高效浅层气浮设备在高浓度炼油废水处理中的应用

介绍了高效浅层气浮设备、技术原理及在高浓度炼油污水处理中的应用效果,对设备运行中出现的一些问题进行了原因分析,并提出了处理措施。     

浅议炼油广的环境应急管理

对炼油厂环境应急管理中的应急预案、应急机制和应急制度进行了阐述,提出了应急预案的核心是风险识别、应急机制的核心是应急处置、应急制度的核心是应急演练的新观念。     

炼油厂剩余活性污泥综合利用可行性分析

针对目前炼油企业在剩余活性污泥处置过程中存在费用高、负担重及资源浪费等问题,选择典型代表企业进行采样分析,结果表明:与目前常用处置技术对比,污泥热干化后回用于锅炉做辅助燃料是可行的,同时也是目前较佳的综合利用方式。     

气浮／生化工艺在炼油废水中的应用

通过对石油化工企业炼油废水水质特性的分析,采用隔油一浮选一曝气-A／0生化工艺处理锦西石化的炼油废水。实践表明,二级气浮＋二段生化处理工艺对炼油废水COD和NH3-N的平均去除率为96．7％和99．2％。使外排水水质远优于辽宁省《污水综合排放标准》中规定的CODcr〈50,NH3-N〈8的标准。     

200MW燃煤机组SCR脱硝改造关键技术问题解析

目前,国内200 MW机组SCR脱硝改造尚无样板工程及改造先例。200 MW机组由于其独特地设计,同300 MW以上等级机组相比,脱硝改造的技术方式与改造内容均有较大的差异。文章从国内200 MW机组脱硝改造实际情况出发,从设计参数选取、还原剂选择、SCR反应器布置方式、低氮燃烧器改造、空预器改造及引风机改造、厂用变压器系统改造等关键问题进行了技术分析并提出可行建议,为同等级机组脱硝改造工作提供方法与经验。     

炼铝废渣的综合利用试验

铝灰掺入混凝土后将引起体积膨胀强度下降,故不适用于混凝土。但含一定量的铝灰,石灰和统砂的混合材料一种优质的路用材料,用铝灰制成的水处理剂对印染废水,制革废水均有较好的去除效果。     

电吸附组合工艺在炼油污水回用中的研究与应用

采用生物深度处理-过滤-电吸附除盐组合工艺对炼油二级生化排污进行深度处理,中试和工业应用试验结果表明:该组合工艺具有较好的抗石油类有机物污染的能力,电吸附除盐设备核心部件预期使用寿命长,产水可以直接回用于循环水作补水,浓水达到国家一级排放标准,可以直接排放。该工艺不产生二次污染,属于绿色环保工艺。     

炼油废水絮凝剂筛选

通过试验对炼油废水絮凝剂进行了筛选。结果表明 ,有机高分子絮凝剂 (PAM、HL - 70 4 )与无机絮凝剂 (PAC)复配显著提高了油类和COD的去除率 ,复配絮凝剂具有投加量少、适用性强等优点。     

紫外光助O3、H2O2氧化降解炼油废碱水的可行性实验

炼油高浓度有机废碱水是石化行业中很难降解的废水.本实验用光化学氧化技术对其进行了降解研究,比较了紫外光/空气、紫外光/O3、紫外光/空气/H2O2系统的处理效果.结果表明,光化学氧化技术降解此废水是可行的,紫外光可使废水中COD、油、酚的降解率明显提高.当废水中O3的投加量每小时为22 mg/L,或H2O2投加量为1%/L时,UV/O3法与UV/空气/H2O2法的降解效果相近.同时,通过控制O3浓度或H2O2的投加量等条件,可使废水中COD、油、酚和硫化物降解到地方污染物二级排放标准.     

Hydrogen explosion incident mitigation in steam reforming units through enhanced inspection and forecasting corrosion tools implementation

Hydrogen (H₂) explosion effects recently examined, are confirming the devastating loss scenarios to humans, environment, assets, and associated business interruption. H₂ production is a core process in refineries used in further process steps. Steam reforming of natural gas or a mix with naphtha or LPG is a common hydrogen production technique, where the latest technologies have adopted enhanced metallurgies to minimize explosion risk and the associated maintenance cost following plant degradation owing to corrosion effects. However, corrosion rates are still high in specific areas of piping and process equipment. The aim of this paper is to present a methodology based on semi-quantitative RBI modeling according to regulations by API and recent EN standards, adopting a family of linear regression forecasting models that depict the yearly corrosion rate (per corrosion loop) of a hydrogen production steam reforming unit; this is done under different operating conditions (e.g., temperature, pressure, and fluid speed), metallurgy and other related physicochemical variables. The model is based on the examination of both ultrasonic wall thinning measurements and the examination of quantitative crosslinking total corrosion effects along with the physicochemical properties prevailing in different plant corrosion loops. The outcome of the regression analysis is an expansive family of multivariable equations describing, with a defined accuracy, the yearly corrosion rate and associated lifespan forecast per corrosion loop, and per examined part. These equations were further utilized in a custom-made database that can be used as an additional loss prevention tool by the hydrogen production unit management team. Evaluation results regarding the tool efficiency are presented in the following of this paper.