Agricultural pesticide residues of farm runoff in the Okanagan Valley,British Columbia,Canada

The objectives of this study were to determine environmental occurrence and concentrations of selected currently-used-pesticides and some transformation products in agricultural farms in the Okanagan Valley (OKV), and to conduct a simple risk assessment of environmental pesticides levels detected in OKV on non-target aquatic organisms. The OKV is the tree fruit country of the Province of British Columbia where considerable amount of pesticides are applied annually. Water, sediment and soil samples were collected at eleven sites in early June and late September following rainfall events and/or extended periods of irrigation from drainage ditches and/or from small streams. Undisturbed reference sites were also sampled. Study results showed that forty of the eighty chemicals analyzed, including organochlorine, nitrogen-containing and organophosphate pesticides commonly used for OKV crops, were detected in runoff and small stream water samples. Among which, endosulfan-sulfate was the most frequently detected chemical. Also, azinophos-methyl (0.699–25.5 ng/L), diazinon (0.088–214 ng/L) exceeded, and α-, β- endosulfan, endosulfan sulphate approached the guidelines for the protection of aquatic life.     

Simulation of Surface Water for Un‐Gauged Areas with Storage‐Attenuation Wetlands1

Abstract: A nontraditional application of the Hydrological Simulation Program – FORTRAN (HSPF) model to simulate freshwater discharge to upper Charlotte Harbor along Florida’s west coast was performed. This application was different from traditional HSPF applications in three ways. First, the domain of the model was defined based on the hydraulic characteristics of the landforms using small distributed parameter discretization. Second, broad wetland land forms, representing more than 20% of this area, were simulated as reaches with storage‐attenuation characteristics and not as pervious land segments (PERLNDs). Finally, the reach flow‐tables (F‐Tables) were configured in a unique way to be calibrated representing the uncertainty of the storage‐attenuation process. Characterizing wetlands as hydrography elements allows flow from the wetlands to be treated as a stage‐dependent flux. The study was conducted for the un‐gauged portion of the Peace and Myakka rivers in west‐central Florida. Due to low gradient tidal influences, a large portion of the basin is un‐gauged. The objective of this study was to simulate stream flow discharges and to estimate freshwater inflow from these un‐gauged areas to upper Charlotte Harbor. Two local gauging stations were located within the model domain and were used for calibration. Another gauge with a shorter period of record was used for verification. A set of global hydrologic parameters were selected and tested using the parameter optimization software (PEST) during the calibration. Model results were evaluated using PEST and well‐known statistical indices. The correlation coefficients were very high (0.899 and 0.825) for the two calibration stations. Further testing of this approach appears warranted for watersheds with significant wetlands coverage.     

Superstorm Sandy and voter vulnerability in the 2012 US Presidential Election: a case study of New Jersey and Connecticut

Superstorm Sandy was an unprecedented meteorological event that devastated the Caribbean and the Northeastern Coast of the USA in October 2012. While many research efforts will focus on the atmospheric conditions that led to the creation and unusual track of the storm, this study evaluates the impact of Sandy on voter turnout in the 2012 US Presidential Election. The goals of this paper are to (1) determine if any alterations in voter turnout occurred, (2) assess the extent to which Sandy was responsible for any voter turnout changes and (3) investigate if the influence of Sandy on voter turnout was contingent upon social vulnerability. To accomplish these goals, voter turnout change between the 2008 and 2012 US Presidential Elections was analysed at the county and municipal level for both New Jersey and Connecticut. The notable decreases in voter turnout discovered in both states were likely due to the election occurring in the aftermath of Superstorm Sandy. The correlation, spatial clustering analysis, analysis of variance and multiple regression results all suggest that storm surge was more likely to be responsible for reduced voter turnout in New Jersey than in Connecticut. Specifically in New Jersey, the findings indicate that storm surge coverage, rather than height, was influential in reducing voter turnout and that this relationship was contingent upon the racial composition of the municipalities. Overall, understanding how Sandy affected voter turnout will help improve the resiliency of electoral systems to future natural disasters.     

