Synergistic effects of sodium hypochlorite disinfection and iron-oxidizing bacteria on early corrosion in cast iron pipes

• The early corrosion process in the cast iron pipes was investigated. • The increase of NaOCl (<0.75 mg/L) accelerated the cast iron corrosion. • Biocorrosion caused by IOB could be divided into three stages in the early stage. • Synergistic and antagonistic effects exist between residual chlorine and IOB. Corrosion in drinking water distribution systems (DWDSs) may lead to pipe failures and water quality deterioration; biocorrosion is the most common type. Chlorine disinfectants are widely used in DWDSs to inhibit microorganism growth, but these also promote electrochemical corrosion to a certain extent. This study explored the independent and synergistic effects of chlorine and microorganisms on pipeline corrosion. Sodium hypochlorite (NaOCl) at different concentrations (0, 0.25, 0.50, and 0.75 mg/L) and iron-oxidizing bacteria (IOB) were added to the reaction system, and a biofilm annular reactor (BAR) was employed to simulate operational water supply pipes and explain the composite effects. The degree of corrosion became severe with increasing NaOCl dosage. IOB accelerated the corrosion rate at an early stage, after which the reaction system gradually stabilized. When NaOCl and IOB existed together in the BAR, both synergistic and antagonistic effects occurred during the corrosion process. The AOC content increased due to the addition of NaOCl, which is conducive to bacterial regrowth. However, biofilm on cast iron coupons was greatly influenced by the disinfectant, leading to a decrease in microbial biomass over time. More research is needed to provide guidelines for pipeline corrosion control.     

利用DMA-80自动测汞仪直接测定海水中痕量汞

采用DMA-80自动测汞仪直接测定海水中的痕量汞,详细介绍了干燥时间、分解温度、释放温度等分析条件的优化选择。试验结果,方法在0.4～400ng范围内线性良好,检出限为2×10-5mg/L,方法操作简单,灵敏度高,结果准确。     

嵩屿电厂烟气海水脱硫工艺及特点分析

介绍了厦门嵩屿电厂4×300 MW燃煤机组烟气海水脱硫系统所选用的工艺,分析了海水FGD系统的主要技术特点,为日益增多的同类型脱硫装置的工艺设计与设备选型提供一定的借鉴.     

双套管长距离气力输送技术的应用

介绍了北仑发电厂5×600 MW机组烟气脱硫项目石灰石粉双套管长距离气力输送工程的系统设计、安装、调试、运行等情况,并分析了该系统的主要特点.     

基于微粒群算法的供水管网抗震优化设计

以管网年费用折算值为优化目标、管网拓扑结构与管径为优化参数、管网节点最低可靠度为约束条件,建立了供水管网抗震优化设计模型。利用微粒群算法对这一模型进行了求解,该算法以管网作为微粒个体,通过不断地更新微粒的位置来搜索最优的管网结构,直到最后给出优化的管网结构。利用上述方法对一典型供水管网进行了抗震优化设计分析,给出了3种不同节点最低可靠度约束条件下的优化改造方案。     

城市市政排水管网污染物溯源技术研究进展

城市市政排水管网污染源种类繁多且难以辨析,在未明确污染源前提下进行污染控制通常会因缺乏针对性而导致效果不佳,目前尚缺乏对已有管网污染物溯源技术的系统梳理,难以快速准确根据污染场景确定相应的溯源技术。系统综述了现有城市市政排水管网污染物溯源技术,包括物理排查法、特征因子法和水纹识别法等,阐明了各种典型技术方法的原理及在管网污染物溯源研究中的应用现状,比较了各溯源技术的优劣性及其应用场景,最后对管网溯源技术的未来研究方向进行了展望。针对排水管网内污染源错位问题,可在对管网物理排查的基础上,耦合使用数值模拟法、水纹识别法及特征因子法,确定目标溯源管段、可能排放行业以及具体排水户等,再结合稳定同位素法,厘清污染物的产生、输送及排放特性。本研究旨在为高效识别污染源位置、源强及排放过程提供基础支撑。

     

