布洛芬降解菌降解谱研究

以从西安污水处理厂筛选所得的3株布洛芬降解菌株I2(克雷伯氏菌)、I4(假单胞菌)和I14(不动杆菌)为研究对象,探索其生长特性及对布洛芬同系物降解的广谱性.结果表明,3株菌对7种选定的布洛芬同系物均有降解作用,但降解能力表现出一定的差异.I2、I4菌株的降解能力优于I14菌株,对7种布洛芬同系物的最高耐受浓度均在300 mg·L-1以上.3株降解菌都对布洛芬同系物中的间苯二酚有良好的耐受能力,最高耐受浓度均在1000 mg·L-1以上,I2菌株甚至达到2500 mg·L-1;3株降解菌对于邻苯二酚、对苯二酚的耐受程度最差,其中,I14菌株在对苯二酚达到100 mg·L-1时就会死亡.I2、I4菌株可作为布洛芬及其同系物降解的优良备选菌株,用于进一步研究多重污染治理的方式.     

Photocatalytic degradation of the diazo dye naphthol blue black in water using MWCNT/Gd,N,S-TiO2 nanocomposites under simulated solar light

A simple sol–gel method was employed to prepare gadolinium, nitrogen and sulphur tridoped titania decorated on oxidised multiwalled carbon nanotubes (MWCNT/Gd,N,S-TiO₂), using titanium (IV) butoxide and thiourea as titanium and nitrogen and sulphur source, respectively. Samples of varying gadolinium loadings (0.2%, 0.6%, 1.0% and 3.0% Gd^3 +) relative to titania were prepared to investigate the effect of gadolinium loading and the amounts of carbon nanotubes, nitrogen and sulphur were kept constant for all the samples. Furthermore, the prepared nanocomposites were evaluated for the degradation of naphthol blue black (NBB) in water under simulated solar light irradiation. Higher degradation efficiency (95.7%) was recorded for the MWCNT/Gd,N,S-TiO₂ (0.6% Gd) nanocomposites. The higher photocatalytic activity is attributed to the combined effect of improved visible light absorption and charge separation due to the synergistic effect of Gd, MWCNTs, N, S and TiO₂. Total organic carbon (TOC) analysis revealed a higher degree of complete mineralisation of naphthol blue black (78.0% TOC removal) which minimises the possible formation of toxic degradation by-products such as the aromatic amines. The MWCNT/Gd,N,S-TiO₂ (0.6% Gd) was fairly stable and could be re-used for five times, reaching a maximum degradation efficiency of 91.8% after the five cycles.     

太阳能光伏废水处理设施脱氮功能优化实例

某太阳能光伏企业的生产废水约4000 m³/d,废水中的主要污染物是少量的氟离子和大量硝态氮,原废水工艺中缺少去除硝态氮的功能。在原废水处理设施基础上,将生化处理工艺优化为“A/O反硝化”工艺,增加碳源投加设备。工程实践表明,工艺优化后,硝态氮得以有效去除,TN去除率达到95%,出水水质达到《电池工业污染物排放标准》(GB30484—2013)表2的间接标准。     

淹水条件下三峡库区典型消落带土壤释放DOM的光谱特征:紫外-可见吸收光谱

消落带土壤在淹水发生时释放溶解性有机质(DOM),是上覆水体DOM的重要来源.但同时对淹水释放DOM进行定量定性分析的报道并不多见.本文以三峡库区典型消落带为研究对象,通过模拟实验,利用紫外-可见吸收光谱,研究了厌氧淹水和正常淹水条件下,淹水土壤释放DOM的光谱特征.结果表明,消落带4个区域土壤淹水均呈"快速释放-下降-动态平衡"释放规律;释放速率和通量计算表明,DOM释放呈现出"源-汇动态交换"特征.对比两种淹水处理,尽管溶解性有机碳(DOC)和有色溶解性有机质(CDOM)无显著差异,但厌氧淹水DOM芳香性(SUVA280)高于正常淹水,而光谱斜率比值(SR)对不同淹水条件不敏感.同时,厌氧淹水时,DOC和CDOM的相关性也明显高于正常淹水.另外,各区域土壤淹水释放DOM存在差异,以忠县石宝寨土壤释放强度最高,尽管土壤有机质含量是影响各区域土壤淹水释放DOM差异的重要原因之一,但其他地化因素仍需考虑.因此,仅仅关注DOC浓度变化并不足以完全描述DOM的释放特征.     

拉压疲劳载荷对地面停放腐蚀影响系数的影响研究

目的研究拉压疲劳载荷对地面停放腐蚀影响系数的影响。方法首先编制加速腐蚀试验环境谱进行预腐蚀试验,随后对预腐蚀后的试验件加载拉压疲劳载荷进行疲劳试验,最后对预腐蚀疲劳试验得到的寿命进行数据分析。结果疲劳载荷无论是拉还是压,都不能改变预腐蚀后的疲劳试验寿命服从对数正态分布的性质,但是疲劳载荷以拉为主的机翼下壁板试验件预腐蚀后,疲劳寿命的分散性随试验寿命的降低而降低,而疲劳载荷以压为主的机翼上壁板结构模拟件预腐蚀后,疲劳寿命的分散性基本不变。结论疲劳载荷以压为主的机翼上壁板结构模拟件的地面停放腐蚀影响系数不随腐蚀年限的增加而变化,而疲劳载荷以拉为主的机翼下壁板试验件的地面停放腐蚀影响系数随腐蚀年限的增加而显著降低。     

