纸基复合包装中铝塑分离的湿法工艺条件研究

纸基复合包装中的纸基部分通过水力碎浆分离后可直接用于生产再生纸. 其铝塑部分由1层0.02～0.03 mm厚的铝箔和2层0.03～0.08 mm厚的低密度聚乙烯膜层压复合而成,主要对铝塑的湿法分离进行研究.比较了甲酸、乙酸、盐酸3种剥离剂的分离效果; 用甲酸作为铝塑剥离剂时, 考察了剥离剂的浓度、反应温度、液固比及破碎尺寸对铝塑分离的影响; 根据铝塑分离时间、分离率、铝的损失率等指标,通过正交试验及方差分析优化铝塑分离的工艺条件. 结果表明,甲酸分离铝塑的最优条件: 剥离剂浓度为4 mol/L, 反应温度为60 ℃,液固比为60 L/kg, 破碎尺寸为5 cm×5 cm. 在该条件下, 铝塑的分离率达到100%.      

NEAR‐STREAM LANDUSE EFFECTS ON STREAMWATER NUTRIENT DISTRIBUTION IN AN URBANIZING WATERSHED1

ABSTRACT: We investigated spatial and temporal relationships among surface and subsurface watershed attributes and stream nutrient concentrations in urbanizing Johnson Creek watershed in northern Oregon. We sampled stream water at eight urban and five nonurban locations from March 1998 through December 1999. We sampled eight wells distributed over the two primary aquifers in the watershed. Using a Geographic Information System (GIS), percentages of landuse attributes within a radius of 30, 91, and 152 m from each sample site were quantified. We analyzed relationships between (1) nutrient concentrations and percentage cover of different landuse attributes, and (2) nutrient concentrations and underlying hydrologic units. We did not find a significant relationship between ground water chemistry and stream water chemistry. We found elevated levels of phosphorus (P) concentrations correlated with urban landuse, while higher nitrogen (N) concentrations were correlated with nonurban (primarily agricultural) landuse. We concluded that elevated levels of N in nonurban areas of Johnson Creek watershed were associated with agricultural practices. We further concluded that urban development factors such as increases in storm drains, dry wells, and impermeable surfaces may be responsible for higher input of P to the stream in urbanizing areas of the Johnson Creek watershed.     

钛白废酸固液分离与综合利用

介绍了湖南株洲化工集团有限责任公司钛白废酸固液分离与综合利用工艺。将钛白废酸固液分离后得到的清废酸用作磷肥生产用硫酸稀释液、钛白酸解工序硫酸稀释液和板框浸取液,取得了较好的经济效益和环境效益。     

含碳氨水回收集成分离技术的研究与应用

在研究NH3－CO2－H2O三元体系基础上,将解吸、精馏和防结晶技术相结合,开发出集成分离技术,并成功地将其用于原有含碳氨水回收装置的改造,取得了十分显著的经济与环保效益。     

烷基膦酸载体液膜中Cd(II)的传输

采用内耦合大块液膜分离技术,通过考察料液相pH值、温度、载体浓度以及解析相组成对Cd(II)迁移速率的影响,研究了以烷基膦酸为流动载体的液膜中镉的迁移规律,并建立了渗透系数与pH值、温度以及载体浓度之间的关系方程.结果表明,Cd(II)以CdR22HR(Kex值为3.58106)配合物形式在液膜中传输,增加载体浓度或升高温度,迁移速率明显升高.最佳传质条件为料液相pH值4.5～5.1、载体浓度5.0%～7.5%、温度298～308K.     

A COMPARISON OF DELTA CHANGE AND DOWNSCALED GCM SCENARIOS FOR THREE MOUNTAINOUS BASINS IN THE UNITED STATES1

ABSTRACT: Simulated daily precipitation, temperature, and runoff time series were compared in three mountainous basins in the United States: (1) the Animas River basin in Colorado, (2) the East Fork of the Carson River basin in Nevada and California, and (3) the Cle Elum River basin in Washington State. Two methods of climate scenario generation were compared: delta change and statistical downscaling. The delta change method uses differences between simulated current and future climate conditions from the Hadley Centre for Climate Prediction and Research (HadCM2) General Circulation Model (GCM) added to observed time series of climate variables. A statistical downscaling (SDS) model was developed for each basin using station data and output from the National Center for Environmental Prediction/National Center for Atmospheric Research (NCEPINCAR) reanalysis regridded to the scale of HadCM2. The SDS model was then used to simulate local climate variables using HadCM2 output for current and future conditions. Surface climate variables from each scenario were used in a precipitation‐runoff model. Results from this study show that, in the basins tested, a precipitation‐runoff model can simulate realistic runoff series for current conditions using statistically down‐scaled NCEP output. But, use of downscaled HadCM2 output for current or future climate assessments are questionable because the GCM does not produce accurate estimates of the surface variables needed for runoff in these regions. Given the uncertainties in the GCMs ability to simulate current conditions based on either the delta change or downscaling approaches, future climate assessments based on either of these approaches must be treated with caution.     

用离子交换法从β盐母液中分离1-萘磺酸钠的研究

比较了Ｄ２９０、Ｄ２９６、Ｄ３０１、Ｄ３７０、Ｄ３７２、Ｄ３８０ ６种树脂对β盐母液中１－萘磺酸的静态交换性能,筛选出Ｄ２９６用以回收β盐母液中的１－萘磺酸钠,进行了ＰＨ、接触时间、交换温度等影响因素的条件试验及树脂再生试验,得到１－萘磺酸钠收率８０％以上。     

仪表控制与空气分离生产安全的探讨

在传统生产中,人们往往忽略仪器对安全的作用,简述仪器在空气分离生产中的应用及作用.     

和田河年径流变化规律研究

根据和田河实测年径流资料,应用小波分析、R/S分析等多种方法,探讨了在气候变化和人类活动影响下,和田河年径流变化规律及其成因。结果表明,和田河年径流存在减少趋势,且具有一定的持续性。通过径流变化的影响因素分析表明,上游出山口处两支流的径流变化主要受气温升高的影响,下游入塔里木河处除受降水减少的影响外,主要是由于人类对水土资源开发进程的加快,人类活动是其径流变化的主要原因。     

渭河上游天然径流变化及其自然与人为因素影响贡献量

从20世纪60年代开始,渭河上游入陕西境内的水量不断减少,90年代天然径流量仅为60年代的60%。分析天然径流与降水的相关关系,对降水与非降水因素对径流减少的贡献进行了定量分析。结果表明,降水与非降水因素共同作用使得渭河上游径流量不断减少,且从20世纪70年代开始,非降水因素的贡献率逐渐增强,成为影响渭河上游天然径流量减少的主要因素。分析天然径流量与气温的相关关系,两者的相关系数在0.47以上,采用假设法,将气温从非降水因素中提取出来,进一步分析自然因素与人为因素的影响,结果表明,80年代以前,以自然因素影响为主,80年代以后,以人为因素影响为主,且人为因素的影响程度在逐渐增强,其原因在于人类活动改变下垫面导致径流减少。