Statistical Evaluation of Variables Affecting Occurrence of Hydrocarbons in Aquifers Used for Public Supply,California

The variables affecting the occurrence of hydrocarbons in aquifers used for public supply in California were assessed based on statistical evaluation of three large statewide datasets; gasoline oxygenates also were analyzed for comparison with hydrocarbons. Benzene is the most frequently detected (1.7%) compound among 17 hydrocarbons analyzed at generally low concentrations (median detected concentration 0.024 μg/l) in groundwater used for public supply in California; methyl tert‐butyl ether (MTBE) is the most frequently detected (5.8%) compound among seven oxygenates analyzed (median detected concentration 0.1 μg/l). At aquifer depths used for public supply, hydrocarbons and MTBE rarely co‐occur and are generally related to different variables; in shallower groundwater, co‐occurrence is more frequent and there are similar relations to the density or proximity of potential sources. Benzene concentrations are most strongly correlated with reducing conditions, regardless of groundwater age and depth. Multiple lines of evidence indicate that benzene and other hydrocarbons detected in old, deep, and/or brackish groundwater result from geogenic sources of oil and gas. However, in recently recharged (since ~1950), generally shallower groundwater, higher concentrations and detection frequencies of benzene and hydrocarbons were associated with a greater proportion of commercial land use surrounding the well, likely reflecting effects of anthropogenic sources, particularly in combination with reducing conditions.     

基于边界定位法的填埋场渗漏检测

提出了以传输线模型为基础的新型填埋场渗漏检测方法,并且建立了填埋场渗漏检测的非均匀传输线模型.利用模型中边界电气量以及渗漏区域2个分界面电压连续的基本原理推导出测距方程,通过线路两端电气量的采样值,计算模型的特性阻抗和传播系数.结果表明:检测频率为30 MHz时,渗漏和未渗漏区域的衰减常数和相位常数差异性最大;同一频率下,渗漏区域的值高于未渗漏区域;特性阻抗的模值随频率增加而减小,辐角则随频率的增加而增大;测量中不同步采样对测距精度有一定影响.为提高测距精度,应选用较高的检测频率并保证两端电气量同步采样.      

有机污染物的被动采样材料-水分配系数的QSAR研究

污染物的被动采样材料-水分配系数(K_(PW))是衡量被动采样器性能和进行优化的一个重要指标,由于实验方法难以逐个测定众多污染物的K_(PW)值,有必要发展其KP W预测方法。本研究选取聚乙烯(PE)、聚丙烯酸酯(PA)和硅橡胶(SR)3类常用的被动采样材料共7种,采用多元线性回归分析方法构建可用于K_(PW)预测的定量构效关系(QSAR)模型。所构建的QSAR模型具有良好的拟合优度(R2a dj介于0.806~0.989)、稳健性(Q2L O O和Q2B O O T分别介于0.786~0.988和0.773~0.801)和预测能力(R_(ext)~2和Q_(ext)~2分别介于0.769~0.989和0.757~0.982),可以用于预测烷烃、烯烃、芳香类、醇类、酮类、酯类、醚类等多种有机污染物的log KP W值。有机污染物的log KP W与分子Mc Gowan体积(Vx)、氯原子个数(n Cl)、环周长(Rperim)、多重键个数(n BM)、N,O极性贡献的拓扑极性表面积(TPSA(NO))、[-N(=)=]结构个数(Ndds N)和羟基个数(nROH)等参数有关。     

Trace metals in the western Mediterranean Sea∗

Data on Cd, Pb and Cu concentrations in seawater referring to five years of field studies on the western Mediterranean Sea are reported in order to present a space and time integrated situation on the levels of these metals. Surface total metal concentrations present rather homogeneous distributions between the different areas considered, including the Tyrrhenian Sea. The metal concentrations in three areas affected by natural and industrial wastes are also discussed. The vertical distribution of the dissolved Cd, Pb and Cu in the Alboran Sea seems to be rather homogeneous, both vertically and among the stations chosen between the Strait of Gibraltar and the Island of Alboran.     

Variations in the elemental compositions of plants,and computer‐aided sampling in ecosystems∗

To obtain comparable results of multi‐element analysis of plant materials by different laboratories, a harmonized sampling procedure for terrestrial and marine ecosystems is essential. The heterogeneous distribution of chemical elements in living organisms is influenced by different biological parameters. These parameters are mainly characterized by genetic predetermination, seasonal changes, edaphic and climatic conditions, and delocalization processes of chemical substances by metabolic activities.

