汽车制造企业恶臭来源及影响分析

挥发性有机物(VOCs)是工业恶臭的重要来源之一.本文以某汽车制造企业为研究对象,对其产生的恶臭来源及对敏感点居民区的影响进行采样和分析.2016年11月15~17日,分别采用三点比较式臭袋法和大气预浓缩仪-气相色谱(GC)-质谱(MS)联用法对该企业厂区内各个车间的排气筒、厂界和敏感点的臭气浓度和VOCs组分进行定性、定量分析.结果表明,该企业整车厂和发动机厂各个车间排气筒的臭气浓度均未超标,发动机厂厂界的臭气浓度未超标,但整车厂的厂界和敏感点的臭气浓度均超过标准限值.监测共确认54种VOCs物种,包括芳香烃、卤代烃、烷烃、烯烃、环烷烃、酮类、酯类、醚类、醇类、含硫化合物和含氧环化合物.其中,卤代烃种类最多,其次是芳香烃.由此可知,汽车制造恶臭类代表物质主要是卤代烃和芳香烃.根据敏感点居民区特征VOCs物种的质量浓度、检知嗅阈和阈稀释倍数筛选出敏感点居民区的典型恶臭物质为1,3-丁二烯.针对涂装车间所用涂料进行定性分析,结果表明,绝大部分特征VOCs物种均来自涂料成分.恶臭贡献最大的1,3-丁二烯,在排除敏感点居民区周边其他污染源影响的情况下,推断其来源是整车厂涂装车间的喷涂和烘干工艺所产生的.建议企业采用含VOCs组分较低的环保涂料或更高处理效率的RTO净化装置,以减少汽车制造过程对居民区敏感点的恶臭影响.     

Visions and strategies for growth management: Teller County/Woodland Park example

This article is the third in a series prepared to explain the Teller County growth management planning process. Once it was determined by local decision-makers that Teller County, Colorado, would pursue a policy of directed growth, concepts based on this policy were developed. These concepts presented visions and options for the future. Landscape plans then were developed for Teller County and the City of Woodland Park planning area so that these options could be visualized by local leaders and the public. The landscape plans were used as part of the ongoing citizen involvement process to inform the public about the options for growth management. To provide even more information, detailed designs were developed for specific areas in the county. From the landscape plan, public involvement effort, and detailed designs, specific implementation measures were identified, discussed, and adopted. These measures included guidelines for administration, so that county and city goals could be linked to the actual day-to-day management of development proposals. Paper 3 in a series of 3.     

烟囱高度合理性论证技术方法研究

通过研究有关烟囱高度合理性的国家标准、规定和方法,指出影响污染物落地浓度的主要影响因子,结合一些烟囱高度合理性设计的实例,总结出了一套论证烟囱高度合理性的方案,并从气象和环境空气影响角度对不同高度烟囱合理性进行了检验.分析结果表明,烟囱高度要以适合当地气象和环境空气质量实际情况为原则,最大限度地减轻污染物落地浓度对当地造成的不利影响.这对减轻污染和减少厂家经费投入以及对于指导大气环境影响评价工作具有重要的现实意义.     

县域生态功能区划研究——以桐柏县为例

结合桐柏县的实例，对县域生态功能区划分的原则和方法进行初步探讨。综合利用3S技术对县域生态敏感性和生态服务功能重要性的分析和评价，提出桐柏县生态服务功能区划的初步方案。将桐柏县划分为生态支持区，产品供给区，生态调节区。简要分析了各功能区在桐柏县经济可持续发展中的地位和作用，指出各区协调发展的方向和途征。     

景观格局类型对热岛效应的影响——以福州市中心城区为例

以“火炉”城市之一福州市为例,运用RS与GIS技术、半变异函数分析等方法,以2009年、2018年Landsat TM/OLI系列影像为数据源,从城市尺度分析了景观格局与城市热岛的关系,从景观格局特征尺度分析了景观格局类型对热岛效应的影响.结果表明：从2009年、2018年9个景观格局指数计算结果显示福州市中心城区景观格局破碎化程度增加;2009年与2018年的景观格局特征尺度分别为3600m,2500m,表明后者的景观格局更为丰富;虽然主城区的热岛效应得到了一定缓解,但城市热岛的范围逐渐扩大,八个新城分别成为了新的热岛中心;不同景观格局类型的热岛效应的严重情况依次为：纯人工本底格局 > 人工本底的散布格局 > 人工本底的指状、网络格局 > 自然本底的指状、网络格局 > 自然本底的散布格局 > 纯自然本底格局.研究以期通过细化景观格局研究尺度,为具有热岛降温作用的景观格局提出优化的方向.     

