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151.
ABSTRACT: A linear filter (Kalman filter) technique was used with a Streamflow-concentration model the minimize surface water quality sampling frequencies when determining annual mean solute concentrations with a predetermined allowable error. The Kalman filter technique used the stream discharge interval as a replacement for the more commonly used time interval. Using filter computations, the measurement error variance was minimized within the sample size constraints. The Kalman filter application proposed here is applicable only under several conditions including: monitoring is solely to estimate annual mean concentration; discharge measurement errors are negligible; the Streamflow-concentration model is valid; and monthly samples reflect the total variance of the solute in question. 相似文献
152.
ABSTRACT: Variability in bedload-transport rates during constant water discharge is an inherent part of the bedload-transport process. Although this variability has been measured extensively in the laboratory, similar information generally is not available from field measurements. During a four-day period of nearly constant water discharge, four sets of consecutively collected bedload samples, ranging from 43 to 120 samples, were obtained at the same cross channel location using a standard 65-pound Helley-Smith bedload sampler. When the measured transport rates are converted to dimensionless rates and plotted as cumulative frequency distributions, they show good agreement with a theoretical probability distribution function of rates derived for the case of ripples on dunes. The distributions show that during constant water discharge individual measured rates at a fixed point vary from near zero to four times the mean rate, and 60 percent of the sampled rates will be less than the mean. Because of the large variation in transport rates that occurs at every location in the cross section, many observations are required to establish an accurate estimate of the mean rate at any given location. 相似文献
153.
William W-G. Yeh Chuching Wang 《Journal of the American Water Resources Association》1987,23(4):569-580
ABSTRACT: This paper presents a method for estimating aquifer dispersivities in solute transport models. Sensitivity equations are derived for the calculation of sensitivity coefficients. A modified Gauss-Newton algorithm is used to perform the least-squares minimization. A statistical procedure is outlined to assess reliability of the estimated parameters. The solute transport model is solved by the upstream weighted, multiple cell balance method which combines the concepts of local mass balance and finite element approximations. A one-dimensional solute transport problem in a vertical column system is first used to illustrate the inverse technique. A second example considers the parameter identification problem for three-dimensional solute transport with a unidirectional steady and uniform flow field. The third example solves the parameter identification problem in a three-dimensional, stream-aquifer, solute transport system with steady state flow. Numerical experiments are conducted to study data requirements for parameter identification. 相似文献
154.
Robert M. Hirsch 《Journal of the American Water Resources Association》1988,24(3):493-503
ABSTRACT: This paper addresses two components of the problem of estimating the magnitude of step trends in surface water quality. The first is finding a robust estimator appropriate to the data characteristics expected in water-quality time series. The Hodges-Lehmann class of estimators is found to be robust in comparison to other nonparametric and moment-based estimators. A seasonal Hodges-Lehmann estimator is developed and shown to have desirable properties. Second, the effectiveness of various sampling strategies are examined using Monte Carlo simulation coupled with application of this estimator. The simulation is based on a large set of total phosphorus data from the Potomac River. To assure that the simulated records have realistic properties, the data are modeled in a multiplicative fashion incorporating flow, hysteresis, seasonal, and noise components. The results demonstrate the importance of balancing the length of the two sampling periods and balancing the number of data values between the two periods. The inefficiency of sampling at frequencies much in excess of 12 samples per year is demonstrated. Rotational sampling designs are discussed, and efficient designs, at least for this river and constituent, are shown to involve more than one year of active sampling at frequencies of about 12 per year. 相似文献
155.
