全文获取类型
收费全文 | 12413篇 |
免费 | 1538篇 |
国内免费 | 7721篇 |
专业分类
安全科学 | 1883篇 |
废物处理 | 453篇 |
环保管理 | 1082篇 |
综合类 | 11734篇 |
基础理论 | 2582篇 |
环境理论 | 2篇 |
污染及防治 | 2609篇 |
评价与监测 | 683篇 |
社会与环境 | 400篇 |
灾害及防治 | 244篇 |
出版年
2024年 | 97篇 |
2023年 | 570篇 |
2022年 | 811篇 |
2021年 | 855篇 |
2020年 | 842篇 |
2019年 | 851篇 |
2018年 | 735篇 |
2017年 | 758篇 |
2016年 | 919篇 |
2015年 | 914篇 |
2014年 | 790篇 |
2013年 | 1356篇 |
2012年 | 1292篇 |
2011年 | 1363篇 |
2010年 | 941篇 |
2009年 | 1080篇 |
2008年 | 886篇 |
2007年 | 1063篇 |
2006年 | 1011篇 |
2005年 | 764篇 |
2004年 | 626篇 |
2003年 | 588篇 |
2002年 | 434篇 |
2001年 | 368篇 |
2000年 | 321篇 |
1999年 | 266篇 |
1998年 | 189篇 |
1997年 | 185篇 |
1996年 | 153篇 |
1995年 | 139篇 |
1994年 | 104篇 |
1993年 | 98篇 |
1992年 | 64篇 |
1991年 | 31篇 |
1990年 | 26篇 |
1989年 | 25篇 |
1988年 | 17篇 |
1987年 | 9篇 |
1986年 | 12篇 |
1985年 | 6篇 |
1984年 | 10篇 |
1983年 | 11篇 |
1982年 | 13篇 |
1981年 | 10篇 |
1980年 | 7篇 |
1979年 | 5篇 |
1975年 | 4篇 |
1973年 | 6篇 |
1972年 | 6篇 |
1971年 | 33篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
61.
Prenatal diagnosis in a kindred with the Opitz (BBB) syndrome is presented. The inheritance is consistent with either autosomal dominant inheritance with sex limited expression or X-linked inheritance. The abnormalities in the kindred consist of hypertelorism, hypospadias, ambiguous genitalia, urocolic fistula, imperforate anus, mental retardation, diaphragmatic hernia, and malrotation with volvulus. A male fetus at 19 weeks was found by ultrasound to have hypertelorism and hypospadias with a small phallus consistent with the syndrome. The diagnosis was confirmed by pathologic examination after pregnancy termination. This is the first report of prenatal diagnosis of Opitz syndrome by ultrasonographic demonstration of hypertelorism and hypospadias in the second trimester. 相似文献
62.
在硫酸介质中,邻苯氨基苯甲酸与硝酸盐(NO_3~-)生成紫红色络合物.本文依据悬浮颗粒对光的吸收性质研究利用该灵敏反应测定 NO_3~—N 新光度法——(?)次双波长法,通过对样品分析,可提高分析灵敏度和精密度,回收良好,且操作简单快速,计算曲线稳定,适合于测定地下水,湖水等天然水体 NO_3~-—N. 相似文献
63.
本文对我国城市有机混合垃圾经模化后,在过剩空气系数α?2,温度在700~900℃条件下焚烧的气态排放物进行了定性和定量分析.实验结果表明:烟气呈碱性,主要污染物NH_2的排放浓度最高.HCl次之,NO_x<100ppm,SO_x<1ppm,H_2S<10ppm. 相似文献
64.
A case of spontaneous abortion after transcervical CVS is presented. Despite no evidence of bacteria in the vagina and cervix prior to sampling and the prophylactic use of Metronidazole, pathological evidence of chorioamnionitis was found. The implications of this are discussed. 相似文献
65.
Fan Jinhong Xu Wenying Gao Tingyao Ma Luming 《Frontiers of Environmental Science & Engineering in China》2007,1(4):504-508
Iron and copper bimetallic system (catalyzed Fe-Cu process) is a promising technology for alkaline nitrobenzene-containing
wastewater treatment. However, little is currently known about the changes of treatment efficiency with time going. This research
investigated the long-term performance of the catalyzed Fe-Cu process to reduce nitrobenzene (NB) in alkaline wastewater.
In addition, the changes of the metal surfaces morphologies and matters before and after the reaction were analyzed by scanning
electron microscopy (SEM) in conjunction with energy-dispersion spectroscopy (EDS) and X-ray diffraction spectroscopy (XRD).
