多承载索货运索道计算方法及张力不平衡效应分析

通过分析多承载索货运索道工作索的空间位置关系,在弹性悬链线计算方法的基础上,建立包括索道结构守恒方程和力平衡方程的非线性方程组,形成多承载索货运索道系统整体耦合计算方法。针对四承载索货运索道的典型设计工况,应用该方法完成承载索长度不一致情况下,货运索道的承载索张力变化分析。研究结果表明:多承载索货运索道承载索间的张力不平衡受索长偏差影响极大,而且不平衡效应与索长变化工况（索长偏差变化量、变化索的位置等）和载荷重量密切相关,多索索长不一致造成的张力不平衡使得承载索破断风险急剧增加。     

盾构隧道安全疏散通道加压送风计算分析

为防止盾构隧道行车道发生火灾时烟气侵入人员疏散通道,可通过在盾构隧道疏散通道内设置独立机械加压送风系统保证疏散通道内正压状态进行防烟,提高人员疏散安全性。分别利用风速法和压差法对某隧道工程疏散通道加压送风系统送风量进行试算,并采用FDS(Fire Dynamics Simulator)软件对疏散前室送风、疏散通道单侧送风及疏散通道双侧送风3种加压送风方式进行模拟分析,对比不同加压送风方式下各疏散口风速、温度、能见度的情况。结果表明,通过风速法计算得到的加压送风量要大于压差法。采用前室加压送风会造成较强的气流扰动,导致疏散口附近风速及温度剧烈波动,部分烟气进入前室,不利于人员疏散。采用疏散通道加压送风时,疏散口处风速稳定。但采用单侧加压送风时,火源下游疏散口处会有部分烟气积聚,影响人员疏散。采用双侧加压送风时烟气积聚少,疏散口附近温度、能见度等安全指标均在临界范围内,防烟效果良好,可以保证人员疏散安全。因此,建议采用纵向疏散通道加压送风,送风量建议采用风速法计算,当采用纵向疏散通道双侧加压送风时,建议在风速法得出的送风量基础上增加10%作为安全值。     

Temperature effect on photolysis decomposing of perfluorooctanoic acid

Perfluorooctanoic acid(PFOA)is recalcitrant to degrade and mineralize.Here,the effect of temperature on the photolytic decomposition of PFOA was investigated.The decomposition of PFOA was enhanced from 34% to 99% in 60 min of exposure when the temperature was increased from 25 to 85°C under UV light(201–600 nm).The limited degree of decomposition at 25°C was due to low quantum yield,which was increased by a factor of 12 at 85°C.Under the imposed conditions,the defluorination ratio increased from 8% at 25°C to 50% at85°C in 60 min.Production of perfluorinated carboxylic acids(PFCAs,C7–C5),PFCAs(C4–C3)and TFA(trifluoroacetic acid,C2)accelerated and attained a maximum within 30 to 90 min at 85°C.However,these reactions did not occur at 25°C despite extended irradiation to180 min.PFOA was decomposed in a step-wise process by surrendering one CF2unit.In each cyclical process,increased temperature enhanced the quantum yields of irradiation and reactions between water molecules and intermediates radicals.The energy consumption for removing eachμmol of PFOA was reduced from 82.5 k J at 25°C to 10.9 k J at 85°C using photolysis.Photolysis coupled with heat achieved high rates of PFOA degradation and defluorination.     

无机沉淀对土壤有机质吸附疏水有机污染物的影响

土壤有机质对疏水性有机污染物的吸附解吸是影响其在土壤中迁移、转化和归趋的重要因素之一。老化是有机污染物和土壤等介质长时间相互作用的结果,它影响着污染物的生物有效性。已有的老化研究注重有机污染物被土壤等介质吸附隔离的机制,很少考虑土壤等吸附剂自身演化对有机污染物吸附的影响。本文通过无机沉淀处理方法来模拟自然环境过程吸附剂自身的演化对土壤有机质吸附能力的影响,从而证明吸附剂自身的变化也是影响老化效应的一个重要因素。结果表明,不同无机沉淀包裹和填充的碱提土样品比原始碱提土样品具有更小的吸附能力,同时无机沉淀处理后的样品的吸附性能随着无机沉淀离子浓度增加而降低。这可能是无机沉淀覆盖碱提土样品的内外表面积和填充碱提土样品的微孔所引起的,同时也可能是无机沉淀占据了吸附有机污染物的高能点位所致。     

基于土地利用转型视角的“亚喀斯特”区域生态环境效应研究——以黔中部分地区为例

在遥感与GIS的支持下,以1995、2000、2005和2010年的TM影像及2015年的Landsat8 OLI遥感影像为数据源,从土地利用转型的角度,运用区域生态环境质量指数和土地利用转型类型的生态贡献率对亚喀斯特地区的土地利用/覆盖变化过程及生态环境效应进行了定量分析。结果表明,1995~2015年间,亚喀斯特地区土地利用/覆盖变化较为显著,其中生活用地和生态用地面积增加,而生产用地面积减少,主要表现为农业生产用地向城镇、农村生活用地及林地生态用地的转化。计算得到亚喀斯特区域5期的生态环境质量指数分别为0.540 2、0.539 7、0.552 3、0.558 1和0.561 5,生态环境质量总体维持稳定,呈一定的上升趋势。致使亚喀斯特区域生态环境质量改善的主要原因是农业生产用地向林地、草地和水域生态用地的转化;致使生态环境恶化的主要是农业生产用地向城镇、农村生活用地等的转化,但生态环境改善的趋势要大于恶化的趋势。     

