Dynamic Tracking and Comprehensive Evaluation on the Natural Resources Security Elements and System in China

System theory,pressure-state-response and drivingpressure-state-impact-response model have been applied to establishing China's dynamic tracking evaluation system of natural resources security in this article.Based on analytic hierarchy process and Delphi methods,the natural resources security situation has been evaluated systematically from 1991 to 2007.The result showed that the overall level of China's natural resources security presented a downtrend from 1991 to 2007.The basic reasons are the pressure indicators such as population,GDP,natural resources trade increased gradually,resulting in tension and fragility of natural resources security.     

江苏、安徽能源强度比较分析与启示

能源在社会经济发展中具有重要作用。随着能源消耗量剧增,能源供需矛盾、环境问题日益突出,研究区域能源强度变化具有重要的现实意义。采用Laspeyres因素分解法,定量分析江苏省和安徽省的产业结构和产业效率对能源强度的影响。研究发现：（1）安徽省的能源强度高于江苏省的能源强度,不过差距在逐渐变小,利用重标极差法预测未来两省的能源强度会逐渐趋同;（2）江苏省的产业结构发展有减小能源强度的趋势,不过作用过程有波动;产业效率有利于降低能源强度;（3）安徽省的产业结构有助于增加能源强度,作用趋势还在增大,产业效率有利于降低能源强度,降低作用大于江苏省。因此本文提出目前同样的投入应该偏向欠发达地区或能源强度较高地区,这有利于快速取得降低能源强度的成效.     

Negotiation System of Ecological Compensation of Water Source Areas

In view of no generally accepted ecological compensation standards and methods at present,this paper discusses the introduction of the negotiation system to the process of ecological compensation for water source areas.That is,the government in water source areas and the downstream regions of river basins should confirm their respective rights and obligations and then establish their compensation standards through negotiations according to the different purposes of water use.The amount of compensation should be determined in the comprehensive consideration of the quality,quantity and compensation price of water.Through open and fair negotiations,an institutional arrangement will be set up,which can make the water source areas and the downstream regions of river basins fully express their true preferences and their independent choices on the ecological environment.     

基于分形理论的江苏沿江城镇体系研究

开放条件下,“全球 地方”作用深刻影响着区域城镇体系,沿江发达地区表现尤其典型。基于分形的相关理论和方法,以2006年为时空断面,对江苏沿江地区城镇体系的空间分布进行实证研究。结果表明：（1）区域城镇规模等级结构服从Zipf定律,首位城市南京在区域城市体系中的垄断性相对较强,但并非处于绝对垄断地位;（2）空间关联维数显示,沿江地区城镇体系的交通网络通达性优良,各城镇间联系紧密;（3）根据分维数和无标度区分析,三大城市群中,宁镇扬城市群分形发育最好,苏锡常次之,通泰城市群分形发育最差;（4）扬州、镇江、南京和苏州的城镇集聚程度较高,分形发育较为成熟;南通、泰州、无锡和常州的集聚程度均较低,分形结构不佳。扬州在区域城镇体系中分形发育最为完善,中心性最好,历史上形成的这种空间格局至今没有变化.     

多瑙河流域国际合作实践与启示

多瑙河是世界上流经国家最多的国际河流,其国际合作的成功实践对世界其他国际河流的合作具有积极的示范和借鉴作用。通过分析和总结多瑙河国际合作历程和合作特点（包括多种合作机制并存互补;引入风险管理、公众参与和流域综合管理等先进理念促进全面合作;利用GIS及数据管理等现代技术手段实现信息资源共享;利用协商和司法手段和平解决国际争端等）,结合我国国际河流的特点和国际水法及国际河流合作的发展趋势,提出了对我国的启示：应加强国际河流相关方面的研究与合作（特别是航运与水电开发等）;应充分重视国际河流生态环境保护,生态环境保护和防洪越来越强调全流域的合作与协调;应坚持国际河流的开发利用与保护并举,走平衡发展之路;应根据各国际河流特点及地区条件,选择合适的管理合作模式.     

Metabolism of the Nonylphenol Isomer [Ring-U-14c]-4-(3′,5′-Dimethyl-3′-Heptyl)-Phenol by Cell Suspension Cultures of Agrostemma githago and Soybean

