全文获取类型
收费全文 | 3703篇 |
免费 | 459篇 |
国内免费 | 1642篇 |
专业分类
安全科学 | 253篇 |
废物处理 | 379篇 |
环保管理 | 436篇 |
综合类 | 2893篇 |
基础理论 | 602篇 |
污染及防治 | 879篇 |
评价与监测 | 242篇 |
社会与环境 | 92篇 |
灾害及防治 | 28篇 |
出版年
2024年 | 20篇 |
2023年 | 60篇 |
2022年 | 100篇 |
2021年 | 125篇 |
2020年 | 149篇 |
2019年 | 149篇 |
2018年 | 154篇 |
2017年 | 154篇 |
2016年 | 192篇 |
2015年 | 217篇 |
2014年 | 257篇 |
2013年 | 440篇 |
2012年 | 384篇 |
2011年 | 329篇 |
2010年 | 242篇 |
2009年 | 258篇 |
2008年 | 242篇 |
2007年 | 318篇 |
2006年 | 321篇 |
2005年 | 258篇 |
2004年 | 257篇 |
2003年 | 232篇 |
2002年 | 179篇 |
2001年 | 121篇 |
2000年 | 145篇 |
1999年 | 124篇 |
1998年 | 92篇 |
1997年 | 75篇 |
1996年 | 49篇 |
1995年 | 39篇 |
1994年 | 32篇 |
1993年 | 36篇 |
1992年 | 15篇 |
1991年 | 12篇 |
1990年 | 9篇 |
1989年 | 5篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 6篇 |
1981年 | 1篇 |
1977年 | 1篇 |
1973年 | 2篇 |
排序方式: 共有5804条查询结果,搜索用时 31 毫秒
51.
《环境科学学报(英文版)》2023,35(4):517-530
Graphite carbon nitride has many excellent properties as a two-dimensional semiconductor material so that it has a wide application prospect in the field of photocatalysis. However, the traditional problems such as high recombination rate of photogenerated carriers limit its application. In this work, we introduce nitrogen deficiency into g-C3N4 to solve this problem a simple and safe in-situ reduction method. g-C3N4/CaCO3 was obtained by a simple and safe one-step calcination method with industrial-grade micron particles CaCO3. Cyano group modification was in-situ reduced during the thermal polymerization process, which would change the internal electronic structure of g-C3N4. The successful combination of g-C3N4 and CaCO3 and the introduction of cyanide have been proved by Fourier transform infrared spectroscopy and X-ray photoelectron spectrometer. The formation of the cyano group, an electron-absorbing group, promotes the effective separation of photogenic electron hole pairs and inhibits the recombination of photogenic carriers. These advantages result in the generation of more •O2− and 1O2 in the catalytic system, which increases the photocatalytic efficiency of nicotine degradation by ten times. Furthermore, the degradation process of nicotine has been studied in this work to provide a basis for the degradation of nicotine organic pollutants in the air. 相似文献
52.
Xu Song-ling 《环境科学学报(英文版)》1999,(1):4
1IntroductionVilageandtownshipindustry(VTI)isbecomingaveryimportantcomponentofChinaseconomyandenvironment.In1992,VTIproduced... 相似文献
53.
介绍由一级动力学模式推导废水处理实用公式。文中探讨了20℃降解速率系数K20和温度修正系数θ,仅是某种水质和生化条件下的对应值,不能任意通用。 相似文献
54.
The waterquality of the downstream of Nanfei River and the northwest area of Lake Chao is evaluated from organic analysis aspect. PAHs such as fluoranthene, pyrene are detected in the waters collected from downstream river and river mouth. More phenolic compounds are found in the river water. Some halogenated hydrocarbons are present in the river and lake waters. A great many of aliphatic hydrocarbons and benzene hydrocarbons found in all the water samples are about one third of the total organics detected. The hydrophobic components are found to be present not only in water but also in suspended sediment. The ratio of the amount existing is 0.4 in sediment and 1 in particle-free water. The quantity of humic materials existing in lake water is larger than that in river water. The proportion of the humic materials in lake water to that in river water is 1.9 to 1. In the lake water, some natural substances, such as dimethyl disulfide, alpha-pinene, azulene, and 6- methyl -2-heptanone are observed. 相似文献
55.
固相微萃取是一种快速、简便、集萃取浓缩于一体的样品前处理技术,具有分析快速、灵敏度高、无需有机溶剂的优点。用固相微萃取-毛细管气相色谱分析水中甲醇、丙酮、异丙醇、乙醇、乙腈、丙烯腈,检出限可达0.003~0.03mg/L。 相似文献
56.
Zhe Feng Lin Zeng Qingle Zhang Shifeng Ge Xinyue Zhao Hongjun Lin Yiming He 《环境科学学报(英文版)》2020,32(1):149-162
A graphite carbon nitride(g-C_3N_4) modified Bi_4O_5I_2 composite was successfully prepared insitu via the thermal treatment of a g-C_3N_4/Bi OI precursor at 400°C for 3 hr.The as-prepared g-C_3N_4/Bi_4O_5I_2 showed high photocatalytic performance in Methyl Orange(MO) degradation under visible light.The best sample presented a degradation rate of 0.164 min~(-1),which is 3.2 and 82 times as high as that of Bi_4O_5I_2 and g-C_3N_4,respectively.The g-C_3N_4/Bi_4O_5I_2 was characterized by X-ray powder diffractometer(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),Raman,X-ray photoelectron spectroscopy(XPS),ultraviolet-visible diffuse reflectance spectra(DRS),electrochemical impedance spectroscopy(EIS) and transient photocurrent response in order to explain the enhanced photoactivity.Results indicated that the decoration with a small amount of g-C_3N_4 influenced the specific surface area only slightly.Nevertheless,the capability for absorbing visible light was improved measurably,which was beneficial to the MO degradation.On top of that,a strong interaction between g-C_3N_4 and Bi_4O_5I_2 was detected.This interplay promoted the formation of a favorable heterojunction structure and thereby enhanced the charge separation.Thus,the g-C_3N_4/Bi_4O_5I_2 composite presented greater charge separation efficiency and much better photocatalytic performance than Bi_4O_5I_2.Additionally,g-C_3N_4/Bi_4O_5I_2 also presented high stability.·O_2~-and holes were verified to be the main reactive species. 相似文献
57.
城市生活垃圾综合处理系统的选择 总被引:15,自引:0,他引:15
以上海城市生活垃圾处置为对象,利用层次分析方法,选择了分选回收+堆肥+卫生填埋的综合处置系统,并且确定了堆肥方式应首先考虑仓式静态好氧堆肥。经过运行费比较,所选择的综合处置系统比现行的处置系统具有明显的优势。 相似文献
58.
石油化工厂区土壤中总石油烃分布的研究 总被引:5,自引:0,他引:5
为了进行石油化工厂区地下环境的现场评估,利用气相色谱法(EPA8015B)对其土壤中总石油烃(TPHs)进行了测定,测定结果以柴油范围的有机物(DRO)和润滑油范围的有机物(ORO)表示。结果表明:土壤各层DRO检出率在58%-72%之间,ORO检出率在82%-89%之间,大多数检出点位的DRO、ORO含量小于500mg/kg;个别点位的DRO、ORO高达30000mg/kg。 相似文献
59.
60.