Thermal runaway criterion for chemical reaction systems: A modified divergence method

The chemical reaction in certain range of operating conditions may exhibit parametric sensitivity where small changes in one or more of the input parameters lead to changes in the output variables (eg. reaction temperature). The sharp rise of the reaction temperature is a critical behavior that may lead to runaway conditions. Thus, it is of vital importance to determine the critical operating parameters consisting of the parametric sensitivity region under the consideration of intrinsic safety. In this paper, a modified divergence criterion is proposed based on the trace of Jacobian matrix at the maximum temperature. The nonlinear differential equations describing the dynamic behavior of the chemical reaction is linearized locally in the vicinity of the equilibrium point by the small perturbation analysis. The relationship between the perturbation equation and parametric sensitivity of the reaction system is investigated. The critical values computed by the modified divergence criterion are compared with Morbidelli and Varma criterion (MV criterion), Adler and Enig criterion (AE criterion) and divergence criterion (Div criterion). The comparison demonstrates the validity of the new criterion. In addition, the critical explosion pressures of two kinds of hazardous chemicals are computed by the various critical criteria and compared with published experimental data. The results show that the modified divergence criterion could give smaller computational error compared with the previous criteria.     

A Multidisciplinary Conceptualization of Conservation Opportunity

An opportunity represents an advantageous combination of circumstances that allows goals to be achieved. We reviewed the nature of opportunity and how it manifests in different subsystems (e.g., biophysical, social, political, economic) as conceptualized in other bodies of literature, including behavior, adoption, entrepreneur, public policy, and resilience literature. We then developed a multidisciplinary conceptualization of conservation opportunity. We identified 3 types of conservation opportunity: potential, actors remove barriers to problem solving by identifying the capabilities within the system that can be manipulated to create support for conservation action; traction, actors identify windows of opportunity that arise from exogenous shocks, events, or changes that remove barriers to solving problems; and existing, everything is in place for conservation action (i.e., no barriers exist) and an actor takes advantage of the existing circumstances to solve problems. Different leverage points characterize each type of opportunity. Thus, unique stages of opportunity identification or creation and exploitation exist: characterizing the system and defining problems; identifying potential solutions; assessing the feasibility of solutions; identifying or creating opportunities; and taking advantage of opportunities. These stages can be undertaken independently or as part of a situational analysis and typically comprise the first stage, but they can also be conducted iteratively throughout a conservation planning process. Four types of entrepreneur can be identified (business, policy, social, and conservation), each possessing attributes that enable them to identify or create opportunities and take advantage of them. We examined how different types of conservation opportunity manifest in a social–ecological system (the Great Barrier Reef) and how they can be taken advantage of. Our multidisciplinary conceptualization of conservation opportunity strengthens and legitimizes the concept.     

调节风窗对瓦斯爆炸影响的数值分析*

为研究调节风窗的面积、位置对瓦斯爆炸传播特性的影响,通过FLACS软件构建不同面积和不同位置调节风窗的风门-巷道模型,对瓦斯在该模型中的爆炸及其传播进行数值模拟,并分析瓦斯爆炸压力、火焰传播速度。研究结果表明:风门前最大瓦斯爆炸压力值与调节风窗边长呈现指数减小关系,而风门后最大瓦斯爆炸压力值与调节风窗边长呈现指数增加关系;火焰传播速度与调节风窗边长呈现指数增加关系;相同面积情况下,调节风窗中心位置对瓦斯爆炸影响较小。     

昆仑山北坡黄土粒度特征与环境意义初探

昆仑山北坡沉积了极端干旱区巨厚的黄土,不仅记录了塔克拉玛干沙漠的发生发展过程, 也蕴含了西风环流的演化信息。该地区气候干旱,成壤作用弱,靠近物源,黄土记录了沉积时 的粒度特征,是研究风动力变化的良好载体。本文选取昆仑山北坡的普鲁剖面进行详细的粒度 分析,结果表明黄土颗粒较粗,是沙漠的近源沉积,搬运动力较强。通过粒级– 标准偏差变化 计算,黄土粒度可以分为粉砂（<36 μm）和细砂（>36 μm）两个敏感粒级组分。依据塔里木盆 地内的现代环流特征,粉砂组分主要与近地面较弱的环流风场有关,而细砂组分主要由盆地南 缘频发的沙尘暴搬运,并且沙尘暴对沙尘的搬运作用可能更为显著。     

建筑物窗口尺寸对火灾竖向蔓延影响的研究

本文以不同窗口尺寸下火灾沿外墙竖向蔓延情况为研究对象,通过对ASTM E2307标准实验台下的火灾场景进行模拟计算,完成了不同窗口尺寸下热通量随距燃烧室窗口下沿高度变化的曲线图,并对上层玻璃破裂时的热通量进行分析,得出窗口尺寸对于火灾竖向蔓延的影响,为性能化防火设计中窗口尺寸及窗口间距提供参考.