基于稳态与非稳态的喷吹管内流场的对比研究

针对等孔径喷吹管,利用CFD软件对其内流场进行数值模拟,得到不同入口流量条件下的流场分布特性。对喷吹管进行非稳态流场模拟,并与稳态模拟结果分析比较,模拟结果误差控制在1%以内,验证了将喷吹管非稳态内流场简化为稳态流场分析具有一定的可行性。沿着喷吹管气流流动方向,喷嘴出口流量分布不均匀,整体有增大的趋势;沿喷吹管轴向气流渐趋均匀,即越靠近端面,喷吹偏心角越小,甚至为0。     

餐饮业烟道油垢燃烧特性及动力学模型

利用热重分析仪研究了餐饮业油烟道油垢在不同升温速率下的燃烧特性.所采用的升温速率分别为5℃/min、15℃/min和25℃/min.吹扫气体为干空气,流量为20 mL/min.结果表明,试样从常温至800℃的升温燃烧经历了第1步水分析出、第2～5步燃烧失重过程.采用Doyle和Coats-Redfern方法建立了"4阶段1级反应动力学模型",计算燃烧反应的动力学参数.并用试验热重曲线验证了模型的可靠性.研究表明,油垢燃烧失重的4个主要过程均可用简单反应动力学模型进行简化,反应级数为1;燃烧总趋势是随升温速率提高,活化能增大.     

三通管支管位置对爆炸火焰传播影响分析*

为研究分支管道位置对丙烷爆炸火焰传播的影响规律,通过多组数值模拟与已有实验数据对比,分析不同工况下三通管内火焰传播形态变化特征及温度变化。结果表明:向右传播的爆炸气流在支管左侧形成湍流旋涡,火焰受到拖拽及壁面制约,贴支管右侧壁面呈尖刀状传播;封闭管道中,火焰传播受主管道高速前驱压力波回波影响更显著,垂直支管中火焰与高温风险更大;实验支管位置距离点火源5.6 m时岔口处监测点温度高达2 214.08 K,支管位置增加至5.71 m时,支管处湍流旋涡拖拽火焰,使火焰出现中断,支管移至5.825 m后高温火焰无法传播至支管口,支管中的爆炸风险显著降低。研究结果为工业生产三通管支管位置的选择和支管内二次爆炸风险预测提供科学参考。     

Interactive effects of cadmium and hypoxia on metabolic responses and bacterial loads of eastern oysters Crassostrea virginica Gmelin

Pollution by toxic metals including cadmium (Cd) and hypoxia are important stressors in estuaries and coastal waters which may interactively affect sessile benthic organisms, such as oysters. We studied metabolic responses to prolonged hypoxic acclimation (2 weeks at 5% O₂) in control and Cd-exposed (30 d at 50 μg L⁻¹ Cd) oysters Crassostrea virginica, and analyzed the effects of these stressors on abundance of Vibrio spp. in oysters. Hypoxia-acclimated oysters retained normal standard metabolic rates (SMR) at 5% O₂, in contrast to a decline of SMR observed during acute hypoxia. However, oysters spent more time actively ventilating in hypoxia than normoxia resulting in enhanced Cd uptake and 2.7-fold higher tissue Cd burdens in hypoxia. Cd exposure led to a significant decrease in tissue glycogen stores, increase in free glucose levels and elevated activity of glycolytic enzymes (hexokinase and aldolase) indicating a greater dependence on carbohydrate catabolism. A compensatory increase in activities of two key mitochondrial enzymes (citrate synthase and cytochrome c oxidase) was found during prolonged hypoxia in control oysters but suppressed in Cd-exposed ones. Cd exposure also resulted in a significant increase in abundance of Vibrio parahaemolyticus and Vibrio vulnificus levels during normoxia and hypoxia, respectively. Overall, Cd- and hypoxia-induced changes in metabolic profile, Cd accumulation and bacterial flora of oysters indicate that these stressors can synergistically impact energy homeostasis, performance and survival of oysters in polluted estuaries and have significant consequences for transfer of Cd and bacterial pathogens to the higher levels of the food chain.