水质氨氮自动分析仪分析方法研究

氨氮自动分析仪是根据纳氏试剂分光光度法的原理,通过自动进样,自动蒸馏,来实现快速准确的分析水质氨氮样品。近年来,氨氮自动分析仪广泛应用于环境监测领域,该方法能够快速、准确、方便地测定水质中的氨氮。利用标准方法纳氏试剂分光光度法进行实验室内的比对实验,通过实验分析,氨氮自动分析仪的分析曲线线性较好,相关系数达到0．9998,方法检出限、准确率和精密度能够满足当前环境监测标准的要求,实际样品测定结果理想,适合在环境监测领域推广应用。     

Sorption Kinetics of Atrazine and Diuron in Soils from Southern Brazil

Abstract

Sorption kinetics of atrazine and diuron was evaluated in soil samples from a typical landscape in Paraná. Samples were collected (0–20 cm) in a no-tillage area from Mamborê, PR, which has been cultivated under a crop rotation for the last six years. Six sampling points of the slope were selected to represent a wide range of soil chemical and physical properties found in this area. Radiolabeled tracers (¹⁴C-atrazine and ¹⁴C-diuron) were used and the radioactivity was detected by liquid scintillation counting (LSC). Sorption was accomplished for increasing equilibration periods (0.5, 1.5, 3, 6, 12, 24, and 48 h). Kinetics data fitted adequately well to Elovich equation, providing evidences that soil reaction occurs in two distinct stages: a fast, initial one followed by a slower one. During the fast phase, 34–42 and 71–79% of total atrazine and diuron applied were sorbed to soil samples. No important differences were found among combinations of soil and herbicide sorption during the slow phase. The unrealistic conditions under batch experiments should be overestimating sorption in the fast phase and underestimating diffusion in the slow phase. Sorption of both herbicides was positively correlated to organic carbon and clay contents of soils, but atrazine was much less sorbed than diuron, showing its higher potential to contaminate groundwater, specially in sandy, low organic carbon soils.     

石首麋鹿国家级自然保护区多媒体演示系统的研究

本文利用计算机多媒体技术 ,研制出石首麋鹿国家级自然保护区多媒体演示系统。该系统以 WINDOWS98窗口环境为平台 ,融图、文、声、像、数据库、动画等多种媒体于一体 ,将先进的图像处理技术、声音处理技术、文字处理技术、视频处理技术、以及三维动画技术集成到计算机中 ,可使原本单调的静态材料变成有声有色的动态画面 ,全方位展示该保护区的历史、现状与未来     

Simplified model for the evaluation of the effects of explosions on industrial target

The evaluation of vulnerability of process equipment to explosion is a central issue in the analysis of industrial risks. In this work, we have developed a simplified model, however based on fundamental equations, which includes structural and fluid–dynamic parameters for the target (the industrial equipment) and for the impacting pressure wave (shock waves) or object (fragment, debris) produced by different type of chemical explosions.The validity of methodology has been assessed by case histories. Several insights on the dynamic of structural interaction of the explosion with the target have been obtained, with specific reference to escalation effects.The model derives from the well-known Johnson's number, often adopted in impact engineering.     

Fundamental Moral Attitudes to Animals and Their Role in Judgment: An Empirical Model to Describe Fundamental Moral Attitudes to Animals and Their Role in Judgment on the Culling of Healthy Animals During an Animal Disease Epidemic

In this paper, we present and defend the theoretical framework of an empirical model to describe people’s fundamental moral attitudes (FMAs) to animals, the stratification of FMAs in society and the role of FMAs in judgment on the culling of healthy animals in an animal disease epidemic. We used philosophical animal ethics theories to understand the moral basis of FMA convictions. Moreover, these theories provide us with a moral language for communication between animal ethics, FMAs, and public debates. We defend that FMA is a two-layered concept. The first layer consists of deeply felt convictions about animals. The second layer consists of convictions derived from the first layer to serve as arguments in a debate on animal issues. In a debate, the latter convictions are variable, depending on the animal issue in a specific context, time, and place. This variability facilitates finding common ground in an animal issue between actors with opposing convictions.     

