中国北方某流域畜禽养殖污染与防治对策研究

通过实地调研和等标污染负荷模型等研究方法,对北方某流域内畜禽养殖产生的环境污染进行定量化研究.结果表明:研究区规模化大型畜禽养殖和小户养殖都比较多,管理混乱;流域内畜禽养殖污染向水体排放污染物主要是COD,占排污总量的82.73％;等标污染负荷研究显示流域主要污染物是TN和TP,在对畜禽污染的治理中应着重治理TN和TP的污染;研究区应在合理规划布局选址基础上,建立畜禽粪便治理和综合利用设施,实现资源利用的最大化,促进流域的可持续发展.     

Excretion of manure-borne estrogens and androgens and their potential risk estimation in the Yangtze River Basin

The Yangtze River is the longest river in China, and the river basin spans one fifth of the area of the whole country. Based on statistical data, the excretion of manure-borne steroid hormones, including steroid estrogens(SEs) and steroid androgens(SAs), in 10 provinces of China within the region has been estimated. The potential environmental and ecological risk of manure-borne steroid estrogens to the surface water in this region was also assessed. The manure-borne SE and SA excretions in the 10 provinces and municipalities vary in the order: Sichuan Hunan Hubei Yunnan Jiangsu Anhui Jiangxi Chongqing Qinghai Shanghai. The highest increase of manure-borne SEs(1434.3 kg)and SAs(408.5 kg) was found in Hunan and Hubei provinces, respectively, and the total excretion in 2013 was 65% more than 15 years earlier in these two provinces. However, the emissions in Anhui and Shanghai decreased in this 15 year period of time. Swine urine,chicken feces, cattle urine, and laying hen feces were considered the dominant sources of manure-borne E1, βE2, αE2, and SAs, respectively. Although Jiangsu province did not have the largest excretion of manure-borne SEs, it had the highest level of predicted17β-estradiol equivalency(EEQs) value of 16.65 ng/L in surface water because of the limited surface water resources. According to the lowest observable effect level of 10 ng/L for17β-estradiol, the manure-borne SEs in Jiangsu province might potentially pose ecological risk to its wild aquatic organisms.     

Use of a food web model to evaluate the factors responsible for high PCB fish concentrations in Lake Ellasjøen, a high Arctic Lake

Background, aim, and scope

Lake Ellasjøen, located in the Norwegian high arctic, contains the highest concentrations of polychlorinated biphenyls (PCBs) ever recorded in fish and sediment from high arctic lakes, and concentrations are more than 10 times greater than in nearby Lake Øyangen. These elevated concentrations in Ellasjøen have been previously attributed, in part, to contaminant loadings from seabirds that use Ellasjøen, but not Øyangen, as a resting area. However, other factors, such as food web structure, organism growth rate, weight, lipid content, lake morphology, and nutrient inputs from the seabird guano, also differ between the two systems. The aim of this study is to evaluate the relative influence of these factors as explanatory variables for the higher PCB fish concentrations in Ellasjøen compared with Øyangen, using both a food web model and empirical data.

Methods

The model is based on previously developed models but parameterized for Lakes Ellasjøen and Øyangen using measured data wherever possible. The model was applied to five representative PCB congeners (PCB 105, 118, 138, 153, and 180) using measured sediment and water concentrations as input data and evaluated with previously collected food web data.

Results

Modeled concentrations are within a factor of two of measured concentrations in 60% and 40% of the cases in Lakes Ellasjøen and Øyangen, respectively, and within a factor of 10 in 100% of the cases in both lakes. In many cases, this is comparable to the variability associated with the data as well as the efficacy of the predictions of other food web model applications.

Discussion

We next used the model to quantify the relative importance of five major differences between Ellasjøen and Øyangen by replacing variables representing each of these factors in the Ellasjøen model with those from Øyangen, in separate simulations. The model predicts that the elevated PCB concentrations in Ellasjøen water and sediment account for 49%–58% of differences in modeled fish PCB concentrations between lakes. These elevated sediment and, to a lesser extent, water concentrations in Ellasjøen are due to PCB loadings from seabird guano. However, sediment–water fugacity ratios of PCBs are consistently greater in Ellasjøen compared with Øyangen, which suggests that internal lake processes also contribute to differences in sediment and water concentrations. We hypothesize that the nutrients associated with guano influence sediment–water fugacity ratios of PCBs by increasing the stock of pelagic algae. As both these algae and the guano settle, their organic carbon content is degraded faster than PCBs, which causes an extra magnification step in Ellasjøen before these detrital particles are consumed by benthic organisms, which are in turn consumed by fish. The model predicts that the remaining ～50% of the differences in PCB concentrations observed between the fish of these lakes are due to other subtle differences in their food web structures.

Conclusions

In conclusion, based on the results of a food web model, we found that the most dominant factors influencing the higher PCB fish concentrations in Lake Ellasjøen compared with Øyangen are the higher sediment and water concentrations in Ellasjøen, caused by seabird guano. Together, sediment and water are predicted to account for 49%–58% of differences in fish concentrations between lakes. Although seabird guano provides a source of nutrients to the lake, in addition to contaminants, empirical data and indirect model results suggest that nutrients are not leading to decreased bioaccumulation, in contrast to what has been observed in temperate, pelagic food webs.

