. Some of those factors appeared to interact significantly. This study provides evidence that gender can affect organisms responses to a stressor and consequently has to be considered while assessing a stress impact. We discussed the potential relationships between biological and behavioural responses. 相似文献
168.
土壤-植物系统中磷和砷相互作用关系的研究进展 总被引:2,自引:0,他引:2
砷元素导致的环境污染问题日益突出,施磷已成为植物修复砷污染土壤过程中必要强化措施之一。土壤-植物系统中磷和砷的相互作用关系是非常复杂的,研究表明:磷和砷在土壤中往往是共生的,但又存在竞争吸附关系;磷和砷在不同植物中的相互作用关系主要有拮抗效应和协同效应;有必要通过分子生物学手段对磷和砷表达基理进行深入研究,获得对砷具有超积累能力的植株。 相似文献
169.
170.
采用水蒸气、氨气、过氧化氢气雾和臭氧4种气体对沙林模拟剂氟磷酸二异丙酯(DFP)进行降解研究,发现臭氧对DFP具有较好的降解作用,在流量200 L/h,DFP初始浓度50 mg/m3时,降解率最高可达56.1%。对高浓度DFP(大于80 mg/m3)进行降解研究时,等离子体单独作用最高降解率为89%,而添加臭氧后的降解率都在95%以上。计算得到臭氧作用的能量利用率为0.05 mg/(W·h),等离子体的能量利用率为0.55 mg/(W·h),而添加臭氧后的等离子体能量利用率为0.68 mg/(W·h)明显高于臭氧和等离子体能量利用率之和,因此对高浓度DFP进行处理时,臭氧与等离子体存在耦合作用。对等离子体和臭氧耦合等离子体降解DFP反应进行了产物分析,发现主要的降解产物基本一致,但是臭氧的存在能使降解更加彻底。 相似文献