微电解技术处理难降解工业废水的研究进展

介绍了铁碳微电解技术处理工业废水的作用机理。综述了铁碳微电解技术的研究进展。针对该技术在处理不同工业废水时普遍存在的堵塞、短路、死角、铁屑结块等问题,介绍了研发的新型纳米铁碳微电解复合材料及新工艺,并对铁碳微电解技术今后的研究方向进行了展望。     

Thermal runaway reaction for highly exothermic material in safe storage temperature

Highly exothermic materials have caused many serious accidents involving storage and transportation, due to being thermally reactive. The safe storage and management of these materials is still a critical problem in many countries. Our aim was to study the thermal hazard of thermal reactive materials, such as a propellant, by employing differential scanning calorimetry (DSC) non-isothermal tests and isothermal tests, and then comparing the kinetic parameters by isothermal and non-isothermal of kinetics. The chosen approach was to obtain reliable thermal decomposition by a safe and effective method, which acquired the kinetic and safety parameters of storage conditions that could be applied as highly exothermic materials' reduction of loss prevention and energy potential for safer design during storage transport and processing operations.     

功能化层状复合材料的制备及其电催化性能

目的制备一种新型功能化离子液体修饰层状复合材料,研究其对L-酪氨酸(L-Tyr)的电催化氧化行为。方法通过静电自组装方式将氮氧自由基功能化离子液体(TEMPO-IL)与钙铌酸钾(KCa_2Nb_3O_(10))进行复合,并运用XRD,FTIR,SEM,HRTEM等测试手段对所作材料的微观形貌和结构进行分析表征。另外,将其作为电极修饰剂修饰于电极表面通过电化学工作站测试其电化学性质。结果该修饰电极对于电催化氧化L-Tyr有着较高的电化学活性。同时实验还表明,当L-Tyr的浓度在1×10~(-4)~1.16×10~(-2) mol/L之间时,峰电流值与L-Tyr浓度呈良好的线性相关,检测下限为6.2×10~(-5) mol/L(信噪比为3)。结论静电自组装是一种能够快捷、高效的制备层状复合材料方法,且得到的复合材料显示出在生物传感器方面的应用前景。     

The velocity of DNAPL fingering in water-saturated porous media: laboratory experiments and a mobile–immobile–zone model

Dense nonaqueous phase liquids (DNAPLs) are immiscible with water and can give rise to highly fingered fluid distributions when infiltrating through water-saturated porous media. In this paper, a conceptual mobile–immobile–zone (MIZ) model is presented to describe the structure of a DNAPL finger in water-saturated porous media and the velocity of finger propagation. A finger is composed of a finger body and a tip. The finger body has a mobile core and an immobile sheath. All the DNAPL within the tip of a finger is mobile. Lab experiments utilizing image analyses of a DNAPL (PCE) penetrating into water-saturated homogeneous glass beads were carried out in a two-dimensional transparent chamber. The results show that the fingers elongated almost linearly with time. The fingers did not grow laterally after the tip of the finger had passed. The average finger diameters were between 3.9 and 5.4 mm for PCE propagation in water-saturated glass bead porous media with mean particle diameters from 0.32 to 1.36 mm. The estimated mobile core diameters were 51–60% of the average finger diameters.     

Hydrothermal carbonization of food waste and associated packaging materials for energy source generation

Hydrothermal carbonization (HTC) is a thermal conversion technique that converts food wastes and associated packaging materials to a valuable, energy-rich resource. Food waste collected from local restaurants was carbonized over time at different temperatures (225, 250 and 275 °C) and solids concentrations to determine how process conditions influence carbonization product properties and composition. Experiments were also conducted to determine the influence of packaging material on food waste carbonization. Results indicate the majority of initial carbon remains integrated within the solid-phase at the solids concentrations and reaction temperatures evaluated. Initial solids concentration influences carbon distribution because of increased compound solubilization, while changes in reaction temperature imparted little change on carbon distribution. The presence of packaging materials significantly influences the energy content of the recovered solids. As the proportion of packaging materials increase, the energy content of recovered solids decreases because of the low energetic retention associated with the packaging materials. HTC results in net positive energy balances at all conditions, except at a 5% (dry wt.) solids concentration. Carbonization of food waste and associated packaging materials also results in net positive balances, but energy needs for solids post-processing are significant. Advantages associated with carbonization are not fully realized when only evaluating process energetics. A more detailed life cycle assessment is needed for a more complete comparison of processes.     

高温烟气除尘用纤维滤料研究进展

本文对上程上高温烟气来源进行了分类，对当前高温烟气过滤的核心技术的耐高温过滤材料的使用现状进行了分析，对高温玄武岩纤维过滤材料进行了重点探讨与展望，指出玄武岩纤维滤材当前在高温烟气过滤行业中急需解决的问题和产业科技成果转化方向。     

An analysis of variables influencing the material composition of automobiles

The use of materials is studied broadly, because of the environmental problems related to extraction, production, consumption and waste treatment. The use and substitution of materials in products is therefore a relevant issue for environmental policy making. Studies have been done to describe the material flow or to measure the impact of materials or products on the environment. However, these studies do not often consider economic, substitution and dynamic aspects of material flows. Other studies on material flows analyse the relationship between the use of materials and economic growth, but they do not consider substitution between materials. For environmental policy making economic, technological and environmental aspects of the use of materials need to be considered. Especially, substitution of materials is important. In various countries material and product policies are imposed on a variety of materials and products. For evaluation of these policies their environmental and economic effects need to be examined in detail. This study aims to analyse the economic and technological factors influencing the use of materials and the substitution between different materials dynamically. The goal is to obtain an insight in the effect that material levies may have on the use and substitution of materials. The statistical analysis is performed on a specific product-group because decisions on the use of materials are taken on a product-level. The case study is performed on automobiles. The results show that the material use is largely an autonomous development. The price of aluminium has a positive, significant effect on the use of that material. The price of plastics has a positive, but not significant effect on the use of plastics. Reasons may be that the costs of a raw material are small relative to the processing costs, and that the production process can only be changed slowly. Other factors, like competitiveness and consumers' tastes, may be more important for substitution. This implies that levies or subsidies on certain materials is not a promising policy to change the use of materials. Besides time, there are two other factors that have a positive and significant relationship with the use of aluminium and plastics: the fuel efficiency, which is the distance driven divided by the energy used; and, the road tax, which depends on the weight of a car. However, these effects are caused by their positive relationship with time. The main conclusion of the case study is that imposing a levy on materials may not have the desired or expected effect of reduction in material use.     

The significance of various factors for GHG emissions of buildings

The objective of the research was to create improved understanding of the significance of diverse factors for the total greenhouse gas (GHG) emissions of buildings. The specific focus of the study was on the assessment of the significance of building materials and embodied carbon. The scope of the study covers multi-storey residential buildings in Finland. This research was based on a literature survey and supported by a parametric case study. The parametric study assessed the building-material-related GHG emissions relative to total GHG emissions and the possible range of variation. The research assesses the minimum and maximum GHG emissions for production of buildings with similar spaces, to reveal the likely range of variation for the emissions. The calculations for the ‘minimum’ and ‘maximum’ scenarios assume a similar purpose of use, occupancy and spaces in the building, while the production methods, materials, site conditions and location are varied. The research also assesses the relative importance of various building components and other calculation parameters in terms of GHGs. Total material-related GHG emissions were compared with the GHG emissions caused by the operation of the building, at three distinct levels of energy performance. In addition, the material- and operation-related GHG emissions were compared with the location-related GHG emissions arising from people's mobility.     

水体冻结过程中荧光物质的迁移转化研究

本研究利用荧光区域积分法考察了在水体冻结过程中,溶解性有机物(DOM)组分中荧光物质的迁移转化.同时,利用XAD树脂,将DOM分为3个部分:疏水性有机酸(HPO-A)、过渡亲水性有机酸(TPI-A)和亲水性有机物(HPI).结果表明,在水体冻结过程中,HPO-A、TPI-A和HPI的DOC浓度在水相中逐渐增加,而在冰相中先减少后增加,并且这3种DOM组分在冰、水两相间的分配系数排序为:HPITPI-AHPOA.在水体冻结过程中,水相中HPO-A和HPI的总累计荧光强度(ΦT,n)值,以及冰相中3种DOM组分的总ΦT,n值随冻结时间的变化趋势均为先降低后升高.在水体冻结过程中,水相中3种DOM组分的类腐殖酸荧光峰发生蓝移.冻融作用导致HPO-A和HPI的荧光性降低.与HPO-A和HPI相比,TPI-A的荧光性受冻融作用的影响相对较小.此外,在4类荧光物质中,冻融作用对DOM组分中的类富里酸荧光物质和类腐殖酸荧光物质的影响较显著.