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931.
A method involving high resolution gas chromatography combined with ion trap (HRGC-MS/MS) and negative chemical ionisation
(NCI) was developed for the determination of nitrated or oxygenated polycyclic aromatic hydrocarbons (nitro-PAHs, oxy-PAHs)
and other electrophilic substitutes in soil samples. Efficient clean-up was achieved by a combination of methods for the determination
of PAHs in soil and nitro-PAHs in aerosol using solid phase extraction (SPE) and semipreparative high performance liquid chromatography
(HPLC). In samples of surface soil from the city of Basle (Switzerland), nitro-PAHs (mainly 3-nitrofluoranthene and 1-nitropyrene)
were found in concentrations between 30 and 800 ng/kg dry weight. Oxy-PAHs and parent PAHs revealed 102-104-fold higher levels. Nitro-PAHs which are up to 105 times more mutagenic seem to be less persistent in soil than the parent forms, although their entire mutagenic potential
has to be estimated as being on the same order of magnitude. In urban air particulate matter, the amounts of nitro-PAHs (2–62
pg/m3) were 10–100 times lower than oxyPAHs and parent PAHs which were both found in a similar range. 3-nitrobenzanthrone, a recently
described suspected human carcinogen has not yet been detected. Using multivariate statistical analysis, it was possible to
elucidate similarities or special characteristics of substances in a given matrix reflecting their chemical properties or
specific emission sources. 相似文献
932.
Jørgen Saltbones Anstein Foss Jerzy Bartnicki 《Atmospheric environment (Oxford, England : 1994)》1998,32(24):101
The Norwegian Meteorological Institute (DNMI) has developed and implemented for operational use a real-time dispersion model Severe Nuclear Accident Program (SNAP) with capability for predicting concentrations and depositions of the radioactive debris from large accidental releases. SNAP has been closely linked to DNMI’s operational numerical weather prediction (NWP) models.How good are these predictions? Participation in ETEX has partly answered this question. DNMI used SNAP with LAM50S giving meteorological input for these real-time dispersion calculations. LAM50S Limited Area Model with 50 km grid squareswas DNMI’s operational NWP model in 1994 when ETEX took place.In this article we report on how SNAP performed in the first of the ETEX releases in near-real-time mode, using LAM50S—and in hindcast mode for ATMES II, using “ECMWF 1995: ETEX Data set (ATMES II)”as meteorological input data. These two input data sets came from NWP models with quite different characteristics but with similar resolution in time and space.The results from these dispersion simulations matched closely. Deviations early in the simulation period shrank to insignificant differences later on. Since both input data sets were based on “weather analysis” and had similar resolution in space and time, SNAP described the dispersion of the released material very similar in these two simulations. 相似文献
933.
934.
935.
Triantafyllou AG Zoras S Evagelopoulos V 《Environmental monitoring and assessment》2006,122(1-3):41-60
Lignite mining operations and lignite-fired power stations result in major particulate pollution (fly ash and fugitive dust) problems in the areas surrounding these activities. The problem is more complicated, especially, for urban areas located not far from these activities, due to additional contribution from the urban pollution sources. Knowledge of the distribution of airborne particulate matter into size fraction has become an increasing area of focus when examining the effects of particulate pollution. On the other hand, airborne particle concentration measurements are useful in order to assess the air pollution levels based on national and international air quality standards. These measurements are also necessary for developing air pollutants control strategies or for evaluating the effectiveness of these strategies, especially, for long periods. In this study an attempt is made in order to investigate the particle size distribution of fly ash and fugitive dust in a heavy industrialized (mining and power stations operations) area with complex terrain in the northwestern part of Greece. Parallel total suspended particulates (TSP) and particulate matter with an aerodynamic diameter less than 10 μm (PM10) concentrations are analyzed. These measurements gathered from thirteen monitoring stations located in the greater area of interest. Spatial, temporal variation and trend are analyzed over the last seven years. Furthermore, the geographical variation of PM10 – TSP correlation and PM10/TSP ratio are investigated and compared to those in the literature. The analysis has indicated that a complex system of sources and meteorological conditions modulate the particulate pollution of the examined area. 相似文献
936.
937.
采用水蒸气蒸馏法对荠菜叶挥发油进行了提取。通过毛细管气相色谱—质谱联用法分离并鉴定了其化学成分,用气相色谱面积归一化法测定了各成分的相对百分含量,共分离确定了其中12种化合物,所鉴定化合物的含量占全油的65.62%,主要化学成分为:L-胍基琥珀酰亚胺(21.28%)、植醇(18%)、植酮(9.6%)、油酸(4.71%)、棕榈酸(3.97%)等。 相似文献
938.
939.
Integration of traditional and innovative characterization techniques for flux-based assessment of Dense Non-aqueous Phase Liquid (DNAPL) sites 总被引:1,自引:0,他引:1
Nandita B. Basu P. Suresh C. Rao Irene C. Poyer Subhas Nandy Megharaj Mallavarapu Ravi Naidu Greg B. Davis Bradley M. Patterson Michael D. Annable Kirk Hatfield 《Journal of contaminant hydrology》2009,105(3-4):161-172
Key attributes of the source zone and the expanding dissolved plume at a trichloroethene (TCE) site in Australia were evaluated using trends in groundwater monitoring data along with data from on-line volatile organic compound (VOC) samplers and passive flux meters (PFMs) deployed in selected wells. These data indicate that: (1) residual TCE source mass in the saturated zone, estimated using two innovative techniques, is small ( 10 kg), which is also reflected in small source mass discharge ( 3 g/day); (2) the plume is disconnecting, based on TCE concentration contours and TCE fluxes in wells along a longitudinal transect; (3) there is minimal biodegradation, based on TCE mass discharge of 6 g/day at a plume control plane 175 m from source, which is also consistent with aerobic geochemical conditions observed in the plume; and (4) residual TCE in the vadose zone provides episodic inputs of TCE mass to the plume during infiltration/recharge events. TCE flux data also suggest that the small residual TCE source mass is present in the low-permeability zones, thus making source treatment difficult. Our analysis, based on a synthesis of the archived data and new data, suggests that source treatment is unwarranted, and that containment of the large TCE plume ( 1.2 km long, 0.3 km wide; 17 m deep; 2000–2500 kg TCE mass) or institutional controls, along with a long-term flux monitoring program, might be necessary. The flux-based site management approach outlined in this paper provides a novel way of looking beyond the complexities of groundwater contamination in heterogeneous domains, to make intelligent and informed site decisions based on strategic measurement of the appropriate metrics. 相似文献
940.
Asif Qureshi Martin Scheringer Konrad Hungerbühler 《Environmental pollution (Barking, Essex : 1987)》2009,157(2):452-462
A mass balance model for mercury based on the fugacity concept is applied to Lake Superior, Lake Michigan, Onondaga Lake and Little Rock Lake to evaluate model performance, analyze cycling of three mercury species groups (elemental, divalent and methyl mercury), and identify important processes that determine the source-to-concentration relationship of the three mercury species groups in these lakes. This model application to four disparate ecosystems is an extension of previous applications of fugacity-based models describing mercury cycling. The model performs satisfactorily following site-specific parameterization, and provides an estimate of minimum rates of species interconversion that compare well with literature. Volatilization and sediment burial are the main processes removing mercury from the lakes, and uncertainty analyses indicate that air-water exchange of elemental mercury and water-sediment exchange of divalent mercury attached to particles are influential in governing mercury concentrations in water. Any new model application or field campaign to quantify mercury cycling in a lake should consider these processes as important. 相似文献