Long‐Term Trends in Streamflow and Precipitation in Northwest California and Southwest Oregon, 1953‐2012

Using nonparametric Mann‐Kendall tests, we assessed long‐term (1953‐2012) trends in streamflow and precipitation in Northern California and Southern Oregon at 26 sites regulated by dams and 41 “unregulated” sites. Few (9%) sites had significant decreasing trends in annual precipitation, but September precipitation declined at 70% of sites. Site characteristics such as runoff type (groundwater, snow, or rain) and dam regulation influenced streamflow trends. Decreasing streamflow trends outnumbered increasing trends for most months except at regulated sites for May‐September. Summer (July‐September) streamflow declined at many sites, including 73% of unregulated sites in September. Applying a LOESS regression model of antecedent precipitation vs. average monthly streamflow, we evaluated the underlying streamflow trend caused by factors other than precipitation. Decreasing trends in precipitation‐adjusted streamflow substantially outnumbered increasing trends for most months. As with streamflow, groundwater‐dominated sites had a greater percent of declining trends in precipitation‐adjusted streamflow than other runoff types. The most pristine surface‐runoff‐dominated watersheds within the study area showed no decreases in precipitation‐adjusted streamflow during the summer months. These results suggest that streamflow decreases at other sites were likely due to more increased human withdrawals and vegetation changes than to climate factors other than precipitation quantity.     

Characterizing agrochemical patterns and effective BMPs for surface waters using mechanistic modeling and GIS

Monitoring programs in the agriculturally intense San Joaquin River Valley of California have periodically found organophosphate (OP) insecticide concentrations, predominantly chlorpyrifos, diazinon and methidathion, at levels high enough to cause mortality for the aquatic invertebrate Ceriodaphnia dubia. These detections are likely the result of off-site movement from treated fields. However, the relative significance and magnitude of off-site transport pathways cannot be readily deduced from monitoring data alone. Therefore, a comprehensive modeling system has been constructed to estimate temporal and spatial pesticide source magnitudes and to follow the pesticide dissipation pathways once in surface water. The USEPA models HSPF and PRZM3 were used for the hydrology and non-point source predictions, respectively. Spray drift was accounted for using the mechanistic model AgDrift. The Orestimba Creek Watershed in the San Joaquin Valley was characterized and used as a typical watershed for this region. Representative transport pathways were ranked and quantified, and numerical implementation of best management practices (BMPs) determined which practice may have the highest likelihood for reducing pesticide loadings. Approximately 85% of the predicted chlorpyrifos mass detected between May 1, 1996, and April 30, 1997 resulted from drift, with the largest contributions coming from walnut orchards immediately adjacent to Orestimba Creek. Various simulated drift mitigation measures suggest chlorpyrifos mass loadings can be decreased by over 90% depending upon the type of mitigation chosen. Imposed drift BMPs should be effective in reducing chlorpyrifos levels found in surface waters of the San Joaquin valley if the Orestimba creek watershed is considered representative of watersheds found in this area of California.     

Urban nonpoint source pollution buildup and washoff models for simulating storm runoff quality in the Los Angeles County

Many urban nonpoint source pollution models utilize pollutant buildup and washoff functions to simulate storm runoff quality of urban catchments. In this paper, two urban pollutant washoff load models are derived using pollutant buildup and washoff functions. The first model assumes that there is no residual pollutant after a storm event while the second one assumes that there is always residual pollutant after each storm event. The developed models are calibrated and verified with observed data from an urban catchment in the Los Angeles County. The application results show that the developed model with consideration of residual pollutant is more capable of simulating nonpoint source pollution from urban storm runoff than that without consideration of residual pollutant. For the study area, residual pollutant should be considered in pollutant buildup and washoff functions for simulating urban nonpoint source pollution when the total runoff volume is less than 30 mm.     

城市路面径流污染负荷及采样次数对其估算准确性的影响

在西安市城市主干道南二环路建立路面径流原位采样站,利用自制流量等比例采样装置,采集2009年3月-2010年2月的36场降雨径流,测试各场次径流SS、COD、溶解性COD、NH4-N、Pb、Zn和溶解态Pb、Zn的事件平均浓度(EMC),计算径流年污染负荷,并采用随机抽样方法研究采样次数对污染负荷估算准确性的影响.结果...     

耕作措施对三峡库区土壤侵蚀和养分流失的影响

为研究三峡库区土地耕作措施对土壤侵蚀和营养物质流失的影响,在三峡库区张家冲小流域设置10个不同土地利用方式的试验小区,在自然降雨条件下,进行为期1 a的小区试验,研究不同土地利用方式下土壤侵蚀和径流中氮、磷流失特征.结果表明:在10个试验小区中,土坎梯种柑小区年均径流量和土壤侵蚀量最大,土坎篱种柑小区年均径流量最小,坡地种粮小区土壤侵蚀量最小;坡篱种粮小区总氮和总磷年流失量最大,坡地种柑小区年流失量最小;土壤侵蚀和营养物质流失主要发生在6-8月降雨集中的暴雨季节.在类似于研究区域的其他农业区域,适合于坡地种柑,而坡篱种粮和土坎梯种柑是不适合推广的种植方式.     

