厦门贝类养殖区重金属的含量分布特征与潜在生态危害评价

根据2005年4月和10月厦门贝类养殖区环境调查资料,着重对贝类养殖区海水、表层沉积物中重金属的含量分布进行分析,并对贝类养殖区的生态环境进行质量评价及潜在生态危害评价.结果表明:厦门贝类养殖区海水中Cu、Pb、Cd、Zn、Hg、As的平均含量分别为1.06 μg/L,1.23 μg/L, 0.05 μg/L,6.28 μg/L,0.033 μg/L,1.01 μg/L;沉积物中Cu、Pb、Cd、Zn、Hg、As的平均含量分别为20.0×10-6,39.5×10-6,0.07×10-6,97.3×10-6,0.05×10-6,7.20×10-6.生态质量评价结果表明,贝类养殖区海水重金属的含量符合第二类海水水质标准要求,处于清洁水平.养殖区沉积物重金属的含量符合第一类海洋沉积物质量标准,属于较清洁水平.潜在生态危害评价结果,Hg、As和Cd的潜在生态危害系数大于Cu、Pb、Zn,表明和Hg、As、Cd的潜在危害大于Cu、Pb、Zn,但整个养殖区沉积物中重金属的潜在危害属于轻微,养殖环境良好.     

海水中痕量元素测定及其在重金属污染源判别方面的应用

利用电感耦合等离子体质谱(ICP-MS)研究了胶州湾及莱州湾这两个海域中痕量元素污染水平,发展了ICP-MS海水环境中痕量元素的测定方法,同时找出海水环境中具有保守性的数种元素作为污染示踪元素.达到对于海水环境中痕量污染物被动示踪的目的.对18个真实样品进行了识别率试验,识别率可达90%以上,在选取3个海水样品及1个河水样品混合后的模拟分担率实验,也取得了满意的结果,其误差平均值仅有1.17%.     

福建近岸表层海水中阴离子表面活性剂和PCB的污染

用亚甲蓝分光光度法和GC-ECD法分别对福建近岸表层海水中的阴离子表面活性剂和PCBs进行了分析,初步探讨了表层海水中这两类污染物的来源.表层海水中阴离子表面活性剂浓度范围为0.04～1.987 mg/L,较高浓度值站点主要位于九龙江口、闽江口和湄洲湾海域.PCBs的浓度在3.9～367.1 ng/L之间,整体上近岸站点浓度值比离岸站点高,中北部浓度值比南部高.与其他地区的研究结果及海水水质标准进行比较,福建沿海表层海水中阴离子表面活性剂和PCB的污染都较为严重.     

One-step estimation method and nomogram to predict safety distances of pressurized gas pipelines from blast sources

Pressurized gas pipelines may be endangered by accidental or intentional activities causing excess ground vibrations leading to failure. Thus, many papers have been published on this issue, yet most of these efforts suffer from complexity and inability to ascertain that all engaged factors are taken into account. These factors are attributed, namely, to explosion source, explosion-ground interaction, energy transfer through the ground, ground-pipeline interaction, and response of the pipeline. The deterministic method developed previously by the author has derived useful prediction mathematical formulas that can be used to calculate, either the stand-off distance of purposefully used explosives, or the maximum quantity of explosives to be used at a given distance, or the equivalent stress of a pipeline induced by an explosive charge at a given standoff distance. The method can also be applied to accidental blast events in factories or other activities. Yet, the complex formulas developed are hard to be used in the field and a simpler approach is needed to facilitate and accelerate in-field estimations. Thus, a nomogram was prepared to make the safety estimations easy and fast and taking into account all engaged critical factors starting from the explosion source through the integrity of the structure.     