供给侧结构性改革与环境保护的相互影响

在经济增长放缓,市场中高端需求扩大,但有效供给不足的形势下,国家推行供给侧结构性改革,以期调整产业结构,提高生产率.对于具有政策驱动性特点的环保产业,此轮改革既是机遇也是挑战.环保产业的供给侧结构性改革,对于科技、资本、人才、信息和创新等高级要素的投入提出了新的要求.同时,公众对环境保护的需求又会倒逼供给侧结构性改革的推行.文中介绍了供给侧结构性改革的内涵和必要性,阐述了环保约束对供给侧结构性改革的影响和供给侧结构性改革对环保领域的影响,旨在为环保产业在新常态下的大力发展提供借鉴.     

土体-结构界面接触对地下结构动力反应的影响

迄今为止,关于土体与结构交界面的接触效应对地下结构地震反应的影响尚未引起研究者们的重视,成果鲜有报道。本文基于接触面对法和非线性有限元波动分析方法,建立了考虑土体与结构界面接触效应的地下结构非线性地震反应分析模型和计算方法,并利用大型有限元软件ANSYS进行了求解。分析结果表明:土体与结构界面的接触效应对地下结构地震反应有明显影响,可能增大地下结构节点的峰值加速度、峰值位移和峰值应力反应;随着接触摩擦系数的增大,接触点的相对滑移逐渐减小,而接触应力的变化则无明显规律。     

初中教育师资力量与教育成效耦合协调研究--以大连市为例

基于2015年大连市初中学校教育统计数据,利用熵值法、耦合协调度模型和空间插值分析法,从市域内校际间对大连市初中师资力量与教育成效耦合协调的空间特征进行了研究。结果表明:①师资力量高低分离、抱团分布,教育成效呈现核心高、边缘低的格局。②师资力量与教育成效的耦合度总体水平较高,以高水平耦合为主,空间上基本覆盖整个大连市。③协调度上,勉强协调与初级协调为主,空间呈现明显的中心—外围分布趋势,其中勉强协调占大部分。④学校类型具体划分为6种协调类型,呈核心—外围的圈层分布模式,其中核心城区为师资高成效高的中级协调。     

Welfare effects of rural-urban land conversion on different aged land-lost farmers: exemplified in Wuhan city

Rural-urban land conversion is a universal phenomenon in the rapid process of economic development and urban growth. The welfare of farmers who lost their farmland attracted a widespread concern within the society and academia. However, further research about differentiated policies according to the characteristics of different farmer groups is still need to be conducted. This article divides the land-lost farmers into three age groups: younger than 45, 45–65, and more than 65. It proposes a welfare index system including eight functional areas based on different age groups of affected farmers, taking four districts of Wuhan City as case study area. Fuzzy mathematics method is used to derive the aggregated welfare effect index. Our analysis show that the overall welfare levels of land-lost farmers of all age groups declined, but with a varying degree, with the level of welfare in those farmers who are 45–65 years old, younger than 45 years old, and older than 65 years old decreased by 18.7%, 16.6%, and 12.7%, respectively. The direction and degree of effects on the functional activity index varies among different groups. Economic conditions, living environment, health, and social participation of all age groups decrease while social security and housing conditions increase. On the other hand, development opportunities, social communication, and leisure have different changing directions in different age stages. These results call for differentiated and tailor-made compensation policies for land-lost farmers, towards improving the welfare levels of all farmers and reduce the disparity among them.     

An emergency response plan for cascading post-earthquake fires in fuel storage facilities

Natural disasters such as large earthquakes may rapidly result in cascading events such as post-earthquake fires (PEFs) to trigger. This is particularly the case in industrial facilities which is well known as natural-hazard triggered technological accidents (NaTechs). This study provides a response framework for NaTechs caused by earthquake in fuel storage facilities. To do this, seismic vulnerability of fuel storage tanks and possible damage fashions are studied. Considering fuel leakages can result in PEFs, possible scenarios are simulated numerically using Process Hazard Analysis Software Tool (PHAST). A case study including 20 fuel tanks adjacent one to another is investigated to simulate a domino effect when different arbitrary tanks start to ignite; hence, the worst case scenario can be determined. Based on the results of the case studied, inability to extinguish the possible PEFs over less than 9 min can lead to spreading them to the adjacent tanks. The results indicate that it takes about 40 min the adjacent tanks involve in the fires. Therefore, it is of paramount importance to provide an emergency response plan in advance to properly respond to the fires. The study here also highlights the role of preventive strategies in reducing the associated risks of PEFs in industrial facilities.