流动海水环境中人工破损有机涂层的劣化过程研究

目的研究流动海水环境中人工破损有机涂层的劣化过程。方法使用电化学阻抗谱(EIS)技术对比研究流动海水与静止海水环境中破损涂层的劣化行为,跟踪观察涂层宏观形貌演变。结果根据EIS响应特征,发现流动海水中的人工破损有机涂层劣化更快,且在浸泡后期流动海水中破损涂层没有形成扩散阻抗。根据涂层宏观形貌发展,发现静止海水中涂层仅围绕破损处出现了面积较小的锈点和鼓泡,而流动海水中涂层因劣化而产生的锈点和鼓泡面积更大且大量分布在整个涂层表面。结论当人工破损有机涂层在流动海水和静止海水环境的浸泡过程中,涂层劣化首先从人工破损处开始。破损处成为局部腐蚀反应主要的阳极区,破损处周围的区域和涂层内在缺陷处成为扩展腐蚀反应的阴极区。流动海水中涂层的腐蚀产物累积与脱落更加频繁,导致涂层劣化速度加快和基体金属腐蚀加剧。     

危化品海水快速分离工艺探究

目前国内外均无成熟的危化品海水分离装置,急需探索出可以有效进行危化品海水原位快速分离的工艺,解决海上危化品泄漏后危化品污染海水原位分离困难的问题,提高海上应急水平。用二甲苯作为海上运输常见危化品的代表,选择几种典型的污染物水分离工艺(重力分离、膜分离、吸附分离),分别在海水条件下进行了效果测试,并对3种工艺进行了串联组合和效果验证。结果表明:重力分离能够在10 min内将二甲苯海水高比例混合物快速分离,并将二甲苯质量浓度降至160～200 mg/L;膜分离能够耐冲击地完成对大质量浓度(如20 000 mg/L)二甲苯海水混合物的分离,将二甲苯质量浓度降至60 mg/L左右,但处理后的污染海水再过膜没有进一步的分离效果;吸附分离根据前期的柱试验结果选择了吸附容量较大且适宜填罐的活性炭种类IPG1240;重力分离-膜分离-吸附分离的组合能够实现危化品与海水的快速分离。     

海水环境生物腐蚀污损与防护

以海水环境生物腐蚀污损与防护为中心,就国内外与其相关的报道进行综述分析,并提出建议。首先,分析污损生物的分布与特征,得出污损生物群落的组成和结构对海域、季节、水深、工程结构类型等的依赖性,突出海水环境生物腐蚀污损的复杂性。然后,解析生物附着污损对海水环境腐蚀速率的影响,突出附着生物是导致金属材料腐蚀速率增大的重要因子。再次,介绍海水环境生物腐蚀污损防护技术的现状,分析主要防护技术的优缺点,并展示其在不同行业的联用。最后,提出对海水环境生物腐蚀污损研究工作的建议,包括建立各海域的生物腐蚀污损数据库、大力研制发展绿色生物腐蚀污损控制技术、加强对海洋生物腐蚀污损基础性研究工作的投入、尽快建立海洋生物腐蚀评价标准和规范等。     

Decentralized scheme for leaks’ location in a branched pipeline

This article presents a novel scheme for the detection and isolation of single leaks in a pipeline with a branch junction by measuring only the flow rate and pressure at the ends of the line. For the solution of this realistic issue, which commonly occurs in pipeline networks, the position of the branch junction and its flow rate are supposed to be known. The idea consists of deriving a model considering the branch junction as a known point in the pipeline such that the leak position is characterized by two possible orientations with respect to the branch (upstream and downstream of it). Thus, this model allows proposing a diagnosis scheme which includes a static selector and two identifiers designed by using a continuous extended Kalman filter with only one deviation parameter to be estimated. This framework reduces the identification task to one parameter which is associated with the deviation from a prescribed positive base position located between one of the pipeline ends and the branch. Simulation and experimental results with data of a hydraulic pilot pipeline of 200 [m] show the promise of the novel scheme.     