Underground parallel pipelines domino effect: An analysis based on pipeline crater models and historical accidents

This paper focuses on the analysis of the possibility of domino effect in underground parallel pipelines relying on historical accident data and pipeline crater models. An underground pipeline can be considered as safe following an accident with an adjacent gas or liquefied pipeline when it remains outside the ground crater generated. In order to prevent the domino effect in these cases, the design of parallel pipelines has to consider adequate pipeline separations based on the crater width, which is one of the widely used methods in engineering applications. The objective of this work is the analysis of underground petroleum product pipelines ruptures with the formation of a ground crater as well as the evaluation of possible domino effects in these cases. A detailed literature survey has been carried out to review existing crater models along with a historical analysis of past accidents. A FORTRAN code has been implemented to assess the performance of the Gasunie, the Batelle and the Advantica crater models. In addition to this, a novel Accident-Based crater model has been presented, which allows the prediction of the crater width as a function of the relevant design pipeline parameters as well as the soil density. Modifications have also been made to the Batelle and Accident-Based models in order to overcome the underestimation of the crater width. The calculated crater widths have been compared with real accident data and the performance evaluation showed that the proposed Accident-Based model has a better performance compared to other models studied in this work. The analysis of forty-eight past accidents indicated a major potential of underground parallel pipelines domino effect which is proven by two real cases taken from the literature. Relying on the investigated accidents, the crater width was smaller than or equal to 20 m in most cases indicating that the definition of underground pipeline separations at around 10 m would be sufficient to ensure a small probability of the domino effect.     

烟台夹河河口海水混合过程的地球化学特征研究

海(咸)水混入是河口河水重要的地质过程,深刻地影响河水地球化学过程。本文系统采集夹河河口水样,分析海淡水混合过程的地球化学特征。结果表明,远离河口段(J10~J14)为淡水性质,主要受水-岩作用及人类活动等影响;近河口段(J1~J8)海水混入严重,F~-、Cl~-、Br~-、SO~(2-)_4、Na~+、K~+、Mg~(2+)、Ca~(2+)、盐度等明显较高,主要受海水混入影响。近河口段存在Na-Ca离子交换过程,约占Na~+总量的0.9%~1.5%,离子交换量随海水混入比例增加而增加,Na~+离子交换量与K~+,Ca~(2+)、Mg~(2+)、Br~-、F~-、SO~(2-)_4离子交换量相关,且河水离子含量与盐度回归系数略低于与盐度、Na~+交换量回归系数,表明河口段河水离子交换影响河水地球化学特征。     

RS-PSO-ELM下腐蚀管道失效压力预测

为提高腐蚀管道失效压力的预测精度并简化其计算过程,提出基于粗糙集(RS)和粒子群算法(PSO)融合极限学习机(ELM)的腐蚀管道失效压力预测模型。通过属性约简提取影响失效压力的关键因素,选用PSO优化ELM的输入权值和隐含层偏差,将归一化的核心指标数据代入计算。结果表明:该模型预测结果与实际值基本一致,与单一ELM模型相比,预测结果的均方差(MSE)降至0.255;与其他蚀管道失效压力评价模型相比,该模型预测结果的绝对误差平均值降至0.32。     

盐度变化对崇明东部河口潮滩氮营养盐循环影响实验模拟研究

以长江口咸淡水交互作用最为典型岸段崇明东部潮滩作为研究区域,运用实验模拟方法,定量地研究了盐度变化对潮滩生态系中无机氮的迁移、转化过程的影响。结果发现,盐度升高有利于沉积物中的NH4-N向上覆水扩散,但NO2-N和NO3-N的界面扩散呈现相反的变化趋势;沉积物中可交换态无机氮含量变化特征显示,在盐度变化剧烈的潮滩生态系统内,硝化作用可能是控制沉积物(尤其是表层沉积物)中无机氮分布的重要因素。     

Effects of seawater salinity on nitrite accumulation in short-range nitrification to nitrite as end product

The effect of seawater salinity on nitrite accumulation in short-range nitrification to nitrite as the end product was studied by using a SBR. Experimental results indicated that the growth of nitrobacteria was inhibited and very high levels of nitrite accumulation at different salinities were achieved under the conditions of 25--28℃, pH 7.5--8.0, and the influent ammonia nitrogen of 40--70mg/L when seawater flow used to flush toilet was less than 35% (salinity 12393 mg/L, Cl^- 6778mg/L) of total domestic wastewater flow, which is mainly ascribed to much high chlorine concentration of seawater. Results showed that high seawater salinity is available for short-range nitrification to nitrite as the end product. When the seawater flow used to flush toilet accounting for above 70% of the total domestic wastewater flow, the removal efficiency of ammonia was still above 80% despite the removal of organics declined obviously(less than 60% ). It was found that the effect of seawater salinity on the removal of organics was negative rather than positive one as shown for ammonia removal.