生物法净化再生胶生产废气工业试验研究

在再生橡胶厂进行橡胶再生低浓度有机废气的生物法净化工业试验研究，对于甲苯浓度为300～1400mg/m^3的再生胶脱硫废气，在常温常压下以气体流量10～20m^3/h、循环液体喷淋量300～500L/h运行生物法废气净化装置获得了良好物净化效果。该装置连续运行100d的结果显示，其对再生胶废气中甲苯的净化效率可较长时间的保持在90%左右，废气经处理后可以实现达标排放，废气处理成本约为工厂再生胶产值的0.12%～0.14%，具有明显的技术先进性和经济合理性。     

烤胶废料活性炭对含铬废水的处理能力

介绍了微波照射下氯化锌法制取烤胶废料活的方法,用该方法所制烤胶废料活性炭处理含废水的结果表明,烤胶废料活性炭具有吸附容量大,过滤速度快,操作控制方便等优点,活性炭对铬的吸附容量是市售一级粉末活性炭的１．８倍。     

莱钢煤气柜密封帘破损分析及对策

对莱钢炼钢厂2万m^2煤气柜密封橡胶布帘破损原因进行分析的基础上，提出了有效的预防措施，效果显著。     

Enzyme catalyzed biodiesel production from rubber seed oil containing high free fatty acid

Unrefined rubber seed oil contains high levels of free fatty acids and moisture, which make the conventional chemical catalyzed transesterification unsuitable. The method of enzyme catalyzed transesterification is well suited for biodiesel production from rubber seed oil as the enzymes are insensitive to the free fatty acids. In the present work, rubber seed oil was extracted from preserved rubber seed cake by mechanical means. The extraction process was designed and optimized through 2⁴ full factorial design. Extracted oil was subjected to enzymatic transesterification using four different lipases to identify the best one for the purpose. Transesterification process was optimized by considering three influencing variables for biodiesel production viz. methanol/oil molar ratio, catalyst concentration (% w/v) and solvent content (% v/v). A 2³ full factorial design was applied to design the experiments and optimize the biodiesel production. The interactive effects of the independent variables on biodiesel yield were analyzed and regression models were developed for each set of enzyme reactions. Among the four lipases, Thermomysis Lanugonosus Lipase was found to be the most suitable for the transesterification of rubber seed oil with a biodiesel conversion of 92.83% at a molar ratio of 4% and 5% (w/v) enzyme concentration in solvent free reaction medium.     

Biosorption of copper ions from dilute aqueous solutions on base treated rubber (Hevea brasiliensis) leaves powder: kinetics, isotherm, and biosorption mechanisms

The effciency of sodium hydroxide treated rubber (Hevea brasiliensis) leaves powder (NHBL) for removing copper ions from aqueous solutions has been investigated. The e?ects of physicochemical parameters on biosorption capacities such as stirring speed, pH, biosorbent dose, initial concentrations of copper, and ionic strength were studied. The biosorption capacities of NHBL increased with increase in pH, stirring speed and copper concentration but decreased with increase in biosorbent dose and ionic strength...     

石家庄某橡胶制品有限公司生产废水处理

介绍了用物化法(气浮 过滤)处理橡胶制品废水的工程实例，并对该工艺进行了简单的说明。经过本工艺处理的橡胶制品废水可以直接回用。     

氟醚橡胶在不同介质下的热老化行为与机理研究

目的 对氟醚橡胶FM-2D在空气与飞马Ⅱ号润滑油中的热老化行为与机理进行研究。方法 开展氟醚橡胶高温贮存试验,在热氧、热油的介质环境下,研究氟醚橡胶的力学性能退化规律。试验后对样品的拉伸性能、压缩性能以及硬度进行检测,并且利用傅里叶红外光谱仪、扫描电子显微镜以及X射线电子能谱对试验后样品进行检测。结果 通过热老化试验,发现氟醚橡胶在200℃以下能够长期维持较好的力学性能。试验温度在200℃以上,氟醚橡胶的力学性能出现明显退化趋势,并且在热空气与热油中的老化趋势不同。在220℃的热空气老化31 d后,氟醚橡胶的拉伸强度下降27.0%,断裂伸长率增大89.8%,压缩应力松弛率为34.6%,硬度下降8.7%。在220℃的热油老化31 d后,氟醚橡胶的拉伸强度下降85.9%,断裂伸长率下降83.9%,压缩应力松弛率为-17.5%,硬度上升4.2%。结论 在热空气老化过程中,橡胶分子链受热氧影响发生断裂,使其强度下降;在热油老化过程中,油介质和高温的耦合作用使橡胶的交联网络失效,橡胶发硬变脆。     

使用聚胺脂的锁片成形模设计

介绍了一种使用聚胺脂结构的锁片成形模.对该模具的结构作了详细分析.并介绍了其成形过程及特点.     

橡胶及制品自然贮存老化行为研究进展

针对橡胶及制品自然贮存老化行为的研究现状,从宏观性能、微观结构、自然贮存试验方法等方面进行综述。其中,宏观性能主要包括力学性能和其他宏观性能两个方面;微观结构方面主要包括FTIR技术、热分析技术、SEM及XPS技术等三个方面;自然贮存试验方法方面主要是部分橡胶及制品的相关自然贮存试验规范及标准。橡胶及制品自然贮存老化行为研究应加强自然贮存试验,综合运用分析手段掌握橡胶及制品的真实老化行为,从而改善橡胶性能,延长其使用寿命。     

用于油库VOCs治理末端的膜法油气回收工艺

为应对愈发严格的环保排放标准,使用新型膜分离技术回收轻质油品蒸发出来的油气。介绍了膜分离工艺的基本原理、系统组成、工艺特点等。以橡胶态膜作为核心分离组件,自行设计了"膜法+吸附法"油气回收工艺,在油库搭建了500 m3/h的膜法油气回收装置。现场应用结果表明,装置运行可靠,工艺简单,占地面积小,安全性高,能够较好地满足国家各项标准的要求。