新型重金属絮凝剂巯基乙酰化羟甲基聚丙烯酰胺的优化制备

为提高含铜废水的处理效果及简化处理流程,以聚丙烯酰胺(PAM)、甲醛、氢氧化钠、巯基乙酸(TGA)为原料,先经羟甲基化反应制备中间产物羟甲基聚丙烯酰胺(MPAM),再通过酰胺化反应将巯基接枝到MPAM分子链上,制备出新型重金属絮凝剂巯基乙酰化羟甲基聚丙烯酰胺(MAMPAM).以水样中Cu(Ⅱ)的去除率为考察目标,采用Plackett-Burman实验、最陡爬坡实验和响应面法中CCD实验优化MAMPAM的制备条件.结果表明,MAMPAM最优制备条件为:MPAM浓度0.31%、MPAM与TGA物质的量比为1∶3.2、反应介质p H值为4.76、反应温度为25℃、反应时间为2 h,在此条件下制备的MAMPAM对Cu(Ⅱ)的去除率为95.30%,与模型的理论预测值94.47%接近,相对偏差仅为0.83%,模型合理可靠.红外分析表明MPAM分子链上成功接上了巯基.MAMPAM对不同初始浓度的含Cu(Ⅱ)水样具有很好的去除效果,Cu(Ⅱ)去除率均能达到90%以上.MAMPAM有望成为一种有效的含铜废水处理剂,具有一定的应用前景.     

"十三五"期间地方社会发展领域科技发展思路研究

"十三五"时期,围绕安徽省资源环境领域科技创新紧迫需求.安徽省应重点在矿产资源绿色高效开发利用、水资源高效利用、地理信息产业、水污染防治、大气污染防治、土壤污染防治、生态环境治理、再生资源综合利用、环保装备等领域实施科技攻关.通过完善普惠性创新支持政策、增加多元化科技创新投入、加大公共产品供给、加强适应新常态的社会发展科技治理体系建设等途径,切实增强社会发展领域自主创新能力.     

菌株Pseudomonas sp. JF122降解苯酚同时还原Cr(VI)的条件优化及生长特性研究

采用富集培养法,从钢铁厂附近河流污泥中分离筛选到1株能同时降解苯酚与还原Cr(VI)的菌株JF122.在600 mg·L^-1苯酚与1.2 mg·L^-1 Cr(VI) 的条件下,采用单因素实验考察了温度、初始pH、该菌接种量等因素对其同时降解苯酚与还原Cr(VI)的影响,并通过正交试验L₉(3³)获得适宜的苯酚降解与Cr(VI)还原条件.结果表明,菌株JF122降解苯酚与还原Cr(VI)的适宜条件为:30 ℃、初始pH=6和接种量1%,此条件下,菌株JF122在56 h内能够降解600 mg·L^-1苯酚同时还原1.2 mg·L^-1 Cr(VI).应用响应曲面法建立了菌株JF122的生长与温度、初始pH、接种量等因素间关系的数学模型,并对其生长条件进行了优化.结果表明,菌株JF122最优生长条件与其降解苯酚并同时还原Cr(VI)的最优条件具有一致性.     

昆明市环境应急监测能力建设现状及对策建议

结合昆明市环境应急监测能力建设的现状,着重分析存在的主要问题,提出了相应的对策建议。     

基于时频分析的裂纹转子碰摩故障特征研究

为研究转子系统耦合故障特性,采用有限元方法建立了含有横向裂纹、转静碰摩的非线性转子动力学模型。首先研究了不同转速下裂纹、碰摩单一故障下转子系统的振动响应,其次研究了两种故障耦合情况下系统的振动响应特征。采用波形图、FFT谱图、瞬时频率和Hilbert-Huang时频谱(HHS)相结合的方法对故障转子振动信号进行了分析。分析结果表明:运用多种时频分析相结合的方法可以较为全面地了解转子的故障特征,裂纹转子在1/5、1/3临界转速时会发生较为明显的5X、3X谐波,且裂纹的产生会导致响应幅值增大,从而引起更为严重的碰摩。      

装置级突发事故应急预案编制的思考与对策

结合石化企业装置生产特点,分析装置级突发事故应急预案编制中存在的不足和问题,并对应急预案编制的思路和处置对策进行了深入地探讨.     

