L-半胱氨酸改性甲壳素处理含铅、镉工业废水

研究了L 半胱氨酸改性甲壳素作为吸附剂对Pb2 + 、Cd2 + 的动态吸附性能 ,同时考察了流速、溶液中离子的含量、吸附剂的相对用量等因素对吸附效果的影响 ,以及洗脱液的种类和酸度、洗脱速度、洗脱液体积等因素对解吸率的影响。结果表明 ,用该吸附剂填装的吸附柱对含Pb2 + 、Cd2 + 工业废水直接进行处理 ,处理后的水达到了排放标准。     

污染土壤毒性研究方法进展

综述了国内外有关污染土壤毒性研究方法 ,包括传统的方法如植物法、动物法和微生物法等和生态毒理学方法 ,并从生物、非生物和环境等方面论述了影响土壤毒性的因素 ,提出了当前土壤污染毒性研究方法中存在的问题 ,认为随着环境科学技术的发展 ,污染土壤毒性研究方法在环境保护中必将发挥越来越重要的作用     

含油固体废弃物综合利用技术的研究

就油田含油固体废弃物的存放及其对周边环境存在的潜在隐患 ,全面分析了该废弃物的组成与成分 ,并介绍了几种可用于石油污染土壤治理技术的方法特点 ,尤其是针对这种固体含量和油分含量皆较高的含油固体废弃物 ,开展了综合利用治理技术方面的试验 ,以固体废弃物细粉作为制砖助燃配料成分 ,考查了砖块质量与细粉掺入量及其他因素之间的关系 ,取得了较好的效果     

污染土壤修复的技术再造与展望

污染土壤的面积在迅速扩大,迫切需要修复、治理;随着土壤污染组分的日益复杂化,等待着全面、高效的修复技术的研制。对污染土壤修复相关技术现状进行剖析表明,现有的各种污染土壤修复技术由于存在着许多技术上难以克服的问题,需要从技术的现有进展和技术构想进行整体意义上的创新,即如何把现有的技术进行参数优化、改造后进行最佳组合与综合,才能取得该技术领域的重大突破。污染土壤的生态化学修复,其实质在于技术的再造,代表了21世纪污染土壤修复技术的发展方向。     

污染土壤修复效果评定方法的研究

在实施污染土壤修复的环境工程后,需要通过灵敏和有效的评定方法对污染土壤修复的效果进行评定.然而,单纯依靠化学方法进行污染土壤修复效果的评定,不能揭示土壤的整体质量特征,因此需要生态毒理方法作为相互补充的手段.本文概述了植物毒性评定法、陆生无脊椎动物评定法和土壤微生物评定法及其在污染土壤修复效果评定中的应用,并对污染土壤修复效果评定方法的发展前景进行展望.     

宝应县土壤重金属的污染调查

以宝应县农田土壤重金属调查为依据，采用污染指数法对土壤质量进行评价，分析土壤重金属污染原因，提出防治措施。     

Soil contamination at abandoned sawmill areas

Contamination of soil by technical chlorophenol formulation at wood preserving sites was studied. The examined soils contained 50 to 1000 mg of polychlorinated phenols (CPs), 1 to 50 mg of polychlorinated phenoxyphenols (“pre-dioxins”, PCPPs) and 0.1 to 5 mg of polychlorinated dibenzofurans (PCDFs) per kg of dry soil. CPs were found to be mobile, leaching deep into the soil, while PCPPs and PCDFs accumulated in the top soil. All three classes of contaminants were stable in soil.     

Modeling in situ ozonation for the remediation of nonvolatile PAH-contaminated unsaturated soils

Mathematical models were developed to investigate the characteristics of gaseous ozone transport under various soil conditions and the feasibility of in situ ozone venting for the remediation of unsaturated soils contaminated with phenanthrene. On the basis of assumptions for the mass transfer and reactions of ozone, three approaches were considered: equilibrium, kinetic, and lump models. Water-saturation-dependent reactions of gaseous ozone with soil organic matter (SOM) and phenanthrene were employed. The models were solved numerically by using the finite-difference method, and the model parameters were determined by using the experimental data of Hsu [The use of gaseous ozone to remediate the organic contaminants in the unsaturated soils, PhD Thesis, Michigan State Univ., East Lansing, MI, 1995]. The transport of gas-phase ozone is significantly retarded by ozone consumption due to reactions with SOM and phenanthrene, in addition to dissolution. An operation time of 156 h was required to completely remove phenanthrene in a 5-m natural soil column. In actual situations, however, the operation time is likely to be longer than the ideal time because of unknown factors including heterogeneity of the porous medium and the distribution of SOM and contaminant. The ozone transport front length was found to be very limited (< 1 m). The sensitivity analysis indicated that SOM is the single most important factor affecting in situ ozonation for the remediation of unsaturated soil contaminated with phenanthrene. Models were found to be insensitive to the reaction mechanisms of phenathrene with either gas-phase ozone or dissolved ozone. More study is required to quantify the effect of OH* formation on the removal of contaminant and on ozone transport in the subsurface.     

Concentrations and trends of benzene in ambient air over New York State during 1990–2003

Since 1990s, a systematic program to measure air toxics has been active in New York State with monitors located both in urban and rural areas. In this study we examined the spatial and temporal characteristics of benzene, a known human carcinogen that is emitted by many source categories. The analysis indicates that ambient concentration levels of benzene have decreased by as much as 60% over this period not only in the ozone non-attainment area of New York City that had the reformulated gas (RFG) requirements, but also over the rest of the state as well. Although the rate of decrease appears to have flattened out in recent years, the annual average concentration levels are found to be above the health risk threshold even at the remote location, Whiteface Mountain, suggesting the need for further reductions in benzene emissions.     

长江表层土壤多氯联苯污染特征及风险评价

采用气质联用仪（GC-MS）对长江流域13个干流断面及18个支流断面处沿岸表层土壤样品中的多氯联苯（PCBs）进行测定,分析其残留特征、污染来源和健康风险.结果表明,长江流域表层土中ΣPCBs的含量范围为：1.05~50.11ng/g dw,平均值为5.71ng/g dw,含量处于较低污染水平.干流的PCBs含量从上游到下游呈现逐渐增大的趋势,且PCBs在宜昌、岳阳、武汉、重庆等二三线城市总含量较高.PCB 17,PCB 18,PCB 44,PCB 74,PCB 87的检出率较高,三氯联苯、四氯联苯是主要的同系物,表明长江流域表层土壤主要以低氯联苯污染为主.主成分分析表明研究区域PCBs主要来自于1号国产变压器油、Aorclor 1242、1248、大气沉降及地表径流的混合污染源;对长江流域表层土壤健康风险评价表明,PCBs存在较小健康风险,呼吸摄入潜在风险低于经口摄入及皮肤接触.