Abstract

The biotransformation of the nonylphenol isomer [ring-U-¹⁴C]-4-(3′,5′-dimethyl-3′-heptyl)-phenol (4-353-NP, consisting of two diastereomers) was studied in soybean and Agrostemma githago cell suspension cultures. With the A. githago cells, a batch two-liquid-phase system (medium/n-hexadecane 200:1, v/v) was used, in order to produce higher concentrations and amounts of 4-353-NP metabolites for their identification; 4-353-NP was applied via the n-hexadecane phase. Initial concentrations of [¹⁴C]-4-353-NP were 1 mg L^?1 (soybean), and 5 and 10 mg L^?1 (A. githago). After 2 (soybean) and 7 days (A. githago) of incubation, the applied 4-353-NP was transformed almost completely by both plant species to four types of products: glycosides of parent 4-353-NP, glycosides of primary 4-353-NP metabolites, nonextractable residues and unknown, possibly polymeric materials detected in the media. The latter two products emerged especially in soybean cultures. Portions of primary metabolites amounted to 19–22% (soybean) and 21–42% of applied ¹⁴C (A. githago). After liberation from their glycosides, the primary 4-353-NP metabolites formed by A. githago were isolated by HPLC and examined by GC-EIMS as trimethylsilyl derivatives. In the chromatograms, eight peaks were detected which due to their mass spectra, could be traced back to 4-353-NP. Seven of the compounds were side-chain monohydroxylated 4-353-NP metabolites, while the remaining was a (side-chain) carboxylic acid derivative. Unequivocal identification of the sites of hydroxylation/oxidation of all transformation products was not possible. The main primary metabolites produced by A. githago were supposed to be four diastereomers of 6′-hydroxy-4-353-NP (about 80% of all products identified). It was concluded that plants contribute to the environmental degradation of the xenoestrogen nonylphenol; the toxicological properties of side-chain hydroxylated nonylphenols remain to be examined.     

Feasibility of vermicomposting dairy biosolids using a modified system to avoid earthworm mortality

Abstract

A laboratory study was conducted to examine the feasibility of vermicomposting dairy biosolids (dairy sludge), either alone or with either of the bulking agents ‐ cereal straw or wood shavings, using the epigeic earthworm ‐ Eisinea andrei. Earthworms added directly to these three substrates died within 48 hours. A system was developed to overcome the toxic effect of unprocessed dairy biosolids. The substrates were placed over a layer of vermicomposted sheep manure into which the earthworms were inoculated. Within two weeks, all earthworms were within the upper layer of substrate. Compared to sheep manure which is a favourable substrate for vermicomposting, the three substrates containing dairy biosolids were more effective in supporting earthworm growth and reproduction. The final products obtained after 63 days of vermicomposting had 39–53% less organic carbon than the initial substrates. Organic fractionation indicated that vermicomposting increased the stability of the materials to biological decomposition. The vermicomposts obtained from the three substrates with dairy biosolids had low heavy metal contents and electrical conductivities, and did not inhibit plant growth when compared with a commercial vermicompost in a bioassay.     

Development and application of LC–APCI–MS method for biomonitoring of animal and human exposure to imidacloprid

Imidacloprid (IMI) is a relatively new neuro-active neonicotinoid insecticide and nowadays one of the largest selling insecticides worldwide. In the present study a LC–APCI–MS based method was developed and validated for the quantification of imidacloprid and its main metabolite 6-chloronicotinic acid (6-CINA) in urine and hair specimens. The method was tested in biomonitoring of intentionally exposed animals and subsequently applied for biomonitoring of Cretan urban and rural population.     

生物填料地下渗滤系统对生活污水的脱氮

将草甸棕壤、炉渣和活性污泥等基质按体积比13∶6∶1配制生物填料,研究了生物填料地下渗滤系统（subsurface wastewater infiltration system,SWIS）在不同的水力负荷和污染负荷条件下对校园生活污水的脱氮效果。场地实验结果表明,当BOD5负荷为12.0 g BOD5/（m2·d）,表面水力负荷为0.04-0.10 m3/（m2·d）时,SWIS对NH＋4-N和TN的平均去除率分别为92.4%和82.0%。当水力负荷为0.08 m3/（m2·d）,BOD5负荷9.3-16.8 g BOD5/（m2·d）时,SWIS对NH＋4-N和TN的平均去除率为92.7%和81.2%。SWIS中氧化还原电位（oxygen reduction potential,ORP）随进水水力负荷和BOD5负荷的增加而降低,脱氮效率下降。综合出水水质和处理效率,适宜的水力负荷和污染负荷分别为0.065 m3/（m2·d）和12.0 g BOD5/（m2·d）。在此条件下,SWIS的启动周期为25-30 d。出水水质均优于《城市污水再生利用-景观环境用水水质》（GB/T18921-2002）标准,且处理效果稳定,抗负荷冲击能力强。     

有机污染胁迫对人工湿地中浮萍抗氧化系统的影响

湿地植物在处理高负荷有机废水时会受到不同程度的氧化胁迫。本研究基于对浮萍的有机污染胁迫模拟系统,通过对浮萍脂质过氧化和抗氧化防御系统的监测与分析,研究了浮萍对有机污染胁迫的耐受能力及胁迫去除后浮萍的恢复规律。结果表明,浮萍对有机污染胁迫具有较高的耐受性,在胁迫去除后,具有一定的恢复能力。在COD小于400mg/L时,浮萍并未受到氧化胁迫;当COD达到800 mg/L时,浮萍体内ROS含量上升,细胞膜脂过氧化加剧,但抗氧化酶活性升高,抗氧化物质含量增加,浮萍可保持生长,胁迫去除后,抗氧化防御系统可恢复到对照水平;当COD过高（≥1 000mg/L）,ROS急剧上升,抗氧化防御系统遭受破坏,造成不可逆伤害,胁迫去除后不能恢复正常生长。