Impact of Residential Soil Disturbance on Infiltration Rate and Stormwater Runoff1

Woltemade, Christopher J., 2010. Impact of Residential Soil Disturbance on Infiltration Rate and Stormwater Runoff. Journal of the American Water Resources Association (JAWRA) 46(4): 700-711. DOI: 10.1111/j.1752-1688.2010.00442.x Abstract: Soil disturbances such as excavation and compaction in residential developments affect lawn infiltration rates and stormwater runoff. These effects were investigated via measuring saturated infiltration rates at 108 residential sites and 18 agricultural sites near Shippensburg, south-central Pennsylvania, using a double-ring infiltrometer. Residential sites included four neighborhoods distributed across three soil series classified as hydrologic soil group (HSG) B. Additional parcel data included date of house construction, percentage impervious area, lawn condition, and woody vegetation condition. Measured infiltration rates ranged from 0 to >40 cm/hour. Analysis of variance indicated significantly different mean infiltration rates (p < 0.001) for lots constructed pre-2000 (9.0 cm/hour) and those constructed post-2000 (2.8 cm/hour). Test results were used to determine a “field-tested” HSG for each site, representing disturbed soil conditions. Stormwater runoff was estimated from residential lots for a range of 24-hour design storms using the TR-55 model and several alternative methods of determining curve numbers, including five different representations of soil conditions. Curve numbers and stormwater runoff were substantially higher when based on field-tested HSGs for lots constructed post-2000 compared with lots built pre-2000 and when based on the HSG for undisturbed soils, documenting the magnitude of possible error in stormwater runoff models that neglect soil disturbance.     

Examining Modeling Approaches for the Rainfall‐Runoff Process in Wildfire‐Affected Watersheds: Using San Dimas Experimental Forest

Wildfire can significantly change watershed hydrological processes resulting in increased risks for flooding, erosion, and debris flow. The goal of this study was to evaluate the predictive capability of hydrological models in estimating post‐fire runoff using data from the San Dimas Experimental Forest (SDEF), San Dimas, California. Four methods were chosen representing different types of post‐fire runoff prediction methods, including a Rule of Thumb, Modified Rational Method (MODRAT), HEC‐HMS Curve Number, and KINematic Runoff and EROSion Model 2 (KINEROS2). Results showed that simple, empirical peak flow models performed acceptably if calibrated correctly. However, these models do not reflect hydrological mechanisms and may not be applicable for predictions outside the area where they were calibrated. For pre‐fire conditions, the Curve Number approach implemented in HEC‐HMS provided more accurate results than KINEROS2, whereas for post‐fire conditions, the opposite was observed. Such a trend may imply fundamental changes from pre‐ to post‐fire hydrology. Analysis suggests that the runoff generation mechanism in the watershed may have temporarily changed due to fire effects from saturation‐excess runoff or subsurface storm dominated complex mechanisms to an infiltration‐excess dominated mechanism. Infiltration modeling using the Hydrus‐1D model supports this inference. Results of this study indicate that physically‐based approaches may better reflect this trend and have the potential to provide consistent and satisfactory prediction.     

Stream and Retention Pond Thermal Response to Heated Summer Runoff From Urban Impervious Surfaces1

Abstract: Runoff from parking lots during summer storms injects surges of hot water into receiving water bodies. We present temperature data collected near urban storm sewer outfalls in Blacksburg, Virginia, using arrays of sensors in a stream and a stormwater pond. Surges occurred roughly a dozen times per month, ranging up to 8.1°C with average duration 2 h in the stream and up to 11.2°C with average duration 7 h in the pond. Surges were larger in the pond due to a larger contributing watershed, no dilution by upstream water, and cool background temperatures near the outfall. Surges began abruptly, warming at rates averaging 0.2°C/min for periods of 5‐20 min. Surges dissipated as they propagated into the water bodies, travelling further in the stream (>19 m) than the pond (～10 m) consistent with greater advection in the stream. Surges were largest and most frequent in the afternoon but occurred at all times of day and night. Stream surges exhibited two phases: an early high‐temperature low‐volume input from the storm sewer and a later low‐temperature high‐volume input from upstream. Surges at the pond did not exhibit two phases, consistent with inputs only from storm sewers. Surges are likely common in urban areas, and may cumulatively have consequences for aquatic organisms, biogeochemical process rates, and even human health. Such effects may be compounded by urban heat islands and climate change, so prevention or mitigation should be considered.     

