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91.
Yanhui Li Bing Xi Quansheng Zhao Fuqiang Liu Pan Zhang Qiuju Du Dechang Wang Da Li Zonghua Wang Yanzhi Xia 《环境科学学报(英文版)》2011,23(3):404-411
Kaolin has been widely used as an adsorbent to remove heavy metal ions from aqueous solutions. However, the lower heavy metal
adsorption capacity of kaolin limits its practical application. A novel environmental friendly material, calcium alginate immobilized
kaolin (kaolin/CA), was prepared using a sol-gel method. The e ects of contact time, pH, adsorbent dose, and temperature on Cu2+
adsorption by kaolin/CA were investigated. The Langmuir isotherm was used to describe the experimental adsorption, the maximum
Cu2+ adsorption capacity of the kaolin/CA reached up to 53.63 mg/g. The thermodynamic studies showed that the adsorption reaction
was a spontaneous and endothermic process. 相似文献
92.
This work was designed to explore the characteristics of photodegradation of herbicides in the copper-polluted water body. The
results showed that Cu(II) alone could induce a photo Fenton-like reaction to enhance the degradation of atrazine, in which hydroxyl
radical ( OH) was a main active species. Humic acids restrained atrazine degradation, nevertheless, when introducing Cu(II), the
photodegradation was accelerated, in which singlet oxygen (1O2) replaced OH acting as the prevailing species. A feasible mechanism
for the photochemical process was also proposed, which is helpful for better understanding the environmental photochemistry of
atrazine in the copper-polluted water. 相似文献
93.
Potential particulate pollution derived from UV-induced degradation of
odorous dimethyl sulfide 总被引:1,自引:0,他引:1
UV-induced degradation of odorous dimethyl sulfide (DMS) was carried out in a static White cell chamber with UV irradiation. The
combination of in situ Fourier transform infrared (FT-IR) spectrometer, gas chromatograph-mass spectrometer (GC-MS), wide-range
particle spectrometer (WPS) technique, filter sampling and ion chromatographic (IC) analysis was used to monitor the gaseous and
potential particulate products. During 240 min of UV irradiation, the degradation e ciency of DMS attained 20.9%, and partially
oxidized sulfur-containing gaseous products, such as sulfur dioxide (SO2), carbonyl sulfide (OCS), dimethyl sulfoxide (DMSO),
dimethyl sulfone (DMSO2) and dimethyl disulfide (DMDS) were identified by in situ FT-IR and GC-MS analysis, respectively.
Accompanying with the oxidation of DMS, suspended particles were directly detected to be formed by WPS techniques. These
particles were measured mainly in the size range of accumulation mode, and increased their count median diameter throughout
the whole removal process. IC analysis of the filter samples revealed that methanesulfonic acid (MSA), sulfuric acid (H2SO4) and
other unidentified chemicals accounted for the major non-refractory compositions of these particles. Based on products analysis and
possible intermediates formed, the degradation pathways of DMS were proposed as the combination of the O(1D)- and the OH- initiated
oxidation mechanisms. A plausible formation mechanism of the suspended particles was also analyzed. It is concluded that UV-induced
degradation of odorous DMS is potentially a source of particulate pollutants in the atmosphere. 相似文献
94.
Biosorption of silver ions onto Bacillus cereus biomass was investigated. Overall kinetic experiments were performed for the
determination of the necessary contact time for the attainment of equilibrium. It was found that the overall biosorption process was
best described by pseudo second-order kinetic model. The crystals detected by scanning electron microscope and X-ray photoelectron
spectroscopy suggested the precipitation was a possible mechanism of biosorption. The molecular genetics of silver resistance of B.
cereus biomass was also detected and illustrated by a whole cell sensor tool. 相似文献
95.
Preliminary report on methane emissions from the Three Gorges Reservoir in the summer drainage period 总被引:3,自引:0,他引:3
Fei Lu Le Yang Xiaoke Wang Xiaonan Duan Yujing Mu Wenzhi Song Feixiang Zheng Junfeng Niu Lei Tong Hua Zheng Yongjuan Zhou Jiangxiao Qiu Zhiyun Ouyang 《环境科学学报(英文版)》2011,23(12):2029-2033
Considerable variations may exist in CH4 emissions from the Three Gorges Reservoir. 相似文献
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100.
文章初步研究了水华蓝藻生物质对重金属离子Cu2+的吸附特性,包括生物吸附动力学和吸附等温线。生物吸附动力学结果表明,Cu2+的生物吸附可分为两个阶段,第一个阶段能较快地达到平衡,而之后的阶段进行缓慢。透析袋处理的蓝藻生物质在不同pH(3,4,5,6)的铜离子溶液条件下,吸附效率依次为62.4%,78.1%,71.2%,60.35%,吸附最大值为7.81 mg/g。水华蓝藻生物质对Cu2+的生物吸附平衡等温线可以用Freundlich模型精确拟合。水华蓝藻生物质在处理低浓度的含Cu2+废水方面有潜力。湖泊富营养化的优势在于产生低成本的、大量的、可收集的水华,这说明自然环境中的藻类资源如蓝藻水华生物质,可能作为商业中使用的生物吸附剂。 相似文献