Recommendations and perspectives

The results of this study emphasize the importance of considering even small differences in food web structure when comparing bioaccumulation in two lakes; although the food web structures of Ellasjøen and Øyangen differ only slightly, the model predicts that these differences account for most of the remaining ～50% of the differences in PCB fish concentrations between the two lakes. This study further demonstrates the utility of food web models as we were able to predict and tease apart the influence of various factors responsible for the elevated concentrations in the fish from Lake Ellasjøen, which would have been difficult using the field data alone.     

Polycyclic aromatic hydrocarbon (PAH) deposition to and exchange at the air-water interface of Luhu, an urban lake in Guangzhou, China

Urban lakes are vulnerable to the accumulation of semivolatile organic compounds, such as PAHs from wet and dry atmospheric deposition. Little was reported on the seasonal patterns of atmospheric deposition of PAHs under Asian monsoon climate. Bulk (dry + wet) particle deposition, air-water diffusion exchange, and vapour wet deposition of PAHs in a small urban lake in Guangzhou were estimated based on a year-round monitoring. The total PAH particle deposition fluxes observed were 0.44-3.46 μg m⁻² day⁻¹. The mean air-water diffusive exchange flux was 20.7 μg m⁻² day⁻¹. The vapour deposition fluxes of PAHs ranged 0.15-8.26 μg m⁻² day⁻¹. Remarkable seasonal variations of particulate PAH deposition, air-water exchange fluxes and vapour wet deposition were influenced by seasonal changes in meteorological parameters. The deposition fluxes were predominantly controlled by the precipitation intensity in wet season whereas by atmospheric concentration in dry season.     

活性污泥的耐盐驯化培养

以某污水处理厂二沉池好氧污泥为接种污泥,采用逐步提高盐度和稳定盐度2种方法对活性污泥进行耐盐性驯化培养,考察驯化结果表明,前一种方法更有利于耐盐菌的培养。对比不同盐度情况下各项指标的去除效果得出:本实验污泥适宜盐度为1%。使用稳定进水盐度的方法,出水指标及各指标的去除率均低于逐步提高盐度法,且镜检结果表明大量微生物死亡。     

流域水资源管理中的出境水水质目标管理的思考

从出境水水质目标出发，提出出境水水质目标管理的两个阶段、实施及其可行性。     

人工湿地防治湖泊富营养化污染探讨

针对湖泊富营养化问题,结合抚仙湖当前污染状况,以马料河人工湿地为例,探讨利用人工湿地控制水体水质下降、脱氮除磷机理及其去除效率.结果显示：马料河人工湿地对TN、TP、SS的去除效率分别为：44.21%、46.03%、86.6%;其中TN的去除效率与进水流速具有一定的相关性;TP的去除效率相对稳定,去除机制主要与湿地基质有关.     

抚河流域水生态环境恢复措施初探

论述了江西省抚河流域的概况、水生态环境的现状及存在的问题，包括淤泥的堆积、水土的流失、水污染、沿岸防洪圩堤标准偏低等问题,并提出了流域水生态环境恢复的目标，以及针对恢复目标提出了水权分配、水土保持治理、水工程治理、水质治理等方面的初步措施与建议。     

喀斯特小流域复杂景观中水质状况

以红枫湖流域周边一个受人为活动严重影响的农田源头溪流-王家寨小流域为研究对象,设置11个监测点研究硝酸盐（NO3-N）、氨态氮（NH4＋-N）、溶解性无机磷（PO4--P）、总磷（TP）和总悬浮物（TSS）在复杂景观中的变化状况。降雨后采样水中氮、磷含量明显低于雨后的地表积水,地表积水受各种影响,水质降低。水塘型湿地,其丰水期的PO43--P、TP、SS高于枯水期,与水循环条件较好的流水溪流还是存在明显的区别。从平均值来看,枯水期地表水和地下水TP都超过5级水质标准。水质与＂源＂景观的关系不明显,说明喀斯特小流域中复杂的景观结构对氮磷的截留作用。     

基于水土流失的景观格局分析方法

景观格局和生态过程是景观生态学研究的重要内容,但是很多研究只重视景观格局的研究,而忽略了生态过程的研究。文章针对水土流失这一重要生态过程,提出了基于水土流失过程的景观坡度指数和景观空间负荷对比指数,并对黄土高原泾河流域15个子流域的景观格局进行了分析,认为泾河流北部各子流域主要以水土流失的＂源＂景观为主,景观坡度指数大,空间负荷指数小,水土流失风险大;流域南部各子流域上游以＂汇＂景观为主,坡度指数大,中下游以＂源＂景观为主,景观空间分布不均衡,存在一定的水土流失风险;流域东部局部子流域主要以水土流失的＂汇＂景观为主,＂源＂景观相对较小,＂源＂-＂汇＂景观空间分布均衡,水土流失风险小。