Risk assessment of offshore crude oil pipeline failure

Failure of Leak Detection System (LDS) to detect pipeline leakages or ruptures may result in drastic consequences that could lead to excessive financial losses. To minimize the occurrence of such failure, the functionality of the LDS and the integrity of the pipeline should be assessed on a priority basis. This paper presents an integrated risk-based assessment scheme to predict the failure and the failure consequences of offshore crude oil pipelines. To estimate risk, two important quantities have to be determined, the joint probability of failure of the pipeline and its LDS and the consequences of failure. Consequences incorporate the financial losses associated with environmental damage, oil spill cleanup and lost production. The assessment provides an estimate of the risk in monetary value and determines whether the estimated risk exceeds a predefined target risk. Moreover, the critical year for the asset can be determined. In essence, the outcome of the assessment facilitates an informed decision-making about the future of the asset.     

ADVANCES IN THE BOUNDARY INTEGRAL EQUATION METHOD IN SUBSURFACE FLOW1

ABSTRACT: This paper explores some of the advances of the boundary element method, as applied to ground-water problems, during the last five years. Although the method is still somewhat limited compared to solution by finite elements, the range of solutions has increased considerably. Diffusion and advection-diffusion solutions are done efficiently. These include the incorporation of inhomogeneity, anisotropy, and nonlinear diffusion. The difficult problem of stream-aquifer interaction is an important application as it is much easier to follow a free surface with its multiple configurations. The application must be able to cycle between ground-water connection and disconnection with the stream and include seepage surfaces. Flow in fractured media is a natural application where the flow in fractures can usually be treated without a computational exception in spite of extremely high aspect ratios. The case of seawater intrusion forms a type of free surface problem and thus is a case for which the method has special advantages. For these and other applications the boundary element method provides an inexpensive technique for calculation where the data preparation and setup time is minimal. In most of these cases, programs can and have been written on microcomputers.     

Geostatistical analysis as applied to two environmental radiometric time series

This article details the results of an investigation into the application of geostatistical data analysis to two environmentalradiometric time series. The data series employed consist of ⁹⁹Tc values for seaweed (Fucus vesiculosus) and seawater samples taken as part of a marine monitoring program conducted on the coast of northern Norway by the Norwegian Radiation Protection Authority. Geostatistical methods were selected in order to provide information on values of the variables at unsampled times and to investigate the temporalcorrelation exhibited by the data sets. This information is ofuse in the optimisation of future sampling schemes and for providing information on the temporal behaviour of the variablesin question that may not be obtained during a cursory analysis.The results indicate a high degree of temporal correlation withinthe data sets, the correlation for the seawater and seaweed databeing modelled with an exponential and linear function,respectively. The semi-variogram for the seawater data indicatesa temporal range of correlation of approximately 395 days with noapparent random component to the overall variance structure and was described best by an exponential function. The temporal structure of the seaweed data was best modelled by a linear function with a small nugget component. Evidence of drift was present in both semi-variograms. Interpolation of the data setsusing the fitted models and a simple kriging procedure were compared, using a cross-validation procedure, with simple linearinterpolation. Results of this exercise indicate that, for theseawater data, the kriging procedure outperformed the simpleinterpolation with respect to error distribution andcorrelation of estimates with actual values. Using theunbounded linear model with the seaweed data produced estimatesthat were only marginally better than those produced by thesimple interpolation.     

NH4NO3-Pd(NO3)2联合基体改进剂石墨炉法测海水中痕量镉

用NH4NO3-Pd(NO3)联合基体改进剂,石墨炉法直接测海水中痕量镉.通过不同条件的实验,确定了最佳的分析条件;并通过对实际样品平行性和加标回收率的测定,验证了方法的精密度和准确度.建立了空白实验,在0.19～5.0μg/L线性范围内,镉的最低检出限为0.19μg/L.实验结果表明,该方法快速方便,提高了分析效率,准确度高,精密度好.     

深圳妈湾排海工程非设计条件下海水入侵与冲洗研究

本文从微观的角度，分析了排海工程扩散管内海水入侵与冲洗的临界水力特点，并通过理论分析和物理模型试验的相互验证，得出了上述临界水力条件的判别关系式，提出了判别方法，并由此得到了深圳妈湾排海工程防止海水入侵的临界排放流量和出现海水入侵后的最小冲洗流量，为排海工程在非设计条件下的运行管理提供了依据。     

脱硫海水恢复试验研究

阐述了影响脱硫海水恢复的因素，着重介绍了稀释比、稀释方式、曝气时间、曝气速率等因素对海水恢复的影响试验，试验结果对脱硫海水恢复系统的优化设计具有一定的参考价值。