全文获取类型
收费全文 | 5863篇 |
免费 | 601篇 |
国内免费 | 2879篇 |
专业分类
安全科学 | 322篇 |
废物处理 | 301篇 |
环保管理 | 1241篇 |
综合类 | 4730篇 |
基础理论 | 1167篇 |
污染及防治 | 993篇 |
评价与监测 | 422篇 |
社会与环境 | 126篇 |
灾害及防治 | 41篇 |
出版年
2024年 | 26篇 |
2023年 | 141篇 |
2022年 | 262篇 |
2021年 | 286篇 |
2020年 | 296篇 |
2019年 | 282篇 |
2018年 | 281篇 |
2017年 | 253篇 |
2016年 | 347篇 |
2015年 | 302篇 |
2014年 | 331篇 |
2013年 | 641篇 |
2012年 | 457篇 |
2011年 | 498篇 |
2010年 | 366篇 |
2009年 | 350篇 |
2008年 | 347篇 |
2007年 | 364篇 |
2006年 | 345篇 |
2005年 | 263篇 |
2004年 | 236篇 |
2003年 | 329篇 |
2002年 | 336篇 |
2001年 | 296篇 |
2000年 | 290篇 |
1999年 | 242篇 |
1998年 | 183篇 |
1997年 | 157篇 |
1996年 | 281篇 |
1995年 | 125篇 |
1994年 | 77篇 |
1993年 | 58篇 |
1992年 | 33篇 |
1991年 | 40篇 |
1990年 | 11篇 |
1989年 | 19篇 |
1988年 | 14篇 |
1987年 | 13篇 |
1986年 | 8篇 |
1985年 | 24篇 |
1984年 | 42篇 |
1983年 | 39篇 |
1982年 | 9篇 |
1981年 | 6篇 |
1980年 | 8篇 |
1978年 | 6篇 |
1977年 | 3篇 |
1972年 | 1篇 |
1971年 | 14篇 |
1967年 | 1篇 |
排序方式: 共有9343条查询结果,搜索用时 734 毫秒
141.
142.
《环境科学学报(英文版)》2023,35(4):387-395
This study examined the effectiveness for degradation of hydrophobic (HPO), transphilic (TPI) and hydrophilic (HPI) fractions of natural organic matter (NOM) during UV/H2O2, UV/TiO2 and UV/K2S2O8 (UV/PS) advanced oxidation processes (AOPs). The changing characteristics of NOM were evaluated by dissolved organic carbon (DOC), the specific UV absorbance (SUVA), trihalomethanes formation potential (THMFP), organic halogen adsorbable on activated carbon formation potential (AOXFP) and parallel factor analysis of excitation–emission matrices (PARAFAC-EEMs). In the three UV-based AOPs, HPI fraction with low molecular weight and aromaticity was more likely to degradate than HPO and TPI, and the removal efficiency of SUVA for HPO was much higher than TPI and HPI fraction. In terms of the specific THMFP of HPO, TPI and HPI, a reduction was achieved in the UV/H2O2 process, and the higest removal rate even reached to 83%. UV/TiO2 and UV/PS processes can only decrease the specific THMFP of HPI. The specific AOXFP of HPO, TPI and HPI fractions were all able to be degraded by the three UV-based AOPs, and HPO content is more susceptible to decompose than TPI and HPI content. UV/H2O2 was found to be the most effective treatment for the removal of THMFP and AOXFP under given conditions. C1 (microbial or marine derived humic-like substances), C2 (terrestrially derived humic-like substances) and C3 (tryptophan-like proteins) fluorescent components of HPO fraction were fairly labile across the UV-based AOPs treatment. C3 of each fraction of NOM was the most resistant to degrade upon the UV-based AOPs. Results from this study may provide the prediction about the consequence of UV-based AOPs for the degradation of different fractions of NOM with varied characteristics. 相似文献
143.
土壤有机碳是控制土壤中多环芳烃的吸附解吸及其生物有效性的主要因素之一,土壤中硬碳类吸附剂是土壤有机碳中的重要部分,土壤中软碳类物质和硬碳类物质的相互作用对研究土壤中多环芳烃的解吸行为和生物有效性有重要影响。研究将溶解有机质胡敏酸,通过条件的变化使其转变为非溶解态,研究其对土壤碳质吸附剂(胡敏素和黑碳)吸附多环芳烃的解吸行为的影响。研究结果表明:非溶解态胡敏酸会显著降低土壤硬碳类物质中多环芳烃的解吸能力,解吸滞后性增加,作者认为非溶解态胡敏酸的添加会覆盖土壤硬碳类物质的表面吸附位点和填充吸附多环芳烃的孔隙,造成硬碳类有机质中的多环芳烃解吸能力下降,滞后性增强。研究还发现硬碳类有机质的比表面积和孔隙度和解吸能力的变化强度呈正相关关系。 相似文献
144.
145.
146.
147.
