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41.
《环境科学学报(英文版)》2023,35(3):319-331
Oxidation-absorption technology is a key step for NOx removal from low-temperature gas. Under the condition of low O3 concentration (O3/NO molar ratio = 0.6), F-TiO2 (F-TiO2), which is cheap and environmentally friendly, has been prepared as ozonation catalysts for NO oxidation. Catalytic activity tests performed at 120°C showed that the NO oxidation efficiency of F-TiO2 samples was higher than that of TiO2 (about 43.7%), and the NO oxidation efficiency of F-TiO2-0.15 was the highest, which was 65.3%. Combined with physicochemical characteristics of catalysts and the analysis of active species, it was found that there was a synergistic effect between F sites and oxygen vacancies on F-TiO2, which could accelerate the transformation of monomolecular O3 into multi-molecule singlet oxygen (1O2), thus promoting the selective oxidation of NO to NO2. The oxidation reaction of NO on F-TiO2-0.15 follows the Eley-Rideal mechanism, that is, gaseous NO reacts with adsorbed O3 and finally form NO2. 相似文献
42.
综合分析了现代腕足类生物壳体方解石中的C、O同位素特征,以及有关古生代腕足类生物壳体方解石构造和地球化学研究成果,分析结果证明:只有那些无发光性特点、无胶结和溶蚀构造特点、有较好纤维构造特点、含高Sr、Na和低Mn、Fe(Mg)的第二层腕足类生物壳体方解石的δ18O值不受成岩作用影响;而原始层和壳体中的特殊部位如铰合轴、腕骨、茎孔、交互面、肌痕等在沉积、成岩过程中与海水处于非同位素平衡状态。 相似文献
43.
Yang Zhang Tianyi Zhao Yu Yan Bian Zhou Xuezhen Zhong Xiaoyu Hu Lijia Zhang Peng Huo Kang Xiao Yuanxun Zhang 《环境科学学报(英文版)》2023,35(2):835-845
Ambient particulate matter (PM) can cause adverse health effects via their ability to produce Reactive Oxygen Species (ROS). Water-Soluble Organic Compounds (WSOCs), a complex mixture of organic compounds which usually coexist with Transition Metals (TMs) in PM, have been found to contribute to ROS formation. However, the interaction between WSOCs and TMs and its effect on ROS generation are still unknown. In this study, we examined the ROS concentrations of V, Zn, Suwannee River Fulvic Acid (SRFA), Suwannee River Humic Acid (SRHA) and the mixtures of V/Zn and SRFA/SRHA by using a cell-free 2′,7′-Dichlorodihydrofluorescein (DCFH) assay. The results showed that V or Zn synergistically promoted ROS generated by SRFA, but had an antagonistic effect on ROS generated by SRHA. Fluorescence quenching experiments indicated that V and Zn were more prone to form stable complexes with aromatic humic acid-like component (C1) and fulvic acid-like component (C3) in SRFA and SRHA. Results suggested that the underlying mechanism involving the fulvic acid-like component in SRFA more tending to complex with TMs to facilitate ROS generation through π electron transfer. Our work showed that the complexing ability and complexing stability of atmospheric PM organics with metals could significantly affect ROS generation. It is recommended that the research deploying multiple analytical methods to quantify the impact of PM components on public health and environment is needed in the future. 相似文献
44.
张忠 《石油化工环境保护》2006,29(1):51-53
介绍了HBCOD-1型COD在线自动监测仪的测定原理、分析流程和性能特点。仪器采用重铬酸钾氧化水中有机物和还原性无机物,通过分光光度法测定水中化学耗氧量(COD值)。与国标方法进行线性回归校正后,仪器测定值与国标方法测得的CODCr,值具有较好的一致性。 相似文献
45.
重铬酸钾法测定化学需氧量的几点体会 总被引:1,自引:0,他引:1
重铬酸钾法是测定工业废水中化学需氧量的国家标准方法,通过大量的实验对CODCr的实验进行探索,提出几点体会,在CODCr的测定中有一定的实用性。 相似文献
46.
47.
氮、氧稳定同位素指标在N2 O源汇识别、全球源汇质量估算中具有独特的定量作用。本文主要讨论N2 O的氮、氧稳定同位素真空制样系统的基本原理、总体设计和技术难点 ,为建立N2 O氮、氧稳定同位素真空制样系统提供理论基础。 相似文献
48.
本文主要介绍了用~(210)Pb─~(210)Bi法测定海洋现代沉积速率和数据处理方法的研究。该方法测定的结果与~(210)Pb─~(210)Po法和阴离子交换-EDTA纯化-硫酸钡镭沉淀-α计数法(简称~(226)Ra法)以及厦门大学海洋系经研究改进的分离、纯化~(210)Pb的离子交换法的测定结果相当吻合。 相似文献
49.
《环境科学学报(英文版)》2023,35(3):798-810
Although point and nonpoint sources contribute roughly equal nutrient loads to lakes, their relative role in supporting algae growth has not been clarified. In this research, we have established a quantitative relationship between algae-available phosphorus (P) and P chemical fractions in sediments; the latter indicates the relative contribution of point versus nonpoint sources. Surface sediments from three large shallow lakes in eastern China, namely, the Chaohu, Taihu and Hongzehu Lakes, were sampled to assess their algae-available P and chemically extracted P fractions. The algae-available P primarily comes from iron/aluminium (hydr)oxide-bound P (Fe/Al-bound P), 45% of which is algae-available P. The ratio of Fe/Al-bound P to calcium compound-bound P (Ca-bound P) indicated the relative contribution of point to nonpoint sources, with the point sources contributing the majority of increased Fe/Al-bound P in sediments. Therefore, the reduction of point sources from urbanized areas, rather than nonpoint sources from agricultural areas that primarily contribute to the Ca-bound P fraction, should be prioritized to alleviate cyanobacterial algal blooms (CyanoHABs) in shallow lakes with sediment P as a potential source to support algae growth. With these important results, we proposed a conceptual model for “P-pumping suction” from sediments to algae to aid in the development of the criteria for sediment P concentrations in shallow lakes. 相似文献
50.
结合上海市合流污水治理二期工程排放管稀释扩散规律及泥沙冲淤规律的研究,利用少运动相似理论,通过模型试验,从环境泥沙积在上管喷口上的最不利条件出发,分析喷口对泥沙的冲液规律,提出喷口冲淤临界速的概念,并据此提出适宜的上升管高度及喷口射流角度。 相似文献