过氧化聚吡咯/聚乙烯吡咯烷酮修饰碳糊电极测定废水中苯酚

建立了过氧化聚吡咯(OPPy)和聚乙烯吡咯烷酮(PVP)修饰碳糊电极测定废水中苯酚的方法.优化了试验条件,苯酚的氧化峰电流在1.0×10-5 mol/L～1.0×10-3 mol/L之间线性关系良好,检出限为1.0×10-6 mol/L.该电极制作简单,选择性好,测定灵敏度高,精密度与准确度均符合要求.     

福建省森林固定CO2价值评估

借鉴国内外研究成果,引入“市场逼近系数”,构造森林固定CO2效益经济结构模型,评估福建省森林固定CO2价值,为福建省森林资源的科学管理和资产评估提供了借鉴和参考。     

Potential for carbon sequestration in Canadian forests and agroecosystems

The potential for carbon (C) sequestration was examined in selectedCanadian forest settings and prairie agroecosystems under severalmanagement scenarios. A simple C budget model was developed toquantitatively examine C sequestration potential in living biomass of forestecosystems, in associated forest-product C pools, and in displaced fossil-fuelC. A review of previous studies was conducted to examine C sequestrationpotential in prairie agroecosystems. In the forest settings examined, ourwork suggests that substantial C sequestration opportunities can be realizedin the short term through the establishment of protected forest-C reserves.Where stands can be effectively protected from natural disturbance, peaklevels of biomass C storage can exceed that under alternative managementstrategies for 200 years or more. In settings where it is not feasible tomaintain protected forest-C reserves, C sequestration opportunities can berealized through maximum sustained yield management with harvestedbiomass put towards the displacement of fossil fuels. Because there is afinite capacity for C storage in protected forest-C reserves, harvesting forestbiomass and using it to displace the use of fossil fuels, either directlythrough the production of biofuels or indirectly through the production oflong-lived forest products that displace the use of energy-intensive materialssuch as steel or concrete, can provide the greatest opportunity to mitigategreenhouse gas emissions in the long term. In Canadian prairieagroecosystems, modest C sequestration can be realized while enhancingsoil fertility and improving the efficiency of crop production. This can bedone in situations where soil organic C can be enhanced without relianceupon ongoing inputs of nitrogen fertilizer, or where the use of fossil fuelsin agriculture can be reduced. More substantial C offsets can be generatedthrough the production of dedicated energy crops to displace the use offossil fuels. Where afforestation or reconstruction of native prairieecosystems on previously cultivated land is possible, this represents thegreatest opportunity to sequester C on a per unit-area basis. However,these last two strategies involve the removal of land from crop production,and so they are not applicable on as wide a scale as some other Csequestration options which only involve modifications to currentagricultural practices.     

LPWCO method for the treatment of high concentrated organic wastewater

Based on wet air oxidation (WAO) and Fenton reagent, thispaper raises a new low pressure wet catalytic oxidation(LPWCO)which requires low pressure for the treatment of highlyconcentrated and refractory organic wastewater. Compared withgeneral wet air oxidation, the pressure of the treatment(0.1-0.6MPa) is only one of tens to percentage of latter(3.5-10MPa). Inaddition, its temperature is no more than 180℃.Compared withFenton reagent, while H2O2/COD(weight ratio) less than 1.2, theremoval of COD in the treatment is over twenty percents more thanFenton's even the value of COD is more than 14000mg/L. In thispaper, we study the effect factor of COD removal and the mechanismof this treatment. The existence of synergistic effect (catalytic oxidation and carbonization) for COD removal in H2SO4-Fenton reagent system under the condition of applied pressure and heating (0.1-0.6MPa, 104-165℃) was verified. The best condition of this disposal are as follows:H2O2/COD(weight ratio)=0.2-1.0, Fe2+ 0.6×10-3 mol, H2SO4 0.5mol, COD>1×104mg/L, the operating pressure is 0.1-0.6MPa and temperature is 104-165℃. This method suit to dispose the high-concentrated refractory wastewater, especially to the wastewater containing H2SO produced in the manufacture of pesticide, dyestuff and petrochemical works.     

滇池细菌总数与有机碳、氮、磷的调查研究

通过对滇池水体一年多的定点采样工作,重点调查研究了草海、外海表层水中细菌数量及有机营养盐碳、氮、磷的季节变化规律,分析探讨了细菌总数与环境条件和有机营养盐之间的某些关系.对滇池富营养治理提出了一些建议,并提出利用微生物学的方法参与这一研究.     

高级氧化技术机理及在水处理中的应用进展

综述了近年来发展迅速的高级氧化技术，主要包括Fenton法、臭氧氧化法、湿式氧化技术、超临界水氧化法、纳米光催化氧化法电化学催化降解法及超声降解法等。介绍了各种高级氧化技术的基本原理及在废水处理中的应用进展，并对其特点进行了评述。     

九龙江流域水体有机污染物背景调查方法

阐述了九龙江流域水体有机污染物背景调查的重要性和必要性,比较详细地论述了调查方案的制定方法、分析方法的确立、监测过程中的质量控制和质量保证措施等。     

SBR法处理中药材有机废水工艺研究

应用ＳＢＲ法对中药材有机废水进行了研究。考察了ＣＯＤＣＲ、ＢＯＤ５、ＳＳ、ＮＨ３－Ｈ的处理效果，以及ＰＨ、水温、污泥负荷等条件对去除率的影响。运行结果表明，ＰＨＯ ６．０－９．０、ｔ为１５－３０℃、污沁荷０．３ｋｇＢＯＤ５／ｋｇＭＬＳＳ．ｄ，运行程序：进水０．５ｈ（限制曝气）、曝气１０ｈ、脱氮１．５ｈ，沉降０．５ｈ，排水０．５ｈ、闲置１１ｈ，周期时间２４ｈ时ＣＯＤＣＲ去除率８８％、ＢＯＤ５９４％、     

炭素行业推行清洁生产的污染物排放系数研究

推行清洁生产、减少污染物排放量，根本的方法是控制物料流失。本研究对炭素制品生产过程中的投入产出进行物料平衡测算，确定各工序物料流失总量及污染物排放系数，提出减少流失、降低排污系数的措施。     

郯庐断裂系统与中国东部幔源岩浆成因CO_2关系的初探

中国已发现的幔源岩浆成因CO2气藏主要分布在与郯庐断裂发育密切相关的东部伸展盆地，两者关系具体表现如下：1．中国东部幔源岩浆成因CO2气藏的空间展布与郯庐断裂保持一致；2．郯庐断裂切割深度达到上地幔；3．沿郯庐断裂岩浆活动强烈，且具幔源特点；4．中国东部伸展盆地自中、新生代以来的演化受郯庐断裂带活动影响。本文主要以郯庐断裂带为主线，结合幔源岩浆成因CO2气藏典型实例，从郯庐断裂构造环境、空间格局和演化过程对幔源岩浆成因CO2的控制作用进行初步归纳和分析。