用SOS/umu试验评价降雨径流遗传毒性的变化

通过SOS/umu试验分析检测屋面和道路在2017年5、6月2场降雨过程中的遗传毒性变化。结果表明,从降雨初期到结束,在5月份屋面产生降雨径流2 h内和道路产生径流20 min内雨水样品的检测结果均呈阳性,诱导率IR均大于2,表现出DNA损伤效应;在6月份屋面产生降雨径流60 min内和道路产生径流10~60 min内雨水样品的结果均呈阳性,表现出遗传毒性。2场降雨中屋面和道路雨水样品的TEQ4-NQO均随降雨时间先增加后逐渐减小,5月份屋面雨水样品的毒性大于路面雨水样品的毒性,6月份则相反。遗传毒性分析降雨径流中污染物毒性的变化为雨水的安全利用提供理论基础。     

The Influence of Urban Density and Drainage Infrastructure on the Concentrations and Loads of Pollutants in Small Streams

Effective water quality management of streams in urbanized basins requires identification of the elements of urbanization that contribute most to pollutant concentrations and loads. Drainage connection (the proportion of impervious area directly connected to streams by pipes or lined drains) is proposed as a variable explaining variance in the generally weak relationships between pollutant concentrations and imperviousness. Fifteen small streams draining independent subbasins east of Melbourne, Australia, were sampled for a suite of water quality variables. Geometric mean concentrations of all variables were calculated separately for baseflow and storm events, and these, together with estimates of runoff derived from a rainfall-runoff model, were used to estimate mean annual loads. Patterns of concentrations among the streams were assessed against patterns of imperviousness, drainage connection, unsealed (unpaved) road density, elevation, longitude (all of which were intercorrelated), septic tank density, and basin area. Baseflow and storm event concentrations of dissolved organic carbon (DOC), filterable reactive phosphorus (FRP), total phosphorus (TP) and ammonium, along with electrical conductivity (EC), all increased with imperviousness and its correlates. Hierarchical partitioning showed that DOC, EC, FRP, and storm event TP were independently correlated with drainage connection more strongly than could be explained by chance. Neither pH nor total suspended solids concentrations were strongly correlated with any basin variable. Oxidized and total nitrogen concentrations were most strongly explained by septic tank density. Loads of all variables were strongly correlated with imperviousness and connection. Priority should be given to low-impact urban design, which primarily involves reducing drainage connection, to minimize urbanization-related pollutant impacts on streams.     

Loss of Pesticides from Agricultural Fields in SE Norway – Runoff Through Surface and Drainage Water

Loss of two pesticides with different mobility characteristics, bentazone (Koc 34) and propiconazole (Koc 1800), were studied at three agricultural fields (Askim, Bjørnebekk and Syverud) in SE Norway. A conservative tracer (Br) was used to follow the flow of water. The loss of pesticides varied among the fields, depending on hydrological characteristics and soil properties. The loss of pesticides was higher from two artificially levelled silty clay loam soils with poor aggregate stability (Askim and Bjørnebekk) compared to a loam/silt loam soil with increased content of organic carbon and better aggregate stability (Syverud). The total accumulated loss was <0.5% from all fields. The highest pesticide concentrations were measured at the first runoff episode after application for both the mobile (bentazone) and less mobile pesticide (propiconazole) in the surface runoff. In the drainage water, the peak for the less mobile pesticide coincided with the Br tracer, while the peak for mobile pesticide appeared earlier than the Br tracer. Rapid movement of water, particles and pesticides through soils indicate flow through macropores. Larger proportions (in percent of total applied) of both the mobile and the strongly sorbed pesticides were lost through the drainage as compared to the loss through surface runoff at Askim. Here, it is suggested that macropore flow contribute to the increased loss of pesticides through the drainage. At Syverud, high infiltration capacity reduces the amount of water available for surface runoff, and somewhat higher loss of the mobile pesticide was registered in the drainage compared to the surface runoff. For the strongly sorbed pesticide, however, propiconazole was neither detected in surface nor in drainage water at Syverud. Generally, there was a higher percentage loss of the mobile compared to the strongly sorbed pesticide in both surface and drainage water, which is in agreement with the pesticides mobility characteristics in soil. An exception was, however, the erodible soil Bjørnebekk, where a higher fraction of propiconazole was lost in the surface runoff compared to bentazone. Large amounts of sediment transport from the Bjørnebekk field probably contributed to enhanced transport of the strongly sorbed pesticide.     

从"环评风暴"看《环境影响评价法》的实施

从国家环保局处罚的四起违法案件的分析看，在《环境影响评价法》实施过程中，各相关部门对其理解得不够深刻，执行中存在侥幸心理，从而造成有法不依、执法不严的后果。为此提出管理部门施重拳维护法律权威等系列对策和建议。