Sulfate removal from waste chemicals by precipitation

Chemical oxidation using Fenton's reagent has proven to be a viable alternative to the oxidative destruction of organic pollutants in mixed waste chemicals, but the sulfate concentration in the treated liquor was still above the acceptable limits for effluent discharge. In this paper, the feasibility of sulfate removal from complex laboratory wastewaters using barium and calcium precipitation was investigated. The process was applied to different wastewater cases (two composite samples generated in different periods) in order to study the effect of the wastewater composition on the sulfate precipitation. The experiments were performed with raw and oxidized wastewater samples, and carried out according to the following steps: (1) evaluate the pH effect upon sulfate precipitation on raw wastewaters at pH range of 2-8; (2) conduct sulfate precipitation experiments on raw and oxidized wastewaters; and (3) characterize the precipitate yielded. At a concentration of 80 g L(-1), barium precipitation achieved a sulfate removal up to 61.4% while calcium precipitation provided over 99% sulfate removal in raw and oxidized wastewaters and for both samples. Calcium precipitation was chosen to be performed after Fenton's oxidation; hence this process configuration favors the production of higher quality precipitates. The results showed that, when dried at 105 degrees C, the precipitate is composed of hemidrate and anhydrous calcium sulfate ( approximately 99.8%) and trace metals ( approximately 0.2%: Fe, Cr, Mn, Co, Ag, Mg, K, Na), what makes it suitable for reuse in innumerous processes.     

The apportionment of quadratic entropy: a useful alternative for partitioning diversity in ecological data

Many methods that study the diversity within hierarchically structured populations have been developed in genetics. Among them, the analysis of molecular variance (AMOVA) (Excoffier et al., 1992) has the advantage of including evolutionary distances between individuals. AMOVA is a special case of a far more general statistical scheme produced by Rao (1982a; 1986) and called the apportionment of quadratic entropy (APQE). It links diversity and dissimilarity and allows the decomposition of diversity according to a given hierarchy. We apply this framework to ecological data showing that APQE may be very useful for studying diversity at various spatial scales. Moreover, the quadratic entropy has a critical advantage over usual diversity indices because it takes into account differences between species. Finally, the differences that can be incorporated in APQE may be either taxonomic or functional (biological traits), which may be of critical interest for ecologists.     

而今迈步从头越——《安全生产法》征求意见稿学习体会和修改建议

首先分析了我国《安全生产法》的发展沿革,且认真学习了目前发布的《安全生产法》征求意见稿,归纳了征求意见稿还应实现四个重点突破:必须体现以人为本的执政理念;职业危害防治应列为《安全生产法》的重要条款之一;安全生产执法监察应与公共安全及行政管理分离;应对工伤保险预防机制作出明确要求。此外,建议通过《安全生产法》的进一步修订实现我国安全生产的制度化建设:建议逐步建立安全生产分级监察管理体制;推进风险管理制度,对企业实行风险分级与分级监管;逐步提出建立安全生产监察员专业化制度;建立与国际接轨的生产安全事故统计报告系统;强化城市建设土地使用规划的风险管理和安全许可;生产安全事故应急管理应强化应急准备工作;建立独立生产安全事故调查机构和公开公正调查程序;应在《安全生产法》中明确"安全生产委员会"的组织形式和功能;生产安全事故责任追究应与激励政策相结合。     

An Analysis of Spatial Clustering and Implications for Wildlife Management: A Burrowing Owl Example

Analysis tools that combine large spatial and temporal scales are necessary for efficient management of wildlife species, such as the burrowing owl (Athene cunicularia). We assessed the ability of Ripley’s K-function analysis integrated into a geographic information system (GIS) to determine changes in burrowing owl nest clustering over two years at NASA Ames Research Center. Specifically, we used these tools to detect changes in spatial and temporal nest clustering before, during, and after conducting management by mowing to maintain low vegetation height at nest burrows. We found that the scale and timing of owl nest clustering matched the scale and timing of our conservation management actions over a short time frame. While this study could not determine a causal link between mowing and nest clustering, we did find that Ripley’s K and GIS were effective in detecting owl nest clustering and show promise for future conservation uses.