环境气象因素监测分析在太阳能热发电站选址快速评估中的应用

目的对凉山州某地太阳能热发电站拟选场址的太阳能资源进行评估。方法利用环境气象因素监测设备监测太阳直接辐射、总辐射和温湿度等环境气象因素,采用经验公式估算凉山州某地全年太阳直接辐射和总辐射量,并利用实测值进行验证。结果某地在秋冬之交,直接辐射强度的平均值为5.7k W·h/(m~2·d),总辐射强度的平均值为5.1 k W·h/(m~2·d)。结论某地为太阳能资源很丰富地区,全年太阳直接辐射量大于5000 MJ/m~2,全年太阳总辐射量大于6000 MJ/m~2,2月、3月、4月和5月为太阳能热发电最佳经济运行的月份。在秋冬之交,有利因素为70%以上的天数直接辐射强度都大于经济性运行的直接辐射强度指标,利于太阳能热发电,是潜在的太阳能热发电站候选地区;不利因素为多云天气和阴天占总天数的百分比接近50%,会极大地影响太阳能热发电的发电量和发电效率。     

太阳辐射试验标准中的太阳光谱分布

目的为太阳辐射试验标准、光老化试验标准修订时正确选择太阳光谱提供依据。方法辨析CIE NO.20,CIE NO.85两种出版物太阳辐射光谱特点,从五个方面对此问题进行探讨,统计这两种太阳辐射光谱带宽辐照度的误差;分析相对空气质量、臭氧与水分、云层光学厚度、地表反射率等因素对太阳辐射光谱辐照度的影响;分析人工辐射光源光谱分布特点,以及它们与太阳辐射光谱的差别;分析当前光老化试验标准对光谱辐照度允差的要求;介绍光老化试验结果间的可比性。结果 CIE NO.85光谱更准确、更细致,但其波长范围较窄,两种光谱辐照度的差别很小,大气环境中许多因素会降低到达地面的光谱辐照度;人工辐射光源光谱与太阳光谱的误差、光老化试验标准中光谱辐照度允差都远大于前述太阳辐射光谱间的误差,标准对太阳光谱波长范围的要求比CIE NO.85光谱宽。结论太阳辐射试验标准、光老化试验标准修订时,仍可选用CIE NO.20光谱作为太阳辐射光谱。     

Guidelines for Riparian Vegetative Shade Restoration Based Upon a Theoretical Shaded‐Stream Model1

Abstract: Guidelines for riparian vegetative shade restoration were developed using a theoretical model of total daily radiation received by a shaded stream. The model assumed stream shading by nontransmitting, vertical or overhanging, solid vegetation planes in infinitely long reaches. Radiation components considered in the model were direct beam shortwave on the stream centerline, diffuse atmospheric shortwave, shortwave reflected by vegetation, atmospheric longwave, and longwave emitted by vegetation. Potential or extraterrestrial shortwave irradiation theory was used to compute beam shortwave radiation received at the stream centerline, and view factor theory was used to compute diffuse radiation exchange among stream, vegetation, and atmospheric planes. Model shade effects under clear skies were dominated by reductions in receipt of direct beam shortwave radiation. Model shade effects with cloudy skies were dominated by the “view factor effect” or the decreases in diffuse shortwave and longwave radiation from the atmosphere balanced against increases in longwave radiation from vegetation. Model shade effects on shortwave radiation reflected by vegetation were found to be negligible. The model was used to determine the vegetation height (H) to stream width (W) ratios needed to achieve 50, 75, and 90 % shade restoration for mid‐latitude conditions on clear and cloudy days. Ratios of vegetation height to stream width, for dense nontransmitting vegetation, generally ranged from 1.4 to 2.3 for 75% shade restoration at a mid‐latitude site (40°N). The model was used to show H/W needed for E‐W vs. N‐S stream azimuths, varying stream latitudes between 30° and 50°N, channels with overhanging vegetation, channels undergoing width changes, as well as the limits to shade restoration on very wide channels.     

波谱分辨率与Chandler摆动的双频现象

地极移动中Chandler摆动有时出现的双频现象，一直为许多学者所关注。分析了IERS新近公布的经统一归算的极移数据，结合频谱分析中分辨率的有关问题，进一步讨论了Chandler摆动的双频现象。分析认为，文中采用的极移资料序列的采样间隔及序列长度已满足分辨Chandler摆动双频的要求。所得结果支持Chandler摆动存在双频的观点，同时给出了该极坐标序列存在的约0．3a至50a间的一些周期的参数。     

The diet of juvenile lake trout Salmo trutta L. in rivers of the Onega basin in autumn

The diet of juvenile trout and the state of their food resources in autumn (September–November) were studied in two typical small rivers tributary to Lake Onega (Karelia) in 2003. The relationship between the composition of food objects among benthic and drifting invertebrates and the food spectrum of trout was analyzed. The results show that before freeze-up, despite the disappearance of aerial and terrestrial insects, juveniles trout continue active feeding. However, their feeding priorities change: they begin to take food objects directly from the bottom, as well as from the water surface and within the water column.