《环境科学学报(英文版)》2023,35(4):263-274
The cryptomelane-type manganese oxide (OMS-2)-supported Co (xCo/OMS-2; x = 5, 10, and 15 wt.%) catalysts were prepared via a pre-incorporation route. The as-prepared materials were used as catalysts for catalytic oxidation of toluene (2000 ppmV). Physical and chemical properties of the catalysts were measured using the X-ray diffraction (XRD), Fourier transform infrared spectroscopic (FT-IR), scanning electron microscopic (SEM), X-ray photoelectron spectroscopy (XPS), and hydrogen temperature-programmed reduction (H2-TPR) techniques. Among all of the catalysts, 10Co/OMS-2 performed the best, with the T90%, specific reaction rate at 245°C, and turnover frequency at 245°C (TOFCo) being 245°C, 1.23 × 10−3 moltoluene/(gcat·sec), and 11.58 × 10−3 sec−1 for toluene oxidation at a space velocity of 60,000 mL/(g·hr), respectively. The excellent catalytic performance of 10Co/OMS-2 were due to more oxygen vacancies, enhanced redox ability and oxygen mobility, and strong synergistic effect between Co species and OMS-2 support. Moreover, in the presence of poisoning gases CO2, SO2 or NH3, the activity of 10Co/OMS-2 decreased for the carbonate, sulfate and ammonia species covered the active sites and oxygen vacancies, respectively. After the activation treatment, the catalytic activity was partly recovered. The good low-temperature reducibility of 10Co/OMS-2 could also facilitate the redox process accompanied by the consecutive electron transfer between the adsorbed O2 and the cobalt or manganese ions. In the oxidation process of toluene, the benzoic and aldehydic intermediates were first generated, which were further oxidized to the benzoate intermediate that were eventually converted into H2O and CO2. 相似文献
148.
大孔强碱阴树脂去除饮用水中微量有机物 总被引:2,自引:0,他引:2
比较了大孔强碱阴树脂和颗粒活性炭在饮用水的深度处理中对有机物的去除效果。结果表明:(1)大孔强碱阴树脂的吸附容量比颗粒活性炭的大。在pH为8时,大孔强碱阴树脂对TOC的去除率最高。pH6~8时,对TOC的去除率没有明显的区别,而颗粒活性炭在pH为2时。对TOC的去除率最高;水温低能提高2种吸附材料的吸附容量。(2)在动态实验条件下。当流速相同,大孔强碱阴树脂的穿透时间明显比颗粒活性炭的长,大孔强碱阴树脂的制水量约是吸附床的10000倍。而颗粒活性炭却只有吸附床的4000倍。在饮用水的深度处理中,大孔强碱阴树脂可作为活性炭的最佳替代品。 相似文献
149.
Boris N. Porfiriev 《Environmental management》1996,20(1):25-33
An analysis is presented of the environmental effects of the most serious radiation accident recorded after Chernobyl, which
occurred in the formerly secret town of Tomsk-7 in Siberia, Russia, on 6, April 1993. Fortunately, it appears not to have
become a major industrial crisis or disaster. The causes of the accident are described. It is argued that a mixture of both
objective and subjective prerequisites, including specific human, organizational, and technological factors, were responsible
for the explosion or directly facilitated it. The Tomsk-7 accident's ecological, medical, social, and psychological consequences
are discussed. 相似文献
150.
Atsuyoshi Nakayama Norioki Kawasaki Ioannis Arvanitoyannis Seiichi Aiba Noboru Yamamoto 《Journal of Polymers and the Environment》1996,4(3):205-211
Biodegradable polyesters were synthesized by ring-opening copolymerization of -butyrolactone (BL) and its derivatives withl-lactide (LLA). Although tetraphenyl tin was the main catalyst used, other organometallic catalysts were used as well.1H and13C NMR spectra showed that poly(BL-co-LLA)s were statistical and that their number-average molecular weights were as high as 7×104. The maximum BL content obtained from copolymerization BL/LLA was around 17%. TheT
m andT
g values of the copolymers showed a gradual depression with an increase in BL content. NoT
m was obtained for the copolymers containing more than 13 mol% BL. The biodegradability of the copolyesters was evaluated by enzymatic hydrolysis and nonenzymatic hydrolysis tests. The enzymatic hydrolysis was carried out at 37°C for 24 h using lipases fromRhizopus arrhizus andR. delemar. Hydrolyses by both lipases showed that an increase in BL content of the copolymer resulted in enhanced biodegradability. Nonenzymatic accelerated hydrolysis of copolymers at 70°C was found to increase proportionally to their exposure time. The hydrolysis rate of these copolymers was considerably faster than that of PLLA. The higher hydrolyzability was recorded for the BL-rich copolymers. The copolymerization of -methyl--butyrolactone (MBL) or -ethyl--butyrolactone (EBL) with LLA resulted in relatively LA-rich copolymers. 相似文献