Sheryl Luzzadder-Beach 《Environmental management》1995,19(3):383-392
What size sample is sufficient for spatially sampling ambient groundwater quality? Water quality data are only as spatially accurate as the geographic sampling strategies used to collect them. This research used sequential sampling and regression analysis to evaluate groundwater quality spatial sampling policy changes proposed by California's Department of Water Resources. Iterative or sequential sampling of a hypothetical groundwater basin's water quality produced data sets from sample sizes ranging from 2.8% to 95% coverage of available point sample sites. Contour maps based on these sample data sets were compared to an original (control), mapped hypothetical data set, to determine at which point map information content and pattern portrayal are not improved by increasing sample sizes. Comparing series of contour maps of ground water quality concentration is a common means of evaluating the geographic extent of groundwater quality change. Comparisons included visual inspection of contout maps and statistical tests on digital versions of these map files, including correlation and regression products. This research demonstrated that, down to about 15% sample site coverage, there is no difference between contour maps produced from the different sampling strategies and the contout map of the original data set. 相似文献
156.
William P. Carey 《Journal of the American Water Resources Association》1984,20(2):261-265
ABSTRACT: A technique for weighing bedload samples that was developed for laboratory use has been modified for field application. The technique involves determining the submerged weight of bedload samples as they are collected. The submerged weights are converted to dry weights from a knowledge of the specific gravity of the bedload material. The technique makes bedload transport data available immediately and eliminates costly and time-consuming steps involved with saving samples for laboratory analysis. Only samples designated for particle-size or other lab analyses need to be saved. 相似文献
157.
氰化物测定机理的研究 总被引:1,自引:0,他引:1
研究了酒石酸-硝酸锌法提取易释放氰化物,磷酸-EDTA提取总氰的机理;对异烟酸-吡唑啉酮光度法测定氰化物的条件作了探讨。 相似文献
158.
159.
Hans Preusting Jaap Kingma Gjalt Huisman Alexander Steinbüchel Bernard Witholt 《Journal of Polymers and the Environment》1993,1(1):11-21
WhenPseudomonas oleovorans (GPo1) is grown on sodium octanoate under ammonium limiting conditions, it is able to accumulate a copolyester consisting of medium chain length 3-hydroxyalkanoic acids (PHAm). 3-Hydroxybutyrate is only incorporated in trace amounts. WhenP. oleovorans is equipped with the PHB biosynthetic genes ofAlcaligenes eutrophus (GPo1[pVK101::PP1]), it forms a polyester containing major amounts of 3-hydroxybutyrate. The resulting polymer however is a blend of PHAm and PHB, rather than a copolymer of 3-hydroxybutyrate and medium chain length 3-hydroxyalkanoic acids [11]. To establish whether PHAm and PHB molecules are stored in the same or separate granules by this recombinantP. oleovorans strain, we studied polymer forming cells by freeze-fracture electron microscopy. This approach is possible because previous freeze-fracture electron microscopy studies on PHAm and PHB accumulating strains have shown that PHAm and PHB granules can be distinguished from each other: PHAm granules from mushroom-like structures, whereas PHB granules from needle structures during freeze-fracturing. In this paper we show that stationary phase cells of GPo1[pVK101::PP1] contained both mushroom and needle-like structures, indicating that PHAm and PHB chains were stored in separate granules. To be able to determine whether the separation of PHAm and PHB is complete, the respective granules were separated on sucrose gradients. A total cell extract of GPo1[pVK101::PP1] which was subjected to sucrose gradient centrifugation revealed two white bands of different densities: the upper band with a density of 1.05 g/mL consisted exclusively of PHAm granules, while the lower band with a density of 1.19 g/mL consisted of PHB granules only. Thus, when bacteria synthesize both PHAm and PHB, the resulting polymer chains are segregated completely and stored in separate granules. 相似文献
160.
揭开武汉东湖蓝藻水华消失之谜 总被引:115,自引:3,他引:112
水华(亦称湖靛)是湖泊富营养化最恶劣的表征之一。武汉东湖70年代至1984年间每年夏季出现蓝藻水华,1985年起突然消失,至今已有14年没有重现,原因何在?通过三次设在湖里的围隔试验,证明鲢鳙的大量放养,是水华消失的决定性因素。 相似文献