三峡库区坡耕地利用与水土保持种植制

三峡库区耕地资源十分有限,且坡耕地占有相当大的比重,陡坡地多,在不良的耕作方式下肥力低下,水土流失十分严重在分析三峡库区自然条件与坡耕地资源特点的基础上,讨论了坡耕地种植制度与土壤侵蚀的关系,提出通过合理搭配作物种类进行多熟制间套作,一年生农作物与多年生经饲作物间作及农作物与木本植物等高间作等手段来建立坡耕地水土保持种植制,从而达到减轻土 蚀之目的。     

鄱阳湖水位-淹水面积关系不确定性的分析

湖泊淹水范围的时空变化特征往往决定了湖泊湿地的景观结构和功能。鄱阳湖是我国最大淡水湖,水位和淹水范围的季节变化悬殊,鄱阳湖淹水特征对研究鄱阳湖湿地生态系统的结构与功能都具有显著意义,过去很多研究关注鄱阳湖水位-淹水面积关系,不同的研究者得到的水位-淹水面积关系各有差异,表现出一定的不确定性。利用多时相的卫星遥感影像提取的鄱阳湖水面面积的基础上,结合鄱阳湖长时间序列的水位观测资料,探讨鄱阳湖水位-淹水面积关系不确定的原因。研究结果表明:(1)尽管鄱阳湖水面面积与水位表现分段线性关系,但在相同水位条件下,鄱阳湖水面面积表现出较大的不确定性;(2)鄱阳湖水位表现南高北低的空间异质性格局,随着水位增加,鄱阳湖水位的空间异质性降低,并且水面坡降具有季相性,相同水位下退水期的水面坡降大于涨水期的水面坡降;(3)受洲滩地形和"堑秋湖"渔业方式的影响,相同水位下退水期出露洲滩中子湖泊的水面范围大于涨水期中子湖泊水面范围;(4)此外,鄱阳湖采砂显著改变采沙场的湖盆地形,从而改变低水位下的主要采沙场的淹水范围。综上所述,鄱阳湖水位-淹水面积关系的不确定性除了受湖盆地形、"五河"来水、长江顶托等自然原因,还有采砂和堑秋湖渔业方式等人类活动的原因。     

Secondary arsenic minerals in the environment: A review

Information on arsenic (As) speciation in solid materials is critical for many environmental studies concerned with As stability and/or mobility in natural As-impacted soils and mining or industrial sites contaminated by As. The investigation of these systems has provided evidence for a number of secondary As minerals that have often played a significant role in As mobility in the solid phase–water system. This paper presents a list of environmentally important secondary As minerals in contaminated soil and waste systems, summarizes the information about their origin, occurrence, environmental stability and thermodynamics, and proposes several important avenues for further investigation.     

Structure and thermal stability of toxic chromium(VI) species doped onto TiO2 powders through heat treatment

Chromium(VI)-containing sorbents in the form of sludge or solid residue from treatment processes are often landfilled or used as fill materials, therefore the long-term stability of metal binding is important. The reduction of Cr(VI)–Cr(III) through heat treatment may be a useful detoxification method. After heating at 500, 900, 1000, and 1100 °C for 4 h, the transformation of chemical states of chromium on 105 °C-dried, 7.9% Cr(VI)-doped TiO₂ powders was studied on the basis of surface area measurements, scanning electron microscopy (SEM) images, X-ray diffraction (XRD), and extended X-ray absorption fine structure (EXAFS) spectra. It was shown that Cr(VI) was reduced to Cr(III) in the Cr(VI)-doped samples after heating within 500–900 °C. The present results also suggested that the chromium octahedral was bridged to the titanium tetrahedral and was incorporated in TiO₂ minerals formed after 1000 °C treatment.     