Using corporate social responsibility benchmarking framework to identify and assess corporate social responsibility trends of real estate companies owning and developing shopping centres

Shopping centres that include retail activities have come in for criticism as to their environmental, architectural and social impacts. However, the sector has been applying corporate social responsibility (CSR) practices. In an attempt to identify the best practices regarding CSR and trends therein we developed a CSR benchmarking of companies from the real estate sector owning and developing shopping centres. Based on information from websites, annual, environmental and sustainability reports, and customer services department’s information, in 2004 and 2010, a comparative CSR benchmarking was performed on 23 real estate companies with shopping centres based in Europe, China, Australia and the USA. The CRS benchmarking framework focused on reported CSR practices and included categories and sub-categories of evaluation in four domains: (1) external results, (2) internal results, (3) management processes and (4) learning and innovation. The framework was inspired by the sustainability balanced scorecard structure. The United Kingdom real estate sector’s companies studied did relatively well when evaluated by the framework used in this study. The highest ranked real estate companies applied sustainable or environmental buildings standards and did show a commitment to transparency and CSR disclosure. The positive evolution of CSR practices in the 23 companies studied in 2004 and 2010 may reflect efforts to improve competitiveness and the reputation of the companies with shopping centres through CSR initiatives.     

Modeling assessment for ammonium nitrogen recovery from wastewater by chemical precipitation

Chemical precipitation to form magnesium ammonium phosphate (MAP) is an effective technology for recovering ammonium nitrogen (NH4 +-N). In the present research, we investigated the thermodynamic modeling of the PHREEQC program for NH4 +-N recovery to evaluate the effect of reaction factors on MAP precipitation. The case study of NH4 +-N recovery from coking wastewater was conducted to provide a comparison. Response surface methodology (RSM) was applied to assist in understanding the relative significance of reaction factors and the interactive effects of solution conditions. Thermodynamic modeling indicated that the saturation index (SI) of MAP followed a polynomial function of pH. The SI of MAP increased logarithmically with the Mg2+/NH4 + molar ratio (Mg/N) and the initial NH4 +-N concentration (CN), respectively, while it decreased with an increase in Ca2+/NH4 + and CO3 2??/NH4 + molar ratios (Ca/N and CO3 2??/N), respectively. The trends for NH4 +-N removal at different pH and Mg/N levels were similar to the thermodynamic modeling predictions. The RSM analysis indicated that the factors including pH, Mg/N, CN, Ca/N, (Mg/N) (CO3 2??/N), (pH)2, (Mg/N)2, and (CN)2 were significant. Response surface plots were useful for understanding the interaction effects on NH4 +-N recovery.     

中心组合设计优化S-Cr-TiO2催化剂光降解工艺条件

在确定的温度和光照条件下,采用中心组合设计法研究了固相反应法合成的硫与铬共掺杂二氧化钛(S-Cr-TiO2)光催化剂与水溶苯胺蓝(ANB)可见光降解过程中的三个作用因子:催化剂的浓度、水溶苯胺蓝水溶液的pH值及其初始浓度之间的相互作用关系,得到了影响因子与降解速率之间的回归方程及因素之间相互作用的响应面图.结果表明,S...     

The social impact of natural hazards: a multi‐level analysis of disasters and forms of trust in mainland China

This study aimed to assess the multi‐level effects of natural hazards on trust in Chinese society. Drawing on the Chinese General Social Survey conducted in 2012 and provincial disaster damage records, it examined the association between individuals’ past experiences of disasters and province‐level damage (measured by the number of affected people, deaths, and economic loss) and various forms of trust: in‐group; out‐group; generalised; and political. The findings indicate that Chinese individuals with experience of disasters have higher levels of out‐group trust but lower levels of political trust. Similarly, at the province level, damage owing to disasters over the past three years (2009–11) positively impacted on residents’ out‐group trust while negatively affecting their political trust. However, when provincial damage was aggregated for disasters over the past five years (2007–11), which included the devastating Sichuan earthquake on 12 May 2008, only total deaths had a positive effect on generalised trust.