延边地区水稻稳产高产施肥体系的探讨

采用二次饱和D-最优设计,建立了有机肥、氮肥、磷肥和钾肥配合施用对水稻产量影响的数学模型.研究表明有机肥施用量的过多或过少均使水稻产量下降,化肥的施用也有相似的影响;有机肥与氮肥、磷肥、钾肥只有施用量在适宜的范围内,交互作用较大,产量最高.提出了延边地区水稻获得稳产、高产的施肥体系.     

秸秆腐解剂在秸秆还田中的效果研究初报

在大田、微区和盆栽条件下,研究了秸秆腐解剂对小麦、水稻生长及产量的影响,同时研究了秸秆腐解剂对小麦、水稻秸秆腐解速率及对土壤肥力的影响。结果表明,稻、麦秸秆还田时施用秸秆腐解剂对提高稻、麦产量具有明显的增产效果,增产的原因是穗数和粒数增加;稻、麦秸秆还田量不同时,还田量大且配施秸秆腐解剂的效果较还田量小好;麦秸秆还田方式不同时,麦秸以栽稻前耕翻还田且配施秸秆腐解剂的效果较好,上水沤制的效果较差;秸秆腐解剂能促进稻、麦秸秆较快腐解,减轻和防止多量秸秆还田给作物生长带来不利影响,并可稳定和提高土壤养分含量。     

Penicillin fermentation residue biochar as a high-performance electrode for membrane capacitive deionization

● We have provided an activated method to remove the toxicity of antibiotic residue. ● PFRB can greatly improve the salt adsorption capacity of MCDI. ● The hierarchical porous and abundant O/N-doped played the key role for the high-capacity desalination. ● A new field of reuse of penicillin fermentation residue has been developed. Membrane capacitive deionization (MCDI) is an efficient desalination technology for brine. Penicillin fermentation residue biochar (PFRB) possesses a hierarchical porous and O/N-doped structure which could serve as a high-capacity desalination electrode in the MCDI system. Under optimal conditions (electrode weight, voltage, and concentration) and a carbonization temperature of 700 °C, the maximum salt adsorption capacity of the electrode can reach 26.4 mg/g, which is higher than that of most carbon electrodes. Furthermore, the electrochemical properties of the PFRB electrode were characterized through cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) with a maximum specific capacitance of 212.18 F/g. Finally, biotoxicity tests have showed that PFRB was non-biotoxin against luminescent bacteria and the MCDI system with the PFRB electrode remained stable even after 27 adsorption–desorption cycles. This study provides a novel way to recycle penicillin residue and an electrode that can achieve excellent desalination.     

Development of an analytical method for analysis of flubendiamide,des-iodo flubendiamide and study of their residue persistence in tomato and soil

Flubendiamide is a new insecticide that has been found to give excellent control of lepidopterous pests of tomato. This study has been undertaken to develop an improved method for analysis of flubendiamide and its metabolite des-iodo flubendiamide and determine residue retention in tomato and soil. The analytical method developed involved extraction of flubendiamide and its metabolite des-iodo flubendiamide with acetonitrile, liquid-liquid partitioning into hexane-ethyl acetate mixture (6:4, v v^?1) and cleanup with activated neutral alumina. Finally the residues were dissolved in gradient high pressure liquid chromatography (HPLC) grade acetonitrile for analysis by HPLC. The mobile phase, acetonitrile-water at 60:40 (v v^?1) proportion and the wavelength of 235 nm gave maximum peak resolution. Using the above method and HPLC parameters described, nearly 100 % recovery of both insecticides were obtained. There was no matrix interference and the limit of quantification (LOQ) of the method was 0.01 mg kg^?1. Initial residue deposits of flubendiamide on field-treated tomato from treatments @ 48 and 96 g active ingredient hectare^?1 were 0.83 and 1.68 mg kg^?1,respectively. The residues of flubendiamide dissipated at the half-life of 3.9 and 4.4 days from treatments @ 48 and 96 g a.i. ha^?1, respectively and persisted for 15 days from both the treatments. Des-iodo flubendiamide was not detected in tomato fruits at any time during the study period. Residues of flubendiamide and des-iodo flubendiamide in soil from treatment @ 48 and 96 g a.i. ha^?1 were below detectable level (BDL, < 0.01 mg kg^?1) after 20 days. Flubendiamide completely dissipated from tomato within 20 days when the 480 SC formulation was applied at doses recommended for protection against lepidopterous pests.     

