腐植酸中不同分子量组分与As(Ⅲ)的络合性能

采用超滤方法将腐植酸（HA）分成5个不同分子量组分,利用平衡透析法研究HA中不同分子量组分与As（III）的络合特征和作用机理,计算络合过程的条件分配系数、表观稳定常数.结果表明,腐植酸组分的分子量对HA与As（III）的络合过程有显著的影响,当分子量小于10kDa时,HA与As（III）络合能力明显强于其他条件.其中羧基和酚羟基在HA与砷络合中起重要作用,为主要络合位点.采用Scatchard分析和双位点配体模型对络合结果进行拟合,发现HA中不同分子量组分和As（III）的络合过程中均存在强和弱2种络合位点.     

雨天硫酸盐化速率样品扩散分析

选择采样期不同降雨天数的碱片，测定余边的硫酸盐化速率含量，其结果为：采样期全月无雨时，余边上的硫酸盐均未检出；半月以上至全月有雨时检出率为１００％，检出量占样品量的２．７０～１５．９５％。经扩散试验，查清了余边上的硫酸盐主要是有效面积上采集的样品的扩散，并提出了相应的修正方法。     

Effect of Humic Acid on the Bioavailability of γ-Hexachlorocyclohexane in Marsilea Minuta (L.)

Effect of various concentrations of humic acid (0.2 to 1%) on thebioavailability of -HCH in vegetative clones of theaquatic fern Marsilea minuta was studied in a staticexperimental bioassay system on different photoperiods. Additionof humic acid showed the reduction in the bioavailability of-HCH in all the photoperiods (72 hr light to 144 hrlight) at the interval of 16 hr light (L) and 8 hr dark (D) inboth aerial and submerged portion as compared to controlindicating its protective role in toxicity.     

Application of a systemic approach to the study of pollution of the Tinto and Odiel rivers (Spain)

The province of Huelva in the SW of Spain presents high environmental contrasts: together with the great abundance of natural spaces, it shows the impacts of historical natural resources exploitation processes. In the Ria of Huelva, the effluents of the chemical industries must be added to the contaminating inputs of the Tinto and Odiel rivers, coming from the acid drainage of the mines located in the Iberian Pyrite Belt. This forced the Environmental Agency (AMA) to elaborate in 1987 an Effluent Remediation Plan in order to negate unacceptable environmental impacts. The application of a grey box systemic analysis to the AMD pollution, undergone by the Tinto and Odiel rivers has allowed to set a conclusive explanation of the sampling results observed for a period of 11 years, thus making available an overall view of the polluting process and, above all, an explanation of its partial aspects.     

天青石及锶矿中硫酸锶的测定

通过实验，解决了测定天青石中硫酸锶时的不足，结果令人满意。     

微波高压络合消解石墨炉原子吸收分光光度法测定环境空气中锑

用有机滤膜采集空气中颗粒物样品,用微波高压络合消解后制成样品溶液。用石墨炉原子吸收分光光度法可确定样品溶液中锑的浓度。该方法具有对有机滤膜和样品消解完全,省时,无损失,灵敏度高,准确度、精密度好等特点。     

工作场所空气中硫酸雾（SO3）的分析

采用碘量法测定工作场所空气中的三氧化硫及硫酸雾，三氧化硫及硫酸雾经中性水吸收后与碘化钾和碘酸钾反应，析出的碘与淀粉指示剂作用产生蓝色，进行比色测定。     

酸雨研究的现状和发展趋势

介绍了酸雨的起因和目前国内外开展的 1 1个研究领域 ,叙述了各个领域的研究现状和发展趋势 ,指出要解决酸雨问题 ,应通过对酸性污染物的排放、迁移扩散、转化、沉降、对水及陆地生态系统的影响等基础研究和信息 ,制定出控制污染源的排放、节能及生态恢复对策     

Kinetics of photoelectrocatalytic degradation of humic acid using B_2O_3·TiO_2/Ti photoelectrode

IntroductionEightypercentoforganicsubstancesinthesourcewaterisfromcrudehumicacidthatisacrudeorganiccompoundcreatedbyrottinganddecomposinginnaturalcycle ,thehighercontentofhumicacidis ,theworsequalityofthewateris,notonlycanitcausechrominance,offensiveodor,…     

德兴地区超大型铜、金矿床成矿控制因素及其模拟实验

在深入研究德兴地区超大型铜、金矿成矿地质背景的基础上 ,从构造地球化学方面着重研究德兴地区超大型铜、金矿床成矿的控制因素 ,并进行构造控矿模拟实验。研究结果表明 ,德兴地区超大型铜、金矿床的形成除因其处于特殊的构造位置 ,具有特殊的地质背景及成矿环境外 ,还与多种地质作用、多种控矿因素耦合作用及地质构造长期发展演化使成矿物质多次叠加富集密切相关