用SOS/umu试验评价降雨径流遗传毒性的变化

通过SOS/umu试验分析检测屋面和道路在2017年5、6月2场降雨过程中的遗传毒性变化。结果表明,从降雨初期到结束,在5月份屋面产生降雨径流2 h内和道路产生径流20 min内雨水样品的检测结果均呈阳性,诱导率IR均大于2,表现出DNA损伤效应;在6月份屋面产生降雨径流60 min内和道路产生径流10~60 min内雨水样品的结果均呈阳性,表现出遗传毒性。2场降雨中屋面和道路雨水样品的TEQ4-NQO均随降雨时间先增加后逐渐减小,5月份屋面雨水样品的毒性大于路面雨水样品的毒性,6月份则相反。遗传毒性分析降雨径流中污染物毒性的变化为雨水的安全利用提供理论基础。     

Source diagnostics of polycyclic aromatic hydrocarbons in urban road runoff, dust, rain and canopy throughfall

Diagnostic ratios and multivariate analysis were utilized to apportion polycyclic aromatic hydrocarbon (PAH) sources for road runoff, road dust, rain and canopy throughfall based on samples collected in an urban area of Beijing, China. Three sampling sites representing vehicle lane, bicycle lane and branch road were selected. For road runoff and road dust, vehicular emission and coal combustion were identified as major sources, and the source contributions varied among the sampling sites. For rain, three principal components were apportioned representing coal/oil combustion (54%), vehicular emission (34%) and coking (12%). For canopy throughfall, vehicular emission (56%), coal combustion (30%) and oil combustion (14%) were identified as major sources. Overall, the PAH's source for road runoff mainly reflected that for road dust. Despite site-specific sources, the findings at the study area provided a general picture of PAHs sources for the road runoff system in urban area of Beijing.     

重庆市河堰村景观改变对水环境的影响

为了研究农村景观改变对水环境的影响,选取重庆市河堰村为研究对象,运用SWMM水文模拟软件,分析了研究区域的景观变迁与水量、水质变化的相互关系;通过访谈当地居民,分析了土地利用与景观变化对水环境的影响机制。认为(1)散点状的居民点分布模式与"村村通公路,户户通水泥"的农村道路建设以及庭院硬质化导致农村不透水表面面积迅速增加,缩短了雨水汇流时间并加速了污染物向水体的转移。(2)山体开发和现代农田水利工程的建设,如水库、山坪塘和排灌沟渠等的建设导致水体自净能力降低,加重了水体污染。(3)地表硬质化与河床沟渠化加速了水过程从而加速水环境的破坏。(4)人水关系由"我"、"你"变成"我"、"它",农民在卫生意识上升的同时缺乏相应的环保意识。     

河水受百年一遇大旱后城市降雨径流的污染与治理

2009年入秋至2010年春,中国西南地区发生了百年一遇的特大旱灾。为探讨河水受百年一遇大旱后降雨径流污染的状况,对昆明典型交通干道路面的降雨径流和河水水质进行了监测,分析了大旱后降雨径流污染的严重性和对河水水质的影响,并考察了曝气塘—浮石床水平潜流人工湿地复合系统处理大旱后由城市降雨径流污染导致的重污染河水的效能。结果表明,大旱后的前3场降雨径流污染程度较正常雨季降雨径流污染程度严重,SS、COD、TN及TP浓度平均高出1.3倍。大旱后的前3场降雨径流溢流会对河流造成严重污染。该复合系统在塘调蓄—循环处理运行工况下能有效处理大旱后的重污染河水,对SS、COD、TP、TN和NH4+-N的平均去除率分别为98%、90%、96%、60%和90%,出水均达《城镇污水处理厂污染物排放标准》(GB 18918—2002)一级A标准。     

城市区域不同屋顶降雨径流水质特征

城市屋顶降雨径流是城市面源污染的主要组成部分之一。为了解城市不同屋顶降雨径流的水质特性,以重庆地区5种屋顶为例进行了20场降雨径流的水质监测。研究结果表明,不透水屋顶降雨径流污染物浓度均随降雨历时的延长而降低,混凝土屋顶降雨径流的COD、TP、TN、NH3-N平均浓度分别是瓦屋顶的1.6、1.7、1.4和1.5倍,且不透水屋顶降雨径流总氮的70%~80%为无机氮,总磷的20%~32%为磷酸盐;浅层屋顶降雨径流COD、TN、TP、NH3-N和NO-3-N浓度分别是深层绿色屋顶的0.25~0.26、0.3~0.5、0.07~0.09、0.3~0.6、0.05~0.06倍,且绿色屋顶降雨径流总氮的60%~80%为硝态氮。前期干旱天数和混凝土屋顶径流中的TN、接骨草屋顶径流中的氨氮浓度呈显著正相关关系,混凝土屋顶径流TP浓度与降雨强度显著正相关,降雨持续时间和瓦屋顶径流TSS平均浓度显著正相关。研究结果为城市建筑屋顶降雨径流的科学管理提供了参考。