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41.
The feasibility of decomplexation removal of typical contaminants in electroplating wastewater, complexed Cu(II) with 1-hydroxyethylidene-1,1-diphosphonic acid (Cu-HEDP), was first performed by a three-dimensional electric
reactor with activated biochar as particle electrodes. For the case of 50 mg/L Cu-HEDP, Cu(II) removal (90.7%) and PO
initial pH 7, acid-treated almond shell biochar (AASB) addition 20 g/L, and reaction time 180 min, with second-order rate constants of 1.10 × 10−3 and 1.94 × 10−5 min−1respectively. The growing chelating effect between Cu(II) and HEDP and the comprehensive actions of adsorptive accumulation, direct and indirect oxidation given by particle electrodes accounted for the enhanced removal of Cu-HEDP, even though the mineralization of HEDP was mainly dependent on anode oxidation. The performance attenuation of AASB particle electrodes was ascribed to the excessive consumption of oxygen-containing functionalities during the reaction, especially acidic carboxylic groups and quinones on particle electrodes, which decreased from 446.74 to 291.48 µmol/g, and 377.55 to 247.71 µmol/g, respectively. Based on the determination of adsorption behavior and indirect electrochemical oxidation mediated by in situ electrogenerated H2O2 and reactive oxygen species (e.g., •OH), a possible removal mechanism of Cu-HEDP by three-dimensional electrolysis was further proposed. 相似文献
42.
A study for the photochemical behavior of some polyaromatic hydrocarbons (PAH), for example B(a )P, B( k )F and fluoranthene in coal smoke particles was performed by using indoor Teflon smog chamber.Experiments suggest that the photochemical reaction of PAH is first order reaction and kinetic rates of some PAH were obtained. It was shown that the reaction rate constant is proportional to light intensity and water vapor concentration. Temperature and PAH loading also have influence on PAH decay rate. A model for PAH loss has been set up on the basis of the results of our experiments and the simulating results of this model suggest that coal particle PAH half lives are of the order of a period of days in winter and a few hours in summer. Other factors which may have effect on the photochemical reaction of PAH have also been discussed. 相似文献
43.
The polymerase chain reaction (PCR) was used on material from a blighted ovum to confirm indirectly the carrier status of a woman with a family history of Becker muscular dystrophy. Conventional testing including creatine kinase levels, muscle biopsy, and EMG had been inconclusive, and on the basis of one elevated creatine kinase level, the woman had been designated a possible carrier. Ultrasound examination at 10 weeks of pregnancy indicated a blighted ovum, from which DNA was subsequently extracted and subjected to PCR testing for determination of sex and genotypic status with respect to the known familial deletion of the dystrophin gene. The blighted ovum was found to have a Y chromosome and also to be deleted for at least exon 6 of the dystrophin gene, indirectly indicating that the mother most likely carried the family mutation for Becker muscular dystrophy. 相似文献
44.
Fe3+催化氧化S(Ⅳ)反应机理初探 总被引:2,自引:0,他引:2
通过分析酸性条件下(pH为1~3),Fe3 催化氧化S(Ⅳ)过程中溶液吸光度变化的趋势,对Fe3 催化氧化S(Ⅳ)的反应机理进行了初步推导.实验证明,液相中该反应机理主要是催化氧化与自由基反应相结合,O2的存在对于反应有重要作用,O-2的生成是S(Ⅳ)被氧化的关键;当水中溶解氧接近耗尽时,反应进程发生改变.当Fe3 、S(Ⅳ)浓度增加,自由基生成量增加时,有利于反应进行;作为反应产物,Fe2 、S(Ⅵ)浓度增加,反应推动力减小,反应速率降低;同时Fe2 、SO24-可以与溶液中的其它物质形成配合物,影响了Fe3 -S(Ⅳ)配合物的生成与分解,不利于S(Ⅵ)的氧化. 相似文献
45.
人工湿地植物在污水处理系统中的作用探讨 总被引:8,自引:0,他引:8
人工湿地污水系统由于具有独特的净化机理和功能而越来越多地被用于处理生活污水和工业废水.湿地植物在人工湿地中起着非常重要的作用,不但可以直接摄取和利用污水中的营养物质、吸收富集污水中的重金属等有毒有害物质;而且还能输送氧气到根区,提供根区微生物生长、繁殖和降解过程中对氧的需求.文章通过详细阐述植物对水中营养元素的吸收作用,说明了植物在人工湿地处理污水中的重要性. 相似文献
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当前中国经济快速增长很大程度是以过度消耗资源、牺牲环境为代价的.生态环境污染严重影响经济的可持续发展,生态问题制约着和谐社会的构建.生态建设已成为协调经济、社会和生态发展,走可持续发展的唯一出路.当前由于政府主导型生态建设出现众多问题,诸如生态环境脆弱、压力大,法律法规不完善,生态建设资金投入少、投入渠道单一,生态治理工程效益有待继续提高等等.因此,倡导企业、农民、专家、投资者和志愿组织、社会团体等积极参与到生态建设中来,并建立激励机制对各参与者实施相应的激励措施,使他们充分发挥能动性,更快、更好的进行生态建设. 相似文献
50.
喷雾干燥法烟气脱硫过程的模拟试验研究 总被引:1,自引:0,他引:1
本文模拟试验研究了喷雾干燥法烟气脱硫中脱硫渣再循环利用、气体参数(SO2浓度、气速、气温)及浆液参数等对脱硫过程的影响,并分析了喷雾干燥塔内传热传质过程。本文结果将有助于改进喷雾脱硫塔的设计和操作。 相似文献