Sugarcane vinasse: Environmental implications of its use

The inadequate and indiscriminate disposal of sugarcane vinasse in soils and water bodies has received much attention since decades ago, due to environmental problems associated to this practice. Vinasse is the final by-product of the biomass distillation, mainly for the production of ethanol, from sugar crops (beet and sugarcane), starch crops (corn, wheat, rice, and cassava), or cellulosic material (harvesting crop residues, sugarcane bagasse, and wood). Because of the large quantities of vinasse produced, alternative treatments and uses have been developed, such as recycling of vinasse in fermentation, fertirrigation, concentration by evaporation, and yeast and energy production. This review was aimed at examining the available data on the subject as a contribution to update the information on sugarcane vinasse, from its characteristics and chemical composition to alternatives uses in Brazil: fertirrigation, concentration by evaporation, energy production; the effects on soil physical, chemical and biological properties; its influence on seed germination, its use as biostimulant and environmental contaminant. The low pH, electric conductivity, and chemical elements present in sugarcane vinasse may cause changes in the chemical and physical–chemical properties of soils, rivers, and lakes with frequent discharges over a long period of time, and also have adverse effects on agricultural soils and biota in general. Thus, new studies and green methods need to be developed aiming at sugarcane vinasse recycling and disposal.     

Limitations in the determination of maximum residue limits and highest residues of pesticides: Part I

The pesticide usages are controlled by comparing residue concentrations in treated commodities to legally permitted maximum levels (MRLs) determined based on supervised trials designed to reflect likely maximum residues occurring in practice following authorised use. The number of trials available may significantly affect the accuracy of estimated maximum residues. We conducted a study with synthetic lognormal distributions with mean of 1 and standard deviations of 0.8 and 1.0, which reflect the residue distributions observed in practice. The likely residues in samples were modelled by drawing random samples of size 3, 5, 10 and 25 from the synthetic populations. The results indicate that the estimations of highest residues (HR), used for calculation of short-term intake, and the MRLs, serving as legal limits, are very uncertain based on 3–5 trials indicated by the calculated HR_0.975/HR_0.025 and MRL_0.975/MRL_0.025 ratios of 12 and 9, and 13 and 10, respectively, which question the suitability of such trials for the intended purpose. As the 95% range of HR and MRL rapidly decreases with number of trials, ideally ≥15 but minimum 6–8 trials should be used for estimation of HR and MRL according to the current typical practice of Codex Alimentarius.     

生物有机除草剂防除水田杂草试验研究

采用田间试验方法,进行了生物稻壳粉、生物稻草粉2种生物有机除草剂对水田杂草的防效试验。结果表明,2种生物有机除草剂对水田杂草均有不同程度的防效,其中生物稻壳粉防效最好、经济效益最高,生物稻草粉防效和经济效益次之。该试验研究为生产有机水稻提供了新的除草方法。     

水稻“早育间作”技术与结果分析

本文以提高光热资源利用率、人工改变秧田微气候条件，提早中稻播期为突破口，辅之以提早移栽期和间种优质懦稻等系列配套技术措施，促成了前季中稻的早熟、高产、早收，同时又为后季再生稻创造了必要的时间和温光条件，从而使水稻单产提高２０％以上。     

酸法锂渣制取白炭黑研究

本文对用硫法锂渣制取白炭黑的基本原理及工艺流程作了较为详细的阐述，对该工艺的各种影响因素进行了探讨，并制得了合格的白炭黑，为锂渣的综合利用开辟了新的途径。     

SIMULATION OF HERBICIDE CONCENTRATIONS IN STORMFLOW FROM FORESTED WATERSHEDS1

The breakpoint rainfall hydrology and pesticide options of the field scale model CREAMS (Chemicals, Runoff, and Erosion from Agricultural Management Systems) were used to predict average concentrations of hexazinone [3 cyclohexyl-6-(dimethyl-amino)-1-methyl-1,3,5-triazine-2,4(1H,3H)-dione] in stormflow from four forested watersheds in the upper Piedmont region of Georgia. Predicted concentrations were compared with measured concentrations recorded over a 13-month period. CREAMS accurately predicted hexazinone concetrations in the initial stormflow events which also contained the highest concentrations. The model underestimated the hexazinone concentrations in stormflow two months and greater following pesticide application. In a companion study, the daily rainfall option of the CREAMS model was used to evaluate the reltive risk associated with the maximum expected concentration of hexazinone, bromacil (5-bromo-3 sec-butyl-6 methyuracil), picloram (4-amino-3,5,6 trichloropicolinic acid), dicamba (3,6-dichloro-0-anisic acid), and triclopyr {[(3,5,6-trichloro-2-pyridinyl)oxy] acetic acid} in stormflow from small forested watersheds. The model predicted the following order of potential residue appearance in stormflow: bromacil>triclopyr>hexazinone>picloram>dicamba. Subsurface movement of residues via interflow and deep leaching losses are not simulated by the version of CREAMS used in these studies.