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31.
Lumei Wang Weihong Ye Shanshan Zhou Kunde Lin Meirong Zhao Weiping Liu 《Journal of environmental science and health. Part. B》2013,48(1):38-43
The acute and chronic toxicity of monocrotophos (MCP), the binary joint toxicity of MCP and bifenthrin (BF), and sodium dodecyl benzene sulfonate (SDBS) to Daphnia magna (D. magna) was evaluated. The 24 h-median effective concentration (24 h-EC50) and 48 h-median lethal concentration (48 h-LC50) of MCP towards D. magna were 161 and 388 μ g/L, respectively. In addition, the lowest-observed effective concentration (LOEC) and non-observed effective concentration (NOEC) of MCP to D. magna were 10 and 5 μ g/L, respectively. Furthermore, the chronic value (ChV) of MCP against D. magna was 7 μ g/L and the acute chronic ratio (ACR) was 55. The number of offspring per female and the intrinsic rate of natural increase (r) were identified as the parameters that were most sensitive to MCP. In addition, toxic unit (TU) analysis was employed to evaluate the joint toxicities. The calculated TUmix values of binary equitoxic mixtures of MCP + BF and MCP + SDBS were 1.47 and 1.63, respectively, which suggests that both equitoxic mixtures exert a limited antagonistic effect. The results of this study revealed that the toxic threshold of MCP towards D. magna is higher than its reported highest residue (4 μ g/L) in the ordinary aquatic environment, and that concurrent exposure to BF or SDBS may exert a slight antagonistic effect. 相似文献
32.
Bappaditya Kanrar Anjan Bhattacharyya 《Journal of environmental science and health. Part. B》2013,48(8):788-797
The photolysis of a rice herbicide Bispyribac sodium (Sodium 2, 6-bis [(4, 6-dimethoxypyrimidin-2-yl) oxy] benzoate) has been studied in different aqueous medium (distilled water, pond water and Irrigation water) under the influence of UV (λ max ≥ 250 nm) and sunlight in presence or absence of sensitizers (TiO2 and KNO3). The study was conducted under laboratory simulated condition which made it possible to evaluate the contribution of different factors viz. source of irradiation, solvent and sensitizers towards the photolysis of bispyribac sodium. The photodegradation proceeds via first order reaction Kinetics in all the cases. Five photo metabolites (M1-M5) were isolated in pure form by column chromatographic method from the irradiation system under UV influenced and TiO2 as sensitizer. From the different spectral data (IR, NMR, UV-VIS, Mass) the structure of these five metabolites were assigned as M1 (Phenol), M2 [2, 6-Dihydroxy benzoic acid], M3 [2, 6-bis [(4, 6 dimethoxypyrimidin-2yl) oxy] benzoic acid], M4 [2-(3-Hydroxy-phenoxy)-pyrimidine-4, 6-diol] and M5 as [2,4-Dihydroxy-3, 5-dimethoxy-6-(4-methoxy pyrimidine-2-yloxy)-benzoic acid]. Moreover, another six photometabolites (M6-M11) were identified from the different irradiation system on the basis of Micromass analysis. On the basis of MS/MS data analysis, the structure of these six photometabolites were assigned as M6 [2-(4, 6-Dimethoxy-pyrimidin-2-yloxy)-6-hydroxy-benzoic acid], M7 [2-Hydroxy-6-(4-hydroxy-6-methoxy-pyrimidin-2-yloxy)-benzoic acid], M8 [4, 6-Dimethoxy-pyrimidin-2-ol], M9 [6-Methoxy-pyrimidine-2, 4-diol], M10 [2-Hydroxy-6-(pyrimidin-2-yloxy)-benzoic acid] and M11 [2, 4, 6-Trimethoxy-pyrimidine]. The plausible Photodegradation pathways of bispyribac sodium in the present investigation were portrayed which proceeds via hydrolysis, hydrolytic cleavage, O-dealkylation, decarboxylation, dehydroxylation, O-alkylation and hydroxylation. 相似文献
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Fenton 法降解抗生素磺胺间甲氧嘧啶钠 总被引:3,自引:1,他引:2
应用Fenton高级氧化技术降解水溶液中抗生素磺胺间甲氧嘧啶钠(SMMS),系统探讨了起始pH、CSMMS、CFe2+、CH2O2和温度等因素对SMMS降解效果的影响。结果表明:CSMMS=4.53 mg/L,pH=4.0,CH2O2=0.49 mmol/L,CFe2+=19.51μmol/L,T=25℃为最佳反应条件。在最佳条件下,87.4%的SMMS可以在120 min内降解。反应动力学研究表明Fenton氧化降解SMMS分为两个阶段,快速反应阶段和慢速反应阶段,并建立了两阶段动力学模型,模型拟合结果较好。研究结果为含有SMMS的污废水处理提供了基础数据和科学参考。 相似文献
35.
旋转填料床/柠檬酸盐法吸收-解吸SO2 总被引:1,自引:1,他引:0
提出采用旋转填料床结合柠檬酸盐法脱除烟气中SO2的方法,考察了旋转填料床转子转速、液气比、初始柠檬酸根浓度和初始pH值等因素对脱硫效率的影响。结果表明,采用超重力法超重机转子转速为1 000 r/min、液气比为7L/m3、初始柠檬酸根浓度为1.5 mol/L、吸收液的初始pH值为5.0,脱硫效率稳定在99%左右。研究了水蒸气汽提法解吸SO2时初始柠檬酸根浓度、初始pH值、SO2浓度、富液流量和水蒸气流量对解吸效率的影响,得出了影响SO2解吸率的基本规律,并进行了分析。通过实验证明该方法在技术上是可行的,具有良好的应用前景。 相似文献
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The main objective of this study was to determine the effects of long-term abiotic processes during aging of organic pollutants in soil on their microbial degradability and formation of non-extractable residues. The specific aims of our study were to investigate how the fate of p353-nonylphenol (NP) and phenanthrene (Phe) in soils might be affected by: (i) saturation of soil by cations with different valency (Na+, Ca2+ or Al3+), (ii) addition of organic substrate (wood flour) during incubation period and (iii) different soil moisture levels. 相似文献
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大坝通过坝身泄流时,巨大的洪水卷吸空气中的大量气体直泻到下游河床,造成下游河道特别是近坝区域气体含量过饱和,给下游水生生物带来不利影响,其中鱼类气泡病就是水体气体过饱和造成的典型病症。为探明大坝泄流对坝下河道溶解氧饱和度的影响,以三峡 葛洲坝区域坝下近坝区定点区域的溶解氧实测资料为基础,建立溶解氧饱和度的BP网络预测模型,对大坝不同运行工况进行下游溶解氧饱和度的预测仿真计算,并将仿真预测值与实测及数值模拟结果进行比较分析。结果得出BP网络模型能很好地逼近坝下近坝区指定区域的溶解氧饱和度,可根据大坝运行工况对下游水体溶解氧饱和度进行快速预测,为有效控制坝下水体溶解氧饱和度提供借鉴 相似文献
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