Field Trial Assessment of Biological,Chemical, and Physical Responses of Soil to Tillage Intensity,Fertilization, and Grazing

Soil microbial populations can fluctuate in response to environmental changes and, therefore, are often used as biological indicators of soil quality. Soil chemical and physical parameters can also be used as indicators because they can vary in response to different management strategies. A long-term field trial was conducted to study the effects of different tillage systems (NT: no tillage, DH: disc harrow, and MP: moldboard plough), P fertilization (diammonium phosphate), and cattle grazing (in terms of crop residue consumption) in maize (Zea mays L.), sunflower (Heliantus annuus L.), and soybean (Glycine max L.) on soil biological, chemical, and physical parameters. The field trial was conducted for four crop years (2000/2001, 2001/2002, 2002/2003, and 2003/2004). Soil populations of Actinomycetes, Trichoderma spp., and Gliocladium spp. were 49% higher under conservation tillage systems, in soil amended with diammonium phosphate (DAP) and not previously grazed. Management practices also influenced soil chemical parameters, especially organic matter content and total N, which were 10% and 55% higher under NT than under MP. Aggregate stability was 61% higher in NT than in MP, 15% higher in P-fertilized soil, and also 9% higher in not grazed strips, bulk density being 12% lower in NT systems compared with MP. DAP application and the absence of grazing also reduced bulk density (3%). Using conservation tillage systems, fertilizing crops with DAP, and avoiding grazing contribute to soil health preservation and enhanced crop production.     

TR-01稠油乳化降粘剂研究

针对河南油田井楼区块稠油,自制TR-01乳化降粘剂,通过实验研究了其降粘性能、稳定性,确定了降粘剂TR-01最佳浓度为0.3%、最佳油水比为70∶30。实验结果表明:TR-01乳化降粘剂对井楼区块油井的普遍适用性较强,具有较好的乳化降粘作用(降粘率达到99%以上),地层水对其降粘效果影响不大。其中的纳米成分能增加对污水中悬浮物的吸附能力和絮凝能力,对油田污水处理起到积极作用。     

老垃圾填埋场渗滤液回灌工艺参数研究

根据理论分析,通过回灌能够实现对老垃圾填埋场所产生渗滤液的场内处理,改善渗滤液水质,同时能加速老填埋场的稳定化进程.以深圳市10座老垃圾填埋场为研究对象,提出渗滤液回灌工艺及其参数.回灌方式以水平渗沟为主,设置聚乙烯罐调节水量.渗滤液回灌加速了填埋气体产生速率,降低了有效应力,可能引起垃圾体边坡失稳.较大的渗滤液回灌量(1.6%)导致较低的垃圾边坡安全系数(1.96).确定满足加速垃圾稳定化和填埋场稳定性的最佳回灌量是填埋场渗滤液回灌大规模应用需要解决的重要问题.     

首钢孟家冲尾矿坝渗流稳定分析

针对孟家冲尾矿库坝面出现的渗水现象,对坝体的渗流以及稳定进行计算分析。计算结果表明,由于堆积坝的不断升高,导致坝体浸润线抬高,安全稳定系数降低,从而将造成坝体失稳,出现溃坝事故。为消除隐患,提出采用辐射井排渗的设计方案,并对该方案的可行性进行计算分析。     

空气和废气监测中H2S标液的选择

有2种不同方法制备的H2S标准溶液进行测定,结果表明,所得标准曲线斜率一致,因此,在实际工作中可对其灵活运用。     

Identification of key parameters controlling dissolved oxygen migration and attenuation in fractured crystalline rocks

In the crystalline rocks of the Canadian Shield, geochemical conditions are currently reducing at depths of 500-1000 m. However, during future glacial periods, altered hydrologic conditions could potentially result in enhanced recharge of glacial melt water containing a relatively high concentration of dissolved oxygen (O2). It is therefore of interest to investigate the physical and geochemical processes, including naturally-occurring redox reactions, that may control O2 ingress. In this study, the reactive transport code MIN3P is used in combination with 2k factorial analyses to identify the most important parameters controlling oxygen migration and attenuation in fractured crystalline rocks. Scenarios considered are based on simplified conceptual models that include a single vertical fracture, or a fracture zone, contained within a rock matrix that extends from the ground surface to a depth of 500 m. Consistent with field observations, Fe(II)-bearing minerals are present in the fractures (i.e. chlorite) and the rock matrix (biotite and small quantities of pyrite). For the parameter ranges investigated, results indicate that for the single fracture case, the most influential factors controlling dissolved O2 ingress are flow velocity in the fracture, fracture aperture, and the biotite reaction rate in the rock matrix. The most important parameters for the fracture zone simulations are flow velocity in the individual fractures, pO2 in the recharge water, biotite reaction rate, and to a lesser degree the abundance and reactivity of chlorite in the fracture zone, and the fracture zone width. These parameters should therefore receive increased consideration during site characterization, and in the formulation of site-specific models intended to predict O2 behavior in crystalline rocks.