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41.
《Journal of environmental science and health. Part. B》2012,47(11):906-914
AbstractWe investigated the adsorption of glyphosate onto five subtropical soils of Paraná and São Paulo states, Brazil, a region of intense agricultural activities, aiming at the determination of kinetic and isotherm adsorption parameters which enable the evaluation of the potential leaching of the herbicide. The adsorption was fast, being described by the pseudo-second order and intraparticle diffusion models, thus suggesting that mixed mechanisms are involved. The Oxisol containing the highest concentrations of metal oxides (209.5?g kg?1 Fe2O3 and 160.2?g kg?1 Al2O3) was the sample with the highest rate constant, indicating the adsorption sites are readily available. All the soils are rich in aluminum and iron oxides, explaining the Freundlich coefficients (KF) between 642 and 1360?mg1-1/n kg?1 L1/n, which are higher than most of the coefficients described for other soils around the world. The maximum desorption (15% of the adsorbed amount) was observed for the Oxisol. For the other soils, desorption ranged from 2 to 7%. These results suggest that the leaching of free glyphosate to nearby surface and groundwaters is unlikely unless excessive doses are used. The adsorption parameters are useful for managing the right doses applied to the crops, thus avoiding contamination of adjacent areas. 相似文献
42.
Faranak Hadi Amir Mousavi Kambiz Akbari Noghabi Hadi Ghaderi Tabar Ali Hatef Salmanian 《Journal of environmental science and health. Part. B》2013,48(3):208-213
Thirty bacterial strains with various abilities to utilize glyphosate as the sole phosphorus source were isolated from farm soils using the glyphosate enrichment cultivation technique. Among them, a strain showing a remarkable glyphosate-degrading activity was identified by biochemical features and 16S rRNA sequence analysis as Ochrobactrum sp. (GDOS). Herbicide (3 mM) degradation was induced by phosphate starvation, and was completed within 60 h. Aminomethylphosphonic acid was detected in the exhausted medium, suggesting glyphosate oxidoreductase as the enzyme responsible for herbicide breakdown. As it grew even in the presence of glyphosate concentrations as high as 200 mM, Ochrobactrum sp. could be used for bioremediation purposes and treatment of heavily contaminated soils. 相似文献
43.
Effect of long-term changes in soil chemistry induced by road salt applications on N-transformations in roadside soils 总被引:2,自引:0,他引:2
Of several impacts of road salting on roadside soils, the potential disruption of the nitrogen cycle has been largely ignored. Therefore the fates of low-level ammonium-N and nitrate-N inputs to roadside soils impacted by salting over an extended period (decades) in the field have been studied. The use of road salts disrupts the proportional contributions of nitrate-N and ammonium-N to the mineral inorganic fraction of roadside soils. It is highly probable that the degree of salt exposure of the soil, in the longer term, controls the rates of key microbial N transformation processes, primarily by increasing soil pH. Additional influxes of ammonium-N to salt-impacted soils are rapidly nitrified therefore and, thereafter, increased leaching of nitrate-N to the local waterways occurs, which has particular relevance to the Water Framework Directive. The results reported are important when assessing the fate of inputs of ammonia to soils from atmospheric pollution. 相似文献
44.
Jörg Luster Manoj Menon Sandra Hermle Rainer Schulin Madeleine S. Günthardt-Goerg Bernd Nowack 《Water, Air, & Soil Pollution: Focus》2008,8(2):163-176
Soil translocation for recultivation of soil removed from construction sites and for the preparation of refilled lysimeters
inevitably involves disturbance of soil structure, and, if intermediate storage is included, also drying and rewetting of
the soil. We report on an experiment with model forest ecosystems, where uncontaminated forest subsoils were covered with
non-contaminated or freshly heavy metal (mainly Zn and Cu) contaminated topsoil in large lysimeters. Monitoring of the chemical
composition of the drainage water revealed two distinct soil conditioning phases. During an initial phase of about a year
strongly elevated nitrate and sulfate concentrations occurred that were attributed to a mineralisation flush caused by the
increased accessability of mineralisable nitrogen and sulfur in destroyed aggregates. These effects were significantly larger
in lysimeters with calcareous subsoil than in those with acidic subsoil. The second phase was characterised by a gradual decrease
in dissolved organic carbon and sulfate concentrations, in particular in the acidic subsoil. This decrease may be attributed
to the depletion of pools made accessible during aggregate destruction or the formation of new aggregates. These chemical
changes had only little effects on the concentrations of copper and zinc in the drainage water. Based on our results, it can
be concluded that large refilled lysimeters can be used for many purposes without risk of compromised results, if a conditioning
phase of about 1 year with sufficiently moist soil conditions is respected. Nevertheless, gradual changes in soil chemical
characteristics still occur after this initial phase. Implications for the recultivation of sites using relocated soils are
discussed. 相似文献
45.