The results showed that the surface properties of copper almost remained unchanged after weeks of operation, which spelled
its strong chemical stability and resistance to poisoning. Moreover, the results indicated that there were two reasons for
the treatment efficiency decreasing with time. One was the gradual iron element consumption due to corrosion. The other was
iron reactivity weakened due to the precipitates accumulation on the surfaces that were mainly Fe3O4 and FeCO.
__________
Translated from Environmental Pollution & Control, 2006, 28(10): 783–785 [译自: 环境污染与防治] 相似文献
66.
67.
68.
《环境科学学报(英文版)》2023,35(4):387-395
This study examined the effectiveness for degradation of hydrophobic (HPO), transphilic (TPI) and hydrophilic (HPI) fractions of natural organic matter (NOM) during UV/H2O2, UV/TiO2 and UV/K2S2O8 (UV/PS) advanced oxidation processes (AOPs). The changing characteristics of NOM were evaluated by dissolved organic carbon (DOC), the specific UV absorbance (SUVA), trihalomethanes formation potential (THMFP), organic halogen adsorbable on activated carbon formation potential (AOXFP) and parallel factor analysis of excitation–emission matrices (PARAFAC-EEMs). In the three UV-based AOPs, HPI fraction with low molecular weight and aromaticity was more likely to degradate than HPO and TPI, and the removal efficiency of SUVA for HPO was much higher than TPI and HPI fraction. In terms of the specific THMFP of HPO, TPI and HPI, a reduction was achieved in the UV/H2O2 process, and the higest removal rate even reached to 83%. UV/TiO2 and UV/PS processes can only decrease the specific THMFP of HPI. The specific AOXFP of HPO, TPI and HPI fractions were all able to be degraded by the three UV-based AOPs, and HPO content is more susceptible to decompose than TPI and HPI content. UV/H2O2 was found to be the most effective treatment for the removal of THMFP and AOXFP under given conditions. C1 (microbial or marine derived humic-like substances), C2 (terrestrially derived humic-like substances) and C3 (tryptophan-like proteins) fluorescent components of HPO fraction were fairly labile across the UV-based AOPs treatment. C3 of each fraction of NOM was the most resistant to degrade upon the UV-based AOPs. Results from this study may provide the prediction about the consequence of UV-based AOPs for the degradation of different fractions of NOM with varied characteristics. 相似文献
69.
Guofei Jiang Benjie Zhu Junzhi Sun Fang Liu Yongqiang Wang Chaocheng Zhao 《环境科学学报(英文版)》2023,35(3):244-257
High-efficiency photocatalysts are of great significance for the application of photocatalytic technology in water treatment.In this study,N/Cu co-doped ZnS nanosphere photocatalys(N/Cu-ZnS) is synthesized by a hydrothermal method for the first time.After doping,the tex ture of nanosphere becomes loose,the nanometer diameter is reduced,making the specific surface area of catalyst increased from 34.73 to 101.59 m2/g.The characterization results show that more ZnS (111) crystal planes a... 相似文献
70.
《环境科学学报(英文版)》2023,35(4):263-274
The cryptomelane-type manganese oxide (OMS-2)-supported Co (xCo/OMS-2; x = 5, 10, and 15 wt.%) catalysts were prepared via a pre-incorporation route. The as-prepared materials were used as catalysts for catalytic oxidation of toluene (2000 ppmV). Physical and chemical properties of the catalysts were measured using the X-ray diffraction (XRD), Fourier transform infrared spectroscopic (FT-IR), scanning electron microscopic (SEM), X-ray photoelectron spectroscopy (XPS), and hydrogen temperature-programmed reduction (H2-TPR) techniques. Among all of the catalysts, 10Co/OMS-2 performed the best, with the T90%, specific reaction rate at 245°C, and turnover frequency at 245°C (TOFCo) being 245°C, 1.23 × 10−3 moltoluene/(gcat·sec), and 11.58 × 10−3 sec−1 for toluene oxidation at a space velocity of 60,000 mL/(g·hr), respectively. The excellent catalytic performance of 10Co/OMS-2 were due to more oxygen vacancies, enhanced redox ability and oxygen mobility, and strong synergistic effect between Co species and OMS-2 support. Moreover, in the presence of poisoning gases CO2, SO2 or NH3, the activity of 10Co/OMS-2 decreased for the carbonate, sulfate and ammonia species covered the active sites and oxygen vacancies, respectively. After the activation treatment, the catalytic activity was partly recovered. The good low-temperature reducibility of 10Co/OMS-2 could also facilitate the redox process accompanied by the consecutive electron transfer between the adsorbed O2 and the cobalt or manganese ions. In the oxidation process of toluene, the benzoic and aldehydic intermediates were first generated, which were further oxidized to the benzoate intermediate that were eventually converted into H2O and CO2. 相似文献