The biological variations of the element content in plants were divided into 5 systematic levels, which are: 1. the plant species; 2. the population; 3. the stand (within an ecosystem); 4. the individual; and 5. the plant compartment. Each of these systematic levels can be related to: 1. genetic variabilities; 2. different climatic, edaphic and anthropogenic influences; 3. microclimatic or microedaphic conditions; 4. age of plants (stage of development), exposure to environmental influences (light, wind, pollution etc.), seasonal changes; and 5. transport and deposition of substances within the different plant compartments (organs, tissues, cells, organelles).

An expert system for random and systematic sampling for multi‐element analysis of environmental materials, such as plants, soils and precipitation is presented. After statistical division of the research area, the program provides advice for contamination‐free collection of environmental samples.     

北京冬季大气中多溴联苯醚的污染水平和分布特征

2010年11月至2011年2月利用聚氨酯泡沫(PUF)大气被动采样技术采集了北京市海淀、朝阳、丰台、石景山、昌平、大兴、通州等区域的大气样品,采用高分辨气相色谱/高分辨质谱联用法(HRGC/HRMS)分析了其中13种多溴联苯醚(PBDEs)同族体的污染浓度和分布特征.结果表明,北京大气中PBDEs总含量(Σ13PBDEs)为0.97~41.1pg/m3,平均值为7.85pg/m3.在区域分布规律方面呈现东南地区的采样点污染物浓度明显高于西北地区,工业地区和人口密集的商业地区明显高于郊区和背景对照区的分布特征.     

Stack sampling for organic emissions

Along with increased activity in source sampling for organics, there have been many improvements in the methods of acquiring samples. Much has been learned about how best to proceed, and a number of potentially serious pitfalls have been discovered, characterized, and circumvented. Unfortunately, communication of all of this new technology has not always been effective.

This paper reviews some of the more important fundamental principles involved in stack sampling for organics, briefly describes and discusses recently developed equipment, and points out a few of the more serious pitfalls to be avoided. Extensive references are provided, many of which are often overlooked by newcomers to the field. The conclusion is reached that it is possible to consistently obtain high‐quality samples of organic materials from stationary source stacks, even though knowledge and caution are necessary.     

我国鸟类监测的现状、问题与对策

鸟类是开展生物多样性监测的重要指示类群.对鸟类的长期、系统监测工作在欧美已经有百余年历史,且野鸟多样性指数已经成为欧美一些国家开展生物多样性监测工作的官方指标.通过对国内鸟类监测现状的分析,结合监测对象、指标、抽样策略和监测方法等监测工作中应重点关注的几个方面,提出了我国鸟类监测存在的问题,并结合国情提出了下一步开展鸟类监测工作的对策与建议.建议我国有关部门尽快制定鸟类监测技术规程和标准,统一数据收集和分析平台,逐步构建政府引导,科研院所、高等院校、自然保护区、观鸟协会和志愿者等多方参与的鸟类监测网络.     

Using experience sampling methodology in organizational behavior

Experience sampling methodology and daily diary (ESM/DD) research elicits repeated reports of immediate or very recent experiences from the same sample of people for several days or weeks. Experience sampling and diary methods were almost unheard of in organizational research 15 years ago, but the past decade has seen a rapid rise in their use. These methods are helpful in studying dynamic within‐person processes involving affect, behavior, interpersonal interactions, work events, and other transient workplace phenomena over time. Assessing cross‐level effects of traits or other stable features on within‐person processes and reactivity is also possible with ESM/DD data. We provide an introduction to issues in designing and carrying out an ESM/DD study, including data collection choices and schedules, measures, technology, training and motivation of participants, and analysis of multilevel data. We offer best practice recommendations and refer readers to further resources for additional detail on conducting and analyzing ESM/DD research. Copyright © 2012 John Wiley & Sons, Ltd.     

吸气式火灾探测系统采样管网优化设计

对吸气式火灾探测报警系统中采样管网进行优化设计是提高其探测性能的重要手段。基于流体动力学原理,建立管网内气体运动数学模型,给出各状态参数之间的关系式。分析常见管网布置方式的优缺点,提出吸气式采样管网的优化设计方案:视每个采样孔为1个点型感烟探测器,采样孔间距基本一致,调整孔径使各采样孔进气量相同,孔数较多时,可增设末端孔,以缩短气体样本传输时间。从理论上分析管网参数对探测性能的影响,并利用Fluent 6.3进行相应的数值模拟。结果表明,样本传输时间与管长、管径、开孔数成正比,与总流量和末端孔孔径成反比。