An analytical procedure involving a three-step sequential extraction was used to determine the chemical association of heavy metals (Zn, Cr, Mn and Fe) with the major phases (exchangable, reducible and oxidizable) in samples from a fishpond of estuarine sediments. The pond is located in the Capibaribe River estuary, within the boundaries of the city of Recife, in the State of Pernambuco in the northeast of Brazil. The total metal content was determined as well. All metals were extracted from the residual fraction at a percentage greater than 50%. 相似文献
Determination of triazines herbicides (atrazine and simazine) by high performance liquid chromatography (HPLC) in samples of trophic chain were worked out. Determination limits of 0.5 μg g−1 for atrazine, 0.8 μg g−1 for simazine with pesticides recovery of 70–77% in trophic chain samples were obtained. The content of simazine in soils was in range 1.72–57.89 μg g−1, in grass 5–88 μg g−1, in milk 2.32–15.29 μg g−1, in cereals 10.98–387 μg g−1, in eggs 30.14–59.48 μg g−1, for fruits: 2.45–6.19 μg g−1. The content of atrazine in soils was in range 0.69–19.59 μg g−1, in grass 7.85–23.85 μg g−1, in cereals 1.88–43.08 μg g−1. Cadmium, lead and zinc were determined by inductively coupled plasma atomic emission spectrometry (ICP-AES) in the same samples as atrazine and simazine. Determination limits for cadmium 5 × 10−3 μg g−1, for lead 1 × 10−2 μg g−1, and for zinc 0.2 × 10−3 μg g−1, were obtained. The content of cadmium in soil was in range 0.13–5.89 μg g−1, in grass 114–627.72 × 10−3 μg g−1, in milk 8.88–61.88 × 10−3 μg g−1, in cereals 0.20–0.31 μg g−1, in eggs 0.11–0.15 μg g−1, in fruits 0.23–0.59 μg g−1. The content of lead in soils was in range 0.57–151.50 μg g−1, in grass 0.16–136.57 μg g−1, in milk 1.16–3.74 μg g−1, in cereals 1.05–5.47 μg g−1, in eggs 5.79–55.87 μg g−1, in fruits 21.00–87.36 μg g−1. Zinc content in soil was in range 9.15–424.5 μg g−1, in grass 35.20–55.87 μg g−1, in milk 20.00–34.38 μg g−1, in cereals 14.94–28.78 μg g−1, in eggs 15.67–32.01 μg g−1, in fruits 14.94–18.88 μg g−1.
Described below extraction and mineralization methods for particular trophic chains allowed to determine of atrazine, simazine, cadmium, lead and zinc with good repeatability and precision. Emphasis was focused on liquid–liquid extraction and solid-phase extraction of atrazine and simazine from analysed materials, as well as, on monitoring the content of herbicides and metals in soil and along trophic chain. Higher concentration of pesticides in samples from west region of Poland in comparison to that of east region is likely related to common applying them in Western Europe in relation to East Europe. The content of metals strongly depends on samples origin (industry area, vicinity of motorways). 相似文献
以深圳市某污水处理厂的污泥为原料,研究了污泥热解过程产生的颗粒物及其中8种重金属的分布规律.结果表明,颗粒物的生成速率分别在400~600℃和1000℃保温30min的两个区间内达到峰值.8种重金属的热挥发性由大到小依次为Cd > Zn > As > Pb > Mn > Ni > Cu > Cr,而其在颗粒物中富集能力大小顺序为Pb > As > Mn > Zn > Cd > Ni > Cr > Cu.颗粒物重金属在热解气中的体积浓度随热解过程呈上升趋势,Zn和Cd则在升温阶段(1000℃以前)达到峰值后开始降低.研究表明,污泥热解颗粒物富集的重金属超标,因而污泥热解尾气颗粒物的去除装置十分必要. 相似文献