废印刷线路板处置和非金属回收利用研究进展

废印刷线路板的资源化处置一直是电子废弃物处理的热点和难点,目前有多种方法已经投入应用或者在研究阶段,这些方法在分离效率、回收率、操作简单性、本身环境友好性、有无二次污染等方面有不同的优缺点。目前主流的广泛采用的方法是分步处理,破碎后利用物理方法进行分选,得到的金属和非金属组分再分别进行进一步的回收利用。本文对近年来废印刷线路板的总体处置技术和物理分选后非金属的回收利用的研究进行了总结,并对将来的研究方向进行了展望,为废印刷线路板资源化再利用产业化发展提供参考。     

火灾自动保护型漏电断路器的应用试验

介绍了新型火灾自动保护型漏电断路器的工作原理、功能和试验情况.该漏电断路器既能解决人身电击保护的问题,又有自动防止电气火灾的功能,推广应用前景广阔.     

Water Security in Uzbekistan: Implication of Return Waters on the Amu Darya Water Quality

- DOI: http://dx.doi.org/10.1065/espr2006.01.007 Goal, Scope and Background Amu Darya river, one of the main water resources of Uzbekistan, shows a relevant longitudinal enrichment of soluble contents which strongly limits the human uses of its waters. Because of the low natural run-off processes, salts and pollutants are mainly driven to the river by the return waters used for washing and irrigating the surrounding lands. The influence of return waters on stream quality is dramatically relevant in the lower reaches of the river where almost all the flowing waters have been previously used for the agriculture practises. To provide analytical evidence on the potential effects of return waters on the quality of the Amu Darya river, the paper reports and comments data on salinity and metals contents of the waters flowing in the artificial channel network of Bukhara and in the Amu Darya river, from Bukhara up to the dam forming the Tuyamuyn Hydro Complex (THC). Methods A total of 15 sampling sites were selected for the analytical survey: Two sites were located on the Amu Darya river downstream from the inflow of the return waters from Bukhara, two in the river entering in the THC, and three downstream from the dam forming the reservoir complex. The waters entering and leaving the Bukhara agricultural area were sampled in two main collectors, while the waters flowing in the channel system were sampled in six distinct collectors. The following parameters were considered in the survey: pH, Oxygen, Hardness, Salinity, Conductivity, P-PO4 3–, P tot, N tot, N-NO3 2–, N-NO2 –, COD, Ca2+, Mg2+, Fe, Mn, Zn, Cr, Cu, Ni, Cd, Pb. Results and Discussion Salt concentrations below 1000 mg/l were measured in the Amu Darya waters upstream to Bukhara. In the drainage system, salinity exceeds the palatability limit and reaches the maximum peak of 3200 mg/l in the outflow collector. Due to dilution effects, salinity returns to lower values (400–700 mg/l) along the Amu Darya river downstream from Bukhara; calcium and magnesium resulted the major constituents of the overall salinity. No serious metal contaminations were detected in the waters entering and leaving the examined channel system. Differently, the Amu Darya waters upstream to the THC showed a relevant metal contamination, with Cr, Ni, Fe concentrations exceeding the limits for human consumption. In the downstream sites, located in the Tuyamuyn Hydro Complex and in the Amu Darya river flowing out from this reservoir, excluding Fe, all the examined metals showed lover concentrations and values below the normative limits. Conclusion The direct human consumption of the lower Amu Darya waters is strongly limited by salinity and by metal contamination. Although the salinity of the return waters from the Bukhara drainage system results in above normal limits, no corresponding increases were measured in the Amu Darya river downstream from the return water inflow at the time of the survey. As for the metal contamination of the Amu Darya river, the survey revealed the presence of relevant sources of metal contamination downstream from Bukhara external to the agricultural drainage system. This contamination resulted in reduced sedimentation processes taking place in the limnetic zones of the Amu Darya river upstream to the dam forming the Tuyamuyn Hydro Complex. Recommendation and Outlook To fully understand the longitudinal increase of Amu Darya salinity, an evaluation of the cumulative effects of the loads from the main agricultural areas is required, also by using mass-balance models. As for the metals, an investigation should be addressed to identify the anthropogenic sources of contaminations present in the lower Amu Darya region and the metal loads should be diverted.     

Info-Gap Decision Theory for Assessing the Management of Catchments for Timber Production and Urban Water Supply

While previous studies have examined how forest management is influenced by the risk of fire, they rely on probabilistic estimates of the occurrence and impacts of fire. However, nonprobabilistic approaches are required for assessing the importance of fire risk when data are poor but risks are appreciable. We explore impacts of fire risk on forest management using as a case study a water catchment in the Australian Capital Territory (ACT) (southeastern Australia). In this forested area, urban water supply and timber yields from exotic plantations are potential joint but also competing land uses. Our analyses were stimulated by extensive wildfires in early 2003 that burned much of the existing exotic pine plantation estate in the water catchment and the resulting need to explore the relative economic benefits of revegetating the catchment with exotic plantations or native vegetation. The current mean fire interval in the ACT is approximately 40 years, making the establishment of a pine plantation economically marginal at a 4% discount rate. However, the relative impact on water yield of revegetation with native species and pines is very uncertain, as is the risk of fire under climate change. We use info-gap decision theory to account for these nonprobabilistic sources of uncertainty, demonstrating that the decision that is most robust to uncertainty is highly sensitive to the cost of native revegetation. If costs of native revegetation are sufficiently small, this option is more robust to uncertainty than revegetation with a commercial pine plantation.     

碳电极直径与负载特性对故障电弧断路器响应时间影响研究*

为解决故障电弧断路器动作响应滞后、效率低等问题，基于电气火灾多发原因与防控实验装置、功率因素可调式负载柜，搭建故障电弧模拟实验台，研究故障电弧断路器响应时间影响因素，利用功率分析仪统计断路器响应时间。研究结果表明:纯电阻电路中，断路器响应时间随碳电极直径增大而缩短；在负载功率P=800,2 000 W条件下，碳电极直径D≥2 mm时,断路器瞬时保护率达100%;负载功率P=3 200 W时,断路器瞬时保护率小于50%；碳电极直径D为1,2 mm时，断路器最佳负载功率保护区间分别为［1 200,1 600］ W,［800,2 400］ W，碳电极直径为2 mm的保护区间范围较宽，安全可靠性更高；感性电路中，断路器响应时间随功率因数减小而延迟，功率因数对断路器动作响应时间的影响随负载功率增加而降低。研究结果可为故障电弧断路器响应时间的设定提供参考。     

Self-catalytic pyrolysis thermodynamics of waste printed circuit boards with co-existing metals

● The co-existing metals in WPCBs has positive catalytic influence in pyrolysis. ● Cu, Fe, Ni can promote reaction progress and reduce the apparent activation energy. ● Ni play better role in promoting WPCB pyrolysis reaction. Waste printed circuit boards (WPCBs) are generated increasingly recent years with the rapid replacement of electric and electronic products. Pyrolysis is considered to be a potential environmentally-friendly technology for recovering organic and metal resources from WPCBs. Thermogravimetric analysis and kinetic analysis of WPCBs were carried out in this study. It showed that the co-existing metals (Cu, Fe, Ni) in WPCBs have positive self-catalytic influence during the pyrolysis process. To illustrate their catalytic effects, the apparent activation energy was calculated by differential model. Contributions of different reactions during catalytic pyrolysis process was studied and the mechanism function was obtained by Šesták-Berggren model. The results showed that Cu, Fe, Ni can promote the reaction progress and reduce the apparent activation energy. Among the three metals, Ni plays better catalytic role than Cu, then Fe. This work provides theoretical base for understanding the three metals’ catalytic influence during the pyrolysis of non-metal powders in WPCBs.