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48.
Schaefer CE do Amaral EF de Mendonça BA Oliveira H Lani JL Costa LM Fernandes Filho EI 《Environmental monitoring and assessment》2008,140(1-3):279-289
The relationships between soils attributes, soil carbon stocks and vegetation carbon stocks are poorly know in Amazonia, even
at regional scale. In this paper, we used the large and reliable soil database from Western Amazonia obtained from the RADAMBRASIL
project and recent estimates of vegetation biomass to investigate some environmental relationships, quantifying C stocks of
intact ecosystem in Western Amazonia. The results allowed separating the western Amazonia into 6 sectors, called pedo-zones:
Roraima, Rio Negro Basin, Tertiary Plateaux of the Amazon, Javari-Juruá-Purus lowland, Acre Basin and Rondonia uplands. The
highest C stock for the whole soil is observed in the Acre and in the Rio Negro sectors. In the former, this is due to the
high nutrient status and high clay activity, whereas in the latter, it is attributed to a downward carbon movement attributed
to widespread podzolization and arenization, forming spodic horizons. The youthful nature of shallow soils of the Javari-Juruá-Purus
lowlands, associated with high Al, results in a high phytomass C/soil C ratio. A similar trend was observed for the shallow
soils from the Roraima and Rondonia highlands. A consistent east–west decline in biomass carbon in the Rio Negro Basin sector
is associated with increasing rainfall and higher sand amounts. It is related to lesser C protection and greater C loss of
sandy soils, subjected to active chemical leaching and widespread podzolization. Also, these soils possess lower cation exchangeable
capacity and lower water retention capacity. Zones where deeply weathered Latosols dominate have a overall pattern of high
C sequestration, and greater than the shallower soils from the upper Amazon, west of Madeira and Negro rivers. This was attributed
to deeper incorporation of carbon in these clayey and highly pedo-bioturbated soils. The results highlight the urgent need
for refining soil data at an appropriate scale for C stocks calculations purposes in Amazonia. There is a risk of misinterpreting
C stocks in Amazonia when such great pedological variability is not taken into account. 相似文献
49.
通过监测和田地区生态修复项目实施后所取得生态效益的结果表明,生态修复项目实施后,由于项目区风速降低,温度和相对湿度的变化减少,提高了植被盖度,降低了风蚀量,促进了成土作用的进行,从而逐渐改善了土壤的理化性质。 相似文献
50.
铅冶炼区土壤重金属总量和有效态含量的函数分析 总被引:1,自引:0,他引:1
采集铅冶炼企业周边3 000 m范围内220个表层土壤样品,测定了有毒有害元素铅、镉、砷和汞的总量和有效态含量,探讨了它们之间的关系。结果表明:研究区土壤受到汞、砷、铅、镉的污染依次明显严重,土壤重金属的总量和有效态含量的变异系数均大于100%,土壤镉、铅、汞、砷的生物有效性系数平均值分别为25.9%、17.2%、0.58%、0.11%。土壤铅、镉和砷的总量与其有效态含量呈显著正相关(P0.001),而汞的总量与其有效态含量的相关性不显著(P0.05)。土壤铅和镉的总量和有效态含量可以用直线函数和幂函数表达,函数反推的有效态值和对应统计值